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Semiconductors

Data Handbook

By: Otfried Madelung

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CD-ROM | 20 November 2003 | Edition Number 3

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This Data Handbook is a updated and largely extended new edition of the book "Semiconductors: Basic Data". The data of the former edition have been updated and a complete representation of all relevant basic data is now given for all known groups of semiconducting materials. The CD-ROM accompanying the handbook contains the electronic version of the printed handbook, the references for all data and additionally to the 240 figures of the printed version about 1000 further figures. Full text search is possible.

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Non-Fiction Engineering & Technology Electronics & Communications Engineering Electronics Engineering Electronic Devices & Materials Semi-Conductors & Super-Conductors Science Physics Electricity Other Technologies & Applied Sciences Applied Optics Energy Technology & Engineering

Electrical Engineering Technology in General Materials & States of Matter

Introduction
General remarks to the structure of the volume	p. 1
Physical quantities tabulated in this volume	p. 2
Tetrahedrally bonded elements and compounds
Elements of the IVth group and IV-IV compounds	p. 7
III-V compounds	p. 71
II-VI compounds	p. 173
I-VII compounds	p. 245
III₂-VI₃ compounds	p. 275
I-III-VI₂ compounds	p. 289
II-IV-V₂ compounds	p. 329
I₂-IV-VI₃ compounds	p. 359
I₃-V-VI₄ compounds	p. 367
II-III₂-VI₄ compounds	p. 373
Further elements (for group IV elements see chapter 1)
Group III elements	p. 397
Group V elements	p. 404
Group VI elements	p. 419
Further binary compounds (for I-VII compounds see chapter 4, for II-VI compounds chapter 3, for III-V compounds chapter 2)
IA_x-IB_y compounds	p. 434
I_x-V_y compounds	p. 437
I_x-VI_y compounds	p. 446
II_x-IV_y compounds	p. 464
II_x-V_y compounds	p. 476
II-VII₂ compounds	p. 507
III_x-VI_y compounds	p. 515
III-VII compounds	p. 553
IV-V compounds	p. 563
IV_x-VI_y compounds	p. 566
IV-VII₂ compounds	p. 606
V_x-VI_y compounds	p. 613
V-VII₃ compounds	p. 634
Further ternary compounds (For tetrahedrally bonded quasi-binary and ternary compounds see chapters 510)
I_x-IV_y-VI_z compounds	p. 640
I_x-V_y-VI_z compounds	p. 645
II_x-III_y-VI_z compounds	p. 653
III_x-V_y-VI_z compounds	p. 657
IV_x-V_y-VI_z compounds	p. 661
V-VI-VII compounds	p. 662
Further ternary compounds	p. 674
Boron, transition metal and rare earths compounds with semiconducting properties (Data only on the enclosed CD-ROM)	p. 679
Boron compompounds
Binary transition metal compounds (Compounds with elements of the IVth group, compounds with elements of the Vth group, oxides, chalcogenides)
Binary rare earth compounds
Ternary transition metal compounds (Pnigochalcogenides, spinels and related compounds, oxides, further chalcogenides)
Ternary rare earth compounds
Index of Substances
