Solid State Ionics

Advanced Materials For Emerging Technologies - Proceedings Of The 10th Asian Conference

By: B V R Chowdari (Editor), V A Seneviratne (Editor), R M G Rajapakse (Editor), M A K L Dissanayake (Editor), M A Careem (Editor)

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Hardcover | 7 June 2006

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920 Pages

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The field of solid state ionics deals with ionically conducting materials in the solid state and numerous devices based on such materials. Solid state ionic materials cover a wide spectrum, ranging from inorganic crystalline and polycrystalline solids, ceramics, glasses, polymers, composites and nano-scale materials. A large number of Scientists in Asia are engaged in research in solid state ionic materials and devices and since 1988. The Asian Society for solid state ionics has played a key role in organizing a series of bi-ennial conferences on solid state ionics in different Asian countries. The contributions in this volume were presented at the 10th conference in the series organized by the Postgraduate Institute of Science (PGIS) and the Faculty of Science, University of Peradeniya, Sri Lanka, which coincided with the 10th Anniversary of the Postgraduate Institute of Science (PGIS). The topics cover solid state ionic materials as well as such devices as solid state batteries, fuel cells, sensors, and electrochromic devices. The aspects covered include theoretical studies and modeling, experimental techniques, materials synthesis and characterization, device fabrication and characterization.

