Vibrational-Rotational Spectroscopy and Molecular Dynamics

By: Dusan Papousek (Editor)

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Hardcover | 1 December 1996

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Hardcover
576 Pages

Dimensions(cm)
23.5 x 15.88 x 3.81

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The book reviews the results of vibration-rotational spectroscopy of molecules obained recently by combining modern computational methods of quantum chemistry with the new techniques of high-resolution rotational and vibration-rotational spectroscopy. It shows for example that the tunnelling vibration-rotational spectroscopy of the van der Waals complexes provides a new look at intermolecular forces which the high precision and sensitivity of the submillimetre-wave and Fourier transform microwave spectroscopy make it possible to study complex rotational spectra of molecules in excited vibrational states. New results of high level "ab initio" quantum chemical computations of vibrational and rotational energy levels and dipole moment functions of unusual molecules will be discussed together with the recent discovery of clustering of energy levels in asymmetric tops. Group theoretical analysis of floppy molecules, especially the tunnelling effects in nongrid molecules, will also be discussed.

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Introduction
Foreword
Preface
High-Resolution Spectroscopy of Transient Molecules and its Applications to Molecular Dynamics	p. 1
Vibration-Rotation Spectra of Reactive Molecules: Interplay of Ab Initio Calculations and High-Resolution Experimental Studies	p. 56
Rotational Spectra of Symmetric Top Molecules: Correlation-Free Reduced Forms of Hamiltonians, Advances in Measuring Techniques, and Determination of Molecular Parameters From Experimental Data	p. 116
Hot Bands in Infrared Spectra of Symmetric Top and Some Other Molecules. A Useful Tool to Reach Hidden Information	p. 239
The Formation of Four-Fold Rovibrational Energy Clusters in H[subscript 2]S, H[subscript 2]Se, and H[subscript 2]Te	p. 298
Phase Angles in the Matrix Elements of Molecular Spectroscopy	p. 352
High-Resolution Infrared Spectroscopy and One-Dimensional Large Amplitude Motion in Asymmetric Tops: HNO[subscript 3] and H[subscript 2]O[subscript 2]	p. 396
Extended Molecular Symmetry Groups: Symmetry Analysis of Molecules Consisting of Two Coaxial Rotors	p. 461
Quantum-Mechanical Studies of Radiative Association Reactions: Formation of HeH[superscript +], NeH[superscript +] and ArH[superscript +]	p. 516
Index	p. 555
Table of Contents provided by Blackwell. All Rights Reserved.

Vibrational-Rotational Spectroscopy and Molecular Dynamics

At a Glance

Hardcover

Shipping

How to return your order

Defective items

You Can Find This Book In

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