Index of substances for chapters 1 to 33	p. 680
Index of substances for chapters 34 to 38	p. 685
Introduction
General remarks to the structure of this volume	p. 1
Physical quantities tabulated in this volume	p. 2
Tetrahedrally bonded elements and compounds
Elements of the IVth group and IV-IV compounds
Crystal structure and electronic structure	p. 7
Diamond (C)	p. 11
Silicon (Si)	p. 16
Germanium (Ge)	p. 45
Grey tin (iu-Sn)	p. 57
Silicon carbide (SiC)	p. 60
Silicon germanium mixed crystals (Si_x^Ge1-_x)	p. 70
III-V compounds
Crystal structure and electronic structure	p. 71
Boron nitride (BN)	p. 79
Boron phosphide (BP)	p. 84
Boron arsenide (BAs)	p. 87
Boron antimonide (BSb)	p. 88
Aluminum nitride (AlN)	p. 88
Aluminum phosphide (AlP)	p. 91
Aluminum arsenide (AlAs)	p. 94
Aluminum antimonide (AlSb)	p. 98
Gallium nitride (GaN)	p. 103
Gallium phosphide (GaP)	p. 109
Gallium arsenide (GaAs)	p. 117
Gallium antimonide (GaSb)	p. 129
Indium nitride (InN)	p. 137
Indium phosphide (InP)	p. 139
Indium arsenide (InAs)	p. 148
Indium antimonide (InSb)	p. 154
Ternary alloys lattice matched to binary III-V compounds	p. 162
Quaternary alloys lattice matched to binary III-V compounds	p. 167
II-VI compounds
Crystal structure and electronic structure	p. 173
Beryllium oxide (BeO)	p. 180
Beryllium sulfide (BeS)	p. 182
Beryllium selenide (BeSe)	p. 182
Beryllium telluride (BeTe)	p. 183
Magnesium oxide (MgO)	p. 184
Magnesium sulfide (MgS)	p. 186
Magnesium selenide (MgSe)	p. 186
Magnesium telluride (MgTe)	p. 187
Calcium oxide (CaO)	p. 187
Strontium oxide (SrO)	p. 190
Barium oxide (BaO)	p. 192
Zinc oxide (ZnO)	p. 194
Zinc sulfide (ZnS)	p. 200
Zinc selenide (ZnSe)	p. 208
Zinc telluride (ZnTe)	p. 213
Cadmium oxide (CdO)	p. 218
Cadmium sulfide (CdS)	p. 220
Cadmium selenide (CdSe)	p. 226
Cadmium telluride (CdTe)	p. 232
Mercury oxide (HgO)	p. 235
Mercury sulfide (HgS)	p. 236
Mercury selenide (HgSe)	p. 239
Mercury telluride (HgTe)	p. 241
I-VII compounds
Crystal structure and electronic structure	p. 245
Cuprous fluoride (CuF )	p. 248
Cuprous chloride (y-CuCl)	p. 248
Cuprous bromide (y-CuBr)	p. 254
Cuprous iodide (y-CuI)	p. 259
Silver fluoride (AgF)	p. 262
Silver chloride (AgCl)	p. 263
Silver bromide (AgBr)	p. 268
Silver iodide (AgI)	p. 271
III₂-VI₃ compounds
Crystal structure of quasi-binary II₂-VI₃ compounds	p. 275
Gallium sulfide (Ga₂S₃)	p. 276
Gallium selenide (Ga₂Se₃)	p. 278
Gallium telluride (Ga₂Te₃)	p. 280
Indium sulfide (In₂S₃)	p. 281
Indium selenide (In₂Se₃)	p. 283
Indium telluride (In₂Te₃)	p. 286
I-III-VI₂ compounds (included are I-Fe-VI₂ compounds)
Crystal structure and electronic structure	p. 289
Copper aluminum sulfide (CuAlS₂)	p. 292
Copper aluminum selenide (CuAlSe₂)	p. 294
Copper aluminum telluride (CuAlTe₂)	p. 297
Copper gallium sulfide (CuGaS₂)	p. 298
Copper gallium selenide (CuGaSe₂)	p. 302
Copper gallium telluride (CuGaTe₂)	p. 304
Copper indium sulfide (CuInS₂)	p. 306
Copper indium selenide (CuInSe₂)	p. 309
Copper indium telluride (CuInTe₂)	p. 311
Silver gallium sulfide (AgGaS₂)	p. 313
Silver gallium selenide (AgGaSe₂)	p. 315