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Challenges and opportunities of solid state ionic devices	p. 1
Multinuclear NMR studies of mass transport of phosphoric acid in water	p. 19
Crystalline glassy and polymeric electrolytes : similarities and differences in ionic transport mechanisms	p. 29
30 years of NMR/NQR experiments in solid electrolytes	p. 30
Analysis of conductivity and NMR measurements in Li[subscript 3x]La[subscript 2/3-x]TiO[subscript 3] fast Li[superscript +] ionic conductor : evidence for correlated Li[superscript +] motion	p. 42
Transport pathways for ions in disordered solids from bond valence mismatch landscapes	p. 54
Proton conductivity in condensed phases of water : implications on linear and ball lightning	p. 66
Proton transport in nanocrystalline bioceramic materials : an Investigative study of synthetic bone with that of natural bone	p. 69
Synthesis and properties of the nanostructured fast ionic conductor Li[subscript 0.3]La[subscript 0.56]TiO[subscript 3]	p. 77
Hydrogen production : ceramic materials for high temperature water electrolysis	p. 85
Influence of the sintering temperature on pH sensor ability of Li[subscript 3x]La[subscript 2/3-x]TiO[subscript 3] : relationship between potentiometric and impedance spectroscopy measurements	p. 96
Microstructure chracterization and ionic conductivity of nano-sized CeO[subscript 2]-Sm[subscript 2]O[subscript 3] system (x = 0.05 - 0.2) prepared by combustion route	p. 104
Red soil in northern Sri Lanka is a natural magnetic ceramic	p. 112
Neutron scattering of LiNiO[subscript 2]	p. 121
Preparation and properties of LiFePO[subscript 4] nanorods	p. 129
Structural and electrochemical properties of monoclinic and othorhombic MoO[subscript 3] phases	p. 136
Preparation of zircon (ZrSiO[subscript 4]) ceramics via solid state sintering of ZrO[subscript 2] and SiO[subscript 2] and the effect of dopants on the zircon yield	p. 146
Preparation and properties of vanadium doped ZnTe cermet thin films	p. 154
Dynamical properties and electronic structure of lithium-ion conductor	p. 162
Cuprous ion conducting montmorillonite- polypyrrole nanocomposites	p. 170
Frequency dependence of conductivity studies on a newly synthesized superionic solid solution/mixed system: [0.75AgI: 0.25AgCl]	p. 179
Diffuse X-ray and neutron scattering from powder PbS	p. 185
Electron affinity and work function of pyrolytic MnO[subscript 2] thin films prepared from Mn(C[subscript 2]H[subscript 3]O[subscript 2])[subscript 2].4H[subscript 2]O	p. 193
Crystal structure and heat capacity of Ba[subscript 3]Ca[subscript 1.18]Nb[subscript 1.82]O[subscript 8.73]	p. 201
XPS and impedance investigations on amorphous vanadium oxide thin films	p. 206
Sintering and mixed electronic-ionic conducting properties of La[subscript 1.9]Sr[subscript 0.1]NiO[subscript 4+[delta]] derived from a polyaminocarboxylate complex precursor	p. 213
Preparation and characteristics of ball milled MgH[subscript 2] + M (M = Fe, VF[subscript 3] and FeF[subscript 3]) nanocomposites for hydrogen storage	p. 220
Structural studies of oxysulfide glasses by X-ray diffraction and molecular dynamics simulation	p. 228
Synthesis, sintering and oxygen ionic conducting properties of Bi[subscript 2]V[subscript 0.9]Cu[subscript 0.1]O[subscript 5.5-[delta]]	p. 236
Synthesis and transport characteristics of PbI[subscript 2]-Ag[subscript 2]O-Cr[subscript 2]O[subscript 3] superionic system	p. 244
Electronic conductivity of La[subscript 0.8]Sr[subscript 0.2]Ga[subscript 0.8]Mg[subscript 0.2-x]Co[subscript x]O[subscript 3-[delta]] electrolytes	p. 252
Cathodic properties of Al-doped LiCoO[subscript 2] prepared by molten salt method Li-ion batteries	p. 265
Layered ion-electron conducting materials	p. 283
LiNi[subscript 0.80]Co[subscript 0.20]O[subscript 2] cathode thin-film prepared by RF sputtering for all-solid-state rechargeable microbatteries	p. 295
Nanocomposite cathode for SOFCs prepared by electrostatic spray deposition	p. 305
Effect of the addition of nanoporous carbon black on the cycling characteristics of Li[subscript 2]Co[subscript 2](MoO[subscript 4])[subscript 3] for lithium batteries	p. 313
Protonic conduction in TiP[subscript 2]O[subscript 7]	p. 321
Preparation and electrochemical LiMn[subscript 2]O[subscript 4] thin film by a solution deposition method	p. 329
Synthesis and characterization LiMPO[subscript 4] (M = Ni, Co)	p. 337
Synthesis and electrical characterization of LiCoO[subscript 2], LiFeO[subscript 2] and NiO compositions	p. 345
Natural Sri Lanka graphite as conducting enhancer in manganese dioxide (emd type) cathode of alkaline batteries	p. 353
Electrochemical properties of LiNi[subscript 1-(x+y)]Al[subscript x]Zn[subscript y]O[subscript 2] cathode material synthesized by emulsion method	p. 361
LiNi[subscript 0.80]Co[subscript 0.20]O[subscript 2] cathode materials synthesized by particulate Sol-gel method for lithium ion batteries	p. 369
Pulsed laser deposition of highly oriented LiCoO[subscript 2] and LiMn[subscript 2]O[subscript 4] thin films for microbattery applications	p. 377
Preparation of LiNi[subscript 0.80]Co[subscript 0.20]O[subscript 2] thin films by a sol-gel method	p. 385
Electrochemical lithium insertion into a manganese dioxide electrode in aqueous solutions	p. 392
AC impedance spectroscopic analysis of thin film LiNiVO[subscript 4] prepared by pulsed laser deposition technique	p. 400
Synthesis and characterization of LiFePO[subscript 4] cathode materials by microwave processing	p. 408
Characterization of Nd[subscript 0.8]Sr[subscript 0.2]CoO[subscript 3-[delta]] including Pt second phase as the cathode material for low-temperature SOFCs	p. 412
Thermodynamic behavior of lithium intercalation into natural vein and synthetic graphite	p. 418
