Theoretical Atomic Spectroscopy

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Paperback | 19 September 2007

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456 Pages

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Spectra are fundamental characteristics of atoms and ions, and are the main source of information on their structure and properties. This monograph presents a complete guide to the theory of modern spectroscopy of atoms. The book describes the contemporary state of the theory of many-electron atoms and ions, the peculiarities of their structure and spectra, the processes of their interaction with radiation, and some of the applications of atomic spectroscopy. It contains a large number of new results, which have been mainly published in Russian and are therefore almost unknown to Western scientists. A graduate level text and research reference, this book is aimed primarily at atomic physicists and physical chemists, but will also be of value to physicists and chemists in other areas who use spectroscopy in their work.

Industry Reviews

'... a worthwhile addition to a university library ...' Andrew M. Ellis, Chemistry in Britain 'The writing of Theoretical Atomic Spectroscopy is an admirable achievement ... The book is indispensible to anyone working in atomic theory and should be of interest also to those working in applied spectroscopy.' Mats Larsson, Journal of Analytical Atomic Spectrometry '... a complete ... guide to the theory of modern spectroscopy of atoms ... The book contains a large number of new results, which have been mainly published in Russian and are therefore almost unknown to western scientists. A graduate-level text and research reference, this book is aimed primarily at atomic physicists, astronomers and physical chemists, but will also be of value to physicists, astronomers and chemists in other areas who use spectroscopy in their work.' K. Moskalev, Optik

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Non-Fiction Science Chemistry Analytical Chemistry Spectrum Analysis Physics Atomic & Molecular Physics Optical Physics Nuclear Physics

Preface
Introduction
Energy Spectrum of Many-electron Atom
Radiative and Autoionizing Transitions (Initial Formulas)
Non-relativistic atomic Hamiltonian and relativistic corrections
Relativistic atomic Hamiltonian
New wave function
Perturbation theory for the energy of an atom
Radiative and autoionizing electronic transitions
Generalized expressions for electric multipole (Ek) transition operators
Foundations of the Angular Momentum Theory
Graphical Methods
Angular momentum and tensorial algebra
Main quantities of angular momentum theory
Angular momentum theory for relativistic case
Graphical methods: their generalization for perturbation theory
Description of Complex Electronic Configurations
Non-relativistic and relativistic cases of a shell of equivalent electrons
Two and more shells of equivalent electrons
Classification of energy levels
Relations between various coupling schemes
Second-quantization in the Theory of an Atom: Quasispin and Isospin
Second-quantization and irreducible tensorial sets
Operators and matrix elements in second-quantization representation
Quasispin for a shell of equivalent electrons
Algebraic expressions for coefficients of fractional parentage (CFP)
Tensorial properties and quasispin of complex configurations
Isospin in the theory of an atom
Matrix Elements of the Energy Operator
The energy of a shell of equivalent electrons
Interaction energy of two shells in LS coupling
Semi-empirical methods of calculation of the energy spectra
Hyperfine structure of the energy spectra, isotopic and Lamb shift
Quasispin and isospin for relativistic matrix elements
Electric and Magnetic Multipole Transitions
General expressions for electric (Ek) and magnetic (Mk) multipole radiation quantities
Non relativistic matrix elements of the Ek-transitions
Relativistic matrix elements of Ek-transitions
Mk-transitions
Particular cases of E2- and M1-transitions
Calculation of Energy Spectra and Electronic Transitions in the Case of Complex Configurations
Methods of determination of radial orbitals
Correlation effects
Perturbation theory
The role of gauge dependence, relativistic and correlation effects in electronic transitions
Peculiarities of the structure and spectra of highly ionized atoms
Global methods in the theory of many-electron atoms
Peculiarities of configurations with vacancies in inner shells
Epilogue
References
Index
Table of Contents provided by Publisher. All Rights Reserved.

Theoretical Atomic Spectroscopy

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