Understanding Distillation Using Column Profile Maps

PREFACE xiii

NOMENCLATURE AND ABBREVIATIONS xix

ABOUT THE AUTHORS xxiii

1 INTRODUCTION 1

1.1 Context and Significance 1

1.2 Important Distillation Concepts 4

1.3 Summary 12

2 FUNDAMENTALS OF RESIDUE CURVE MAPS 15

2.1 Introduction 15

2.2 Batch Boiling 16

2.3 The Mass Balance Triangle (MBT) 17

2.4 The Residue Curve Equation 19

2.5 Residue Curve Maps 21

2.6 Properties of Residue Curve Maps 25

2.7 Applicability of RCMs to Continuous Processes 30

2.8 Limitations of RCMs 39

2.9 Residue Curve Maps: The Bigger Picture 40

2.10 Summary 46

3 DERIVATION AND PROPERTIES OF COLUMN PROFILE MAPS 48

3.1 Introduction 48

3.2 The Column Section (CS) 49

3.3 The Difference Point Equation (DPE) 51

3.4 Column Profile Maps 54

3.5 The Effect of CPM Parameters 61

3.6 Properties of Column Profile Maps 67

3.7 Pinch Point Loci 75

3.8 Some Mathematical Aspects of CPMs 80

3.9 Some Insights and Applications of CPMs 84

3.10 Summary 89

4 EXPERIMENTAL MEASUREMENT OF COLUMN PROFILES 91

4.1 Introduction 91

4.2 The Rectifying Column Section 92

4.3 The Stripping Column Section 98

4.4 Validation of Thermodynamic Models 103

4.5 Continuous Column Sections 105

4.6 Summary 114

5 DESIGN OF SIMPLE COLUMNS USING COLUMN PROFILE MAPS 116

5.1 Introduction 116

5.2 Absorbers and Strippers 117

5.3 Simple Column Design 128

5.4 Azeotropic Systems 141

5.5 Constant Relative Volatility Systems 145

5.6 Summary 154

6 DESIGN OF COMPLEX COLUMNS USING COLUMN PROFILE MAPS 157

6.1 Introduction 157

6.2 Distributed Feed Addition 158

6.3 Sidestream Withdrawal 175

6.4 Thermally Coupled Columns: Side Rectifiers and Strippers 184

6.5 Summary 205

7 DESIGN OF FULLY THERMALLY COUPLED COMPLEX COLUMNS USING COLUMN PROFILE MAPS 206

7.1 Introduction 206

7.2 A Simplified Infinite Reflux Case 208

7.3 General Petlyuk Design 216

7.4 Sharp Split Petlyuk Design Using TTs 240

7.5 Insights into Kaibel Column Design 250

7.6 Summary 258

8 REACTIVE DISTILLATION DESIGN USING COLUMN PROFILE MAPS 261

8.1 Introduction 261

8.2 Simple Reactive Distillation 262

8.3 Reactive Column Sections 275

8.4 Summary 293

9 APPLICATION OF COLUMN PROFILE MAPS TO ALTERNATIVE SEPARATION PROCESSES: MEMBRANE PERMEATION 296

9.1 Introduction 296

9.2 Membrane Permeation 297

9.3 Generalized Membrane Column Sections 299

9.4 Theory 299

9.5 MCS Profiles: Total Reflux 304

9.6 Column Section Profiles: Finite Reflux 306

9.7 Conclusions 314

9.8 Example: Design of Hybrid Systems Using Distillation-Membrane Processes 315

10 CONCLUDING REMARKS 328

10.1 Overall Conclusions 328

10.2 Limitations 329

10.3 Extensions and the Way Forward 330

References 330

APPENDIX A: DODS SOFTWARE PACKAGE 331

APPENDIX B: NRTL PARAMETERS AND ANTOINE COEFFICIENTS 345

INDEX 349