Organised or disorganised? Looking at polymer electrolytes from both points of view	p. 431
Polymer electrolytes - simple low permittivity solutions?	p. 443
Dependence of conductivity enhancement on the dielectric constant of the dispersoid in polymer-ferroelectric composite electrolytes	p. 444
Design and application of boron compounds for high-performance polymer electrolytes	p. 449
Structural, vibrational and AC impedance analysis of nano composite polymer electrolytes based on PVAC	p. 459
Absorption intensity variation with ion association in PEO based electrolytes	p. 469
Study of ion-polymer interactions in cationic and anionic ionomers from the dependence of conductivity on pressure and temperature	p. 477
Triol based polyurethane gel electrolytes for electrochemical devices	p. 485
Accurate conductivity measurements to solvation energies in nafion	p. 499
Ion conducting behaviour of composite polymer gel electrolyte : PEG - PVA - (NH[subscript 4]CH[subscript 2]CO[subscript 2])[subscript 2] system	p. 506
Impedance spectroscopy and DSC studies of poly(vinylalcohol)/silicotungstic acid crosslinked composite membranes	p. 514
(PEO)[subscript n]:Na[subscript 4]P[subscript 2]O[subscript 7] : a report on complex formation	p. 522
Experimental studies on (PVC+LiClO[subscript 4]+DMP) polymer electrolyte systems for lithium battery	p. 530
Stability of the gel electrolyte, PAN: EC: PC: LiCF[subscript 3]SO[subscript 3] towards lithium	p. 538
Montmorillonite as a conductivity enhancer in (PEO)[subscript 9]LiCF[subscript 3]SO[subscript 3] polymer electrolyte	p. 543
Polymeric gel electrolytes for electrochemical capacitors	p. 566
Electrical conductivity studies on proton conducting polymer electrolytes based on poly (viniyl acetate)	p. 577
Conductivity and thermal studies on plasticized PEO:LiTf-Al[subscript 2]O[subscript 3] composite polymer electrolyte	p. 585
Investigation of transport properties of a new biomaterials - gum mangosteen	p. 593
Investigation of ionic conductivity of PEO- MgCl[subscript 2] based solid polymer electrolyte	p. 600
[superscript 1]H NMR and Raman analysis of proton conducting polymer electrolytes based on partially hydrolyzed poly (vinyl alcohol)	p. 608
Influence of Al[subscript 2]O[subscript 3] nanoparticles on the phase matrix of polyethylene oxide - silver triflate polymer electrolytes	p. 616
Effect of different types of ceramic fillers on thermal, dielectric and transport properties of PEO[subscript 9] LiTf solid polymer electrolyte	p. 623
Characterization of PVP based solid polymer electrolytes using spectroscopic techniques	p. 631
Electrochemical and structural properties of polyvinylidene fluoride - silver triflate solid polymer electrolyte system	p. 639
Micro Raman, Li NMR and AC impedance analysis of PVAC:LiClO[subscript 4] solid polymer eectrolytes	p. 647
Study of Na[superscript +] ion conduction in PVA-NaSCN solid polymer electrolytes	p. 655
Effect of filler addition on plasticized polymer electrolyte systems	p. 663
Ionic motion in PEDOT and PPy conducting polymer bilayers	p. 671
Film formation mechanism and electrochemical characterization of V[subscript 2]O[subscript 5] xerogel intercalated by polyaniline	p. 679
Effect of NH[subscript 4]NO[subscript 3] concentration on the conductivity of PVA based solid polymer electrolyte	p. 687
Dielectric and conductivity studies of PVA-KSCN based solid polymer electrolytes	p. 696
The use of solid state ionic materials and devices in medical applications	p. 709
Development of all-solid-state lithium batteries	p. 723
Reversible intermediate temperature solid oxide fuel cells	p. 735
Nano-size effects in lithium batteries	p. 736
Electrochromics : fundamentals and applications	p. 747
Electrochemical CO[subscript 2] gas sensor	p. 756
Polypyrrole for artificial muscles : ionic mechanisms	p. 768
Development and characterization of polyfluorene based light emitting diodes and their colour tuning using forster resonance energy transfer	p. 780
Mesoporous and nanoparticulate metal oxides : applications in new photocatalysis	p. 788
Proton conducting (PC) perovskite membranes for hydrogen separation and PC-SOFC electrodes and electrolytes	p. 789
Electroceramic materials for the development of natural gas fuelled SOFC/GT plant in developing country (Trinidad and Tobogo (T&T))	p. 799
Thin film SOFC supported on nano-porous substrate	p. 811
Characterization and fabrication of silver solid state battery Ag/AgI-AgPO[subscript 3]/I[subscript 2],C	p. 818
Performance of lithium polymer cells with polyacrylonitrile based electrolyte	p. 826
Hydrothermal synthesis and electrochemical behavior of MoO[subscript 3] nanobelts for lithium batteries	p. 833
Electrochemical behaviour of a PPy (DBS)/polyacrylonitrile :LiTF:EC:PC/Li cell	p. 841
Characteristics of thick film CO[subscript 2] sensors based on NASICON using Li[subscript 2]CO[subscript 3]-CaCO[subscript 3] auxiliary phases	p. 849
Solid state battery discharge characteristic study on fast silver ion conducting composite system: 0.9[0.75AgI:0.25AgCl]: 0.1TiO[subscript 2]	p. 854
Intercalating protonic solid-state batteries with series and parallel combination	p. 859
Synthesis and characterization of ZnO fiber by microwave processing	p. 866
Preparation of Sn-Ge alloy coated Ge nanoparticles and Sn-Si alloy coated Si nanoparticles by ball-milling	p. 870
Synthesis of ultrafine and crystallized TiO[subscript 2] by alalkoxied free polymerizable precursor method	p. 878
Development and characterization of polythiophene/fullerene composite solar cells and their degradation studies	p. 884
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Solid State Ionics

Advanced Materials For Emerging Technologies - Proceedings Of The 10th Asian Conference

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Hardcover

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