Silver gallium telluride (AgGaTe₂)	p. 318
Silver indium sulfide (AgInS₂)	p. 319
Silver indium selenide (AgInSe₂)	p. 320
Silver indium telluride (AgInTe₂)	p. 322
Copper thallium sulfide (CuTlS₂)	p. 324
Copper thallium selenide (CuTlSe₂)	p. 324
Copper thallium telluride (CuTlTe₂)	p. 325
Silver thallium selenide (AgTlSe₂)	p. 325
Silver thallium telluride (AgTlTe₂)	p. 325
Copper iron sulfide (CuFeS₂)	p. 326
Copper iron selenide (CuFeSe₂)	p. 327
Copper iron telluride (CuFeTe₂)	p. 327
Silver iron selenide (AgFeSe₂)	p. 328
Silver iron telluride (AgFeTe₂)	p. 328
II-IV-V₂ compounds
Crystal structure and electronic structure	p. 329
Magnesium silicon phosphide (MgSiP₂)	p. 333
Zinc silicon phosphide (ZnSiP₂)	p. 333
Zinc silicon arsenide(ZnSiAs₂)	p. 356
Zinc germanium nitride (ZnGeN₂)	p. 338
Zinc germanium phosphide (ZnGeP₂)	p. 339
Zinc germanium arsenide (ZnGeAs₂)	p. 342
Zinc tin phosphide (ZnSnP₂)	p. 343
Zinc tin arsenide (ZnSnAs₂)	p. 344
Zinc tin antimonide (ZnSnSb₂)	p. 345
Cadmium silicon phosphide (CdSiP₂)	p. 346
Cadmium silicon arsenide (CdSiAs₂)	p. 348
Cadmium germanium phosphide (CdGeP₂)	p. 349
Cadmium germanium arsenide (CdGeAs₂)	p. 352
Cadmium tin phosphide (CdSnP₂)	p. 355
Cadmium tin arsenide (CdSnAs₂)	p. 357
I₂-IV-VI₃ compounds
Copper germanium sulfide (Cu₂GeS₃)	p. 359
Copper germanium selenide (Cu₂GeSe₃)	p. 360
Copper germanium telluride (Cu₂GeTe₃)	p. 362
Copper tin sulfide (Cu₂SnS₃)	p. 362
Copper tin selenide (Cu₂SnSe₃)	p. 363
Copper tin telluride (Cu₂SnTe₃)	p. 364
Silver germanium selenide (Ag₂GeSe₃)	p. 365
Silver germanium telluride (Ag₂GeTe₃)	p. 365
Silver tin sulfide (Ag₂SnS₃)	p. 366
Silver tin selenide (Ag₂SnSe₃)	p. 366
Silver tin telluride (Ag₂SnTe₃)	p. 366
I₃-V-VI₄ compounds
Crystal structure	p. 367
Copper thiophosphate (Cu₃PS₄)	p. 368
Copper thioarsenide, enargite, luzonite (Cu₃AsS₄)	p. 369
Copper arsenic selenide (Cu₃AsSe₄)	p. 370
Copper antimony sulfide, famatinite (Cu₃SbS₄)	p. 371
Copper antimony selenide (Cu₃SbSe₄)	p. 371
Copper arsenic telluride (Cu₃AsTe₄)	p. 372
Copper antimony telluride (Cu₃SbTe₄)	p. 372
U-IU₂-VI₄ compounds
Crystal structure and electronic structure	p. 373
Zinc aluminum sulfide (ZnAl₂S₄)	p. 375
Zinc gallium sulfide (ZnGa₂S₄)	p. 375
Zinc gallium selenide (ZnGa₂Se₃)	p. 377
Zinc thioindate (ZnIn₂S₄)	p. 378
Zinc indium selenide (ZnIn₂Se₄)	p. 379
Zinc indium telluride (ZnIn₂Te₄)	p. 381
Cadmium thioaluminate (CdAl₂S₄)	p. 381
Cadmium thiogallate (CdGa₂S₄)	p. 382
Cadmium gallium selenide (CdGa₂Se₄)	p. 384
Cadmium gallium telluride (CdGa₂Te₄)	p. 386
Cadmium thioindate (CdIn₂S₄)	p. 387
Cadmium indium selenide (CdIn₂Se₄)	p. 389
Cadmium indium telluride (CdIn₂Te₄)	p. 391
Cadmium thallium selenide (CdTl₂Se₄)	p. 392
Mercury thiogallate (HgGa₂S₄)	p. 393
Mercury gallium selenide (HgGa₂Se₄)	p. 393
Mercury indium telluride (HgIn₂Te₄)	p. 394
HgIn.Se-.,.Hg₃In₂Te₆, Hg₅In₂Te₈	p. 396
Further II-III₂-VI₄ compounds with II = Mg. Ca	p. 396
Further elements
Group III elements
Crystal structure and electronic structure of boron	p. 397
