Modified Cyclodextrins : Scaffolds And Templates For Supramolecular Chemistry - Chris J Easton

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Modified Cyclodextrins

Scaffolds And Templates For Supramolecular Chemistry

By: Chris J Easton, Stephen F Lincoln

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Hardcover | 30 April 1999

At a Glance

Hardcover
304 Pages

Dimensions(cm)
22.86 x 16.51 x 1.91

Hardcover

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Through modification, the natural cyclodextrins are effective templates for the generation of a wide range of molecular hosts. This makes it possible to tailor a cyclodextrin host to a particular guest, to meet specific requirements in the host -- guest complex, and opens the way to diverse new areas of supramolecular chemistry. Metallocyclodextrins, rotaxanes and catenanes, as well as surface monolayers of modified cyclodextrins, are readily obtained. The native cyclodextrins serve as scaffolds on which functional groups and other substituents can be assembled, with controlled geometry. This results in substantially improved molecular recognition and procedures for chemical separation, including enantiomer discrimination, through guest binding. Access to the gamut of functional groups greatly expands the utility of cyclodextrins in chemical synthesis and provides catalysts which mimic the entire range of enzymic activity. Modifications to the cyclodextrins also lead to a wide range of photochemistry of cyclodextrin complexes, through which the enhancement of guest reactivity occurs; in addition, light harvesting molecular devices and photochemical frequency switches may be constructed. In solution, modified cyclodextrins have been used to construct molecular reactors, as well as molecular, temperature and pH sensors. At surfaces, they form semipermeable membranes and sensor electrodes. Such exciting fields of chemistry, made possible only through modifications to the natural cyclodextrins, are the subject of this book.

Industry Reviews

"Clearly classified, serves as a solid basis for the coming decades for all those who will work on this inexhaustible section of the synthetic supramolecular chemistry." Cyclodextrin News, 1999 "... this book is a valuable addition to the array of reviews dealing with other aspects of CD chemistry, which have been published recently." Chemistry in Britain, 1999

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You Can Find This Book In

Non-Fiction Science Chemistry Physical Chemistry Biology, Life Sciences Biochemistry Inorganic Chemistry Organic Chemistry Polymer Chemistry Booktopia Publisher Services World Scientific Publishing

Cyclodextrin Structure and Complexation Behaviour	p. 1
Strategies for Synthesis	p. 43
Intramolecular Complexation, Chiral Discrimination and Photochemical Devices	p. 71
Cyclodextrin Catalysts and Enzyme Mimics	p. 101
Metallocyclodextrins	p. 133
Multisite Complexation of Guests and Linked Cyclodextrins	p. 191
Cyclodextrin Rotaxanes and Catenanes	p. 227
Surface and Interface Behaviour	p. 265
Table of Contents provided by Blackwell. All Rights Reserved.

Modified Cyclodextrins

Scaffolds And Templates For Supramolecular Chemistry

At a Glance

Hardcover

Industry Reviews

Shipping

How to return your order

Defective items

You Can Find This Book In

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