Solid State Spectroscopies

Basic Principles And Applications

By: Jorge Garcia, Julio A Gonzalo, Jose De Frutos

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Hardcover | 16 January 2002

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260 Pages

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Materials physics is a very active research field and it is expected to remain so in the foreseeable future. Different spectroscopies are used to investigate the structure and dynamics of crystalline materials. Some traditional spectroscopies are presented in this text: optical, magnetic resonance, ultrasonic, brillouin, neutron scattering, soft mode and dielectric response spectroscopies. For all of them, the presentation is complemented with some reference material for more modern or sophisticated spectroscopies. This work should be useful as an introductory textbook for a short course on solid state spectroscopies. A number of exercises are worked out throughout the text. Ferro- and piezoelectric materials and their phase transitions are paid special attention.

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Preface	p. 1
Fundamentals
Types of solids	p. 3
Crystal lattices	p. 8
Optical properties of solids	p. 13
Lattice vibrations in solids	p. 20
References	p. 27
Optical Spectroscopies
Optical reflectance	p. 29
The Kramers-Kronig relations	p. 32
Electronic interband transitions	p. 38
Excitons	p. 41
References	p. 44
Magnetic Resonance Spectroscopies: EPR
Introduction	p. 45
Analysis of EPR resonances as without relaxation	p. 49
Analysis of resonance with relaxation	p. 52
Concluding remarks	p. 57
References	p. 63
Point Defects in Crystals
Introduction	p. 65
Lattice vacancies: Schottky defects	p. 69
Lattice vacancies: Frenkel defects	p. 73
Diffusion	p. 74
References	p. 76
Sound Waves Spectroscopies in Solids
Normal modes of harmonic crystalline solid	p. 77
Connection with the theory of elasticity	p. 81
Wave equation, sound velocities and elastic constants	p. 87
Ultrasonics spectroscopy	p. 94
Brillouin scattering spectroscopy	p. 97
References	p. 103
Light Scattering Spectroscopies
Classical and quantum theory of light scattering by individual atoms	p. 105
Scattering of light by collective excitations in continuous media	p. 114
Raman scattering in solids	p. 122
Fabry-Perot Interferometer /Double Monochromator	p. 124
References	p. 132
Neutron Scattering Spectroscopies
Elastic and inelastic neutron scattering	p. 133
Neutron scattering length by atomic nuclei	p. 141
Coherent and incoherent neutron scattering	p. 145
Some important applications of elastic and inelastic neutron scattering	p. 147
Neutron scattering by spin waves in ferromagnets	p. 150
Neutron spectrometers	p. 159
References	p. 164
Structural Phase Transitions in Solids
Landau theory for structural phase transitions	p. 165
Microscopic theory of displacive phase transitions: Cochran's model	p. 172
The Lyddanne-Sachs-Teller relation	p. 178
References	p. 181
Soft Mode Spectroscopies
Neutron and Raman scattering investigations of soft modes in perovskites	p. 183
Ultrasonics and Brillouin spectroscopies near order-disorder phase transitions	p. 188
References	p. 192
Dielectric Response Spectroscopies (I)
Contributions to the polarization in insulating solids	p. 193
Dielectric relaxation: Debye theory	p. 200
A microscopic model: the double potential well	p. 203
General solutions to the relaxation equation in ordinary dielectrics	p. 206
References	p. 210
Dielectric Response Spectroscopies (II)
Moderate dipole-dipole interactions: Lorentz approximation	p. 211
Dielectric relaxation near ferroelectric transitions	p. 214
Piezoelectric resonances spectroscopy	p. 221
References	p. 230
Appendix A
Fundamental constants	p. 231
Conversion factors	p. 233
Appendix B
Special topics for oral presentations	p. 235
Appendix C
Tensor parameters of Ferroic phase transitions	p. 243
Index	p. 245
Table of Contents provided by Syndetics. All Rights Reserved.

Solid State Spectroscopies

Basic Principles And Applications

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Hardcover

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