Superionic Conductor Physics

By: Jun-ichi Kawamura (Editor), Shinzo Yoshikado (Editor), Takashi Sakuma (Editor), Yoshitaka Michihiro (Editor), Masaru Aniya (Editor)

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Hardcover | 1 December 2006

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Hardcover
224 Pages

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28.6 x 22.0 x 2.0

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The book presents basic studies on ion transport properties of ionic conductive solid. It describes research on theory, modeling, simulation, crystalline structure, nuclear magnetic resonance, electric conduction, optical properties, and thermal measurement in this field. Superionic conductors are highly promising functional materials. As a stepping stone in the development of new superionic conductors that can be utilized as functinal materials efforts to reevaluate solid-interior diffusion and conduction phenomena of ions and molecules in a superionic conductor on the basis of basic physical properties, and to clarify mechanism governing these phenomena from a microscopic standpoint are important.How are diffusing ions associated with material structures within a superionic conductor? What types of interaction are diffusing ions undergoing with the host ions surrounding them? How important is the correlation among diffusing ions in their motion? The carefully presented detail of this book will be of value to research devoted to the understanding and control of functional materials such as superionic conductors.

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Chemical bonding of moving cations in superionic conductors	p. 1
Electronic state of silver and copper halides based on DV-X[alpha] method	p. 9
Physical studies of electronic structure and ionic dynamics in superionic conductors	p. 15
LDA study on polarizabilities of ions in copper halide crystals with the zinc-blende structure	p. 21
Crystal structure of the superionic phase of CuAgSe	p. 27
Application of ion-conducting microelectrodes for cation doping into oxide materials	p. 31
Reliability and limitations of dielectric continuum model for ionic mobility in subcritical liquid methanol and water	p. 35
Proton conductivity of superionic conductor Tl[subscript 3]H(SO[subscript 4])[subscript 2]	p. 41
Structural and compositional analysis of LaF[subscript 3] thin films suitable for oxygen sensor	p. 46
Fast migration phenomenon of Tl[superscript +] ions diffusing in a KCl crystal through the interface with liquid TlCl and solid KCl	p. 50
Pressure dependence of the effective charge in copper halides	p. 57
Ab initio molecular-dynamics simulations of superionic phases of Cu halides and Ag chalcogenides	p. 61
Modeling conduction pathways in ionic conductors	p. 67
Ion conduction path and low-temperature form : argyrodite-type superionic conductors	p. 73
Glassy and polymeric ionic conductors : statistical modeling and Monte Carlo simulations	p. 77
Universalities of ion-hopping in random systems	p. 81
Excitons in AgI-based-glasses and composites	p. 86
Hopping models for ion conduction in noncrystals	p. 97
Coordination environment and network structure in AgI doped As-chalcogenide glasses	p. 103
Scaling properties of ion conduction and what they reveal about ion motion in glasses	p. 113
Study on superionic conductors by optical measurements	p. 122
Phase stabilization and heat capacity of zirconia	p. 129
Computer simulation study of anomalous diffusion in [beta]-AgI	p. 135
NMR study on Li[superscript +] ionic diffusion in Li[subscript x]V[subscript 2]O[subscript 5] prepared by solid-state reaction	p. 139
Direct diffusion studies of solids using radioactive nuclear beams	p. 145
X-ray absorption spectroscopy of Li ion battery and electronic materials	p. 151
Hole burning spectroscopy and site selective spectroscopy for rare earth ions doped La[subscript 0.5]Li[subscript 0.5]TiO[subscript 3]	p. 157
Relation between structure and lithium ion conductivity in La[subscript 4/3-y]Li[subscript 3y]Ti[subscript 2]O[subscript 6]	p. 163
Theoretical investigation of Lithiation of intermetallic anode materials : InSb, Cu[subscript 2]Sb and [eta]'-Cu[subscript 6]Sn[subscript 5]	p. 170
Dispersion of permittivity in ionic and mixed conductors	p. 174
Diffuse x-ray scattering and molecular dynamics studies of K-hollandite at high temperatures	p. 185
Frequency dependence of spin-lattice relaxation of [superscript 27]Al in one-dimensional ionic conductor, priderites	p. 189
Ion conduction in hollandite-type one-dimensional superionic conductors (K, Cs)-priderites	p. 195
Table of Contents provided by Blackwell. All Rights Reserved.

Superionic Conductor Physics

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