Physical properties of boron	p. 399
Group V elements
Crystal structure and electronic structure	p. 404
Phosphorus (P)	p. 407
Arsenic (As)	p. 409
Antimony (Sb)	p. 412
Bismuth (Bi)	p. 415
Group VI elements
Crystal structure and electronic structure	p. 419
Sulfur (S)	p. 422
Selenium (Se)	p. 424
Tellurium (Te)	p. 429
Further binary compounds
IA_x-IB_y compounds
Crystal structure and electronic structure	p. 434
CsAu	p. 434
RbAu	p. 436
I_x-V_y compounds
Crystal structure and electronic structure	p. 437
I-V compounds (NaSb, KSb, RbSb, CsSb)	p. 440
I₃-V compounds	p. 441
Lattice parameters and melting temperatures	p. 441
Li₃Sb. Li₃Bi	p. 442
Na₃Sb	p. 442
K₃Sb	p. 442
Rb₃Sb	p. 443
Cs₃Sb	p. 443
Rb₃Bi, Cs3Bi	p. 444
I₂-I-V compounds	p. 444
Na₂KSb	p. 444
K₂CsSb	p. 444
Na₂RbSb, Na₂CsSb, K₂RbSb, Rb₂CsSb	p. 445
I_x-VI_y compounds
Crystal structure and electronic structure	p. 446
Cupric oxide (CuO)	p. 449
Cuprous oxide (Cu₂O)	p. 451
Copper sulfides (Cu₂S, Cu₂-_xS)	p. 454
Copper selenides (Cu₂Se, Cu₂-_xSe)	p. 456
Copper tellurides (Cu₂Te, Cu₂-_xTe)	p. 457
Silver oxides (Ag_xO_y)	p. 458
Silver sulfide (Ag₂S)	p. 459
Silver selenide (Ag₂Se)	p. 461
Silver telluride (Ag₂Te)	p. 462
II_x-IV_y compounds
Crystal structure and electronic structure	p. 464
Magnesium silicide (Mg₂Si)	p. 465
Magnesium germanide (Mg₂Ge)	p. 468
Magnesium stannide (Mg₂Sn)	p. 470
Magnesium plumbide (Mg₂Pb)	p. 473
Ca₂Si, Ca₂Sn, Ca₂Pb	p. 475
BaSi₂, BaGe₂, SrGe₂	p. 475
H_x-V_y compounds
Crystal structure and electronic structure	p. 476
Magnesium arsenide (Mg₃As₂)	p. 480
Zinc phosphide (Zn₃P₂)	p. 481
Zinc arsenide (Zn₃As₂)	p. 483
Cadmium phosphide (Cd₃P₂)	p. 485
Cadmium arsenide (Cd₃As₂)	p. 488
Zinc phosphide (ZnP₂)	p. 490
Zinc arsenide (ZnAs₂)	p. 493
Cadmium phosphide (CdP₂)	p. 495
Cadmium arsenide (CdAs₂)	p. 497
Cadmium tetraphosphide (CdP₄)	p. 499
Zinc antimonide (ZnSb)	p. 500
Cadmium antimonide (CdSb)	p. 501
Zinc antimonide (Zn₄Sb₃)	p. 503
Cadmium antimonide (Cd₄Sb₃)	p. 504
Cd₇P₁₀	p. 505
Cd₆P₇	p. 505
II-VII₂ compounds
Crystal structure and electronic structure	p. 507
Cadmium dichloride (CdCl₂)	p. 509
Cadmium dibromide (CdBr₂)	p. 509
Cadmium diiodide (CdI₂)	p. 510
Mercury diiodide (HgI₂)	p. 512
III_x-VI_y compounds
Crystal structure and electronic structure	p. 515
Gallium sulfide (GaS)	p. 520
Gallium selenide (GaSe)	p. 523
Gallium telluride (GaTe)	p. 527
Indium sulfide (InS)	p. 529
Indium selenide (InSe)	p. 530
Indium telluride (InTe)	p. 533
Thallium sulfide (TlS)	p. 535
Thallium selenide (TlSe)	p. 536
Thallium telluride (TlTe)	p. 538
In₆ Se₇	p. 539
In₄ Se₃	p. 540
In₆ Se₇	p. 540
In₆₀ Se₄₀	p. 541
In₅₀ Se₅₀	p. 542
In₄₀ Se₆₀	p. 542
In₅Se₆	p. 542
In₄Te₃	p. 543
Tl₅Te₃	p. 543
TlGaS₂	p. 543
TlGaSe₂	p. 545
TlGaTe₂	p. 547
TlInS₂	p. 548
TlInSe₂	p. 550
TlInTe₂	p. 551
III-VII compounds
Crystal structure and electronic structure	p. 553
Thallium fluoride (TlF)	p. 555
Thallium chloride (TlCl)	p. 556
Thallium bromide (TlBr)	p. 558
Thallium iodide (TlI)	p. 561
IV-V compounds
Crystal structure and lattice parameters	p. 563
SiP, GeP	p. 564
SiAs	p. 564
GeAs	p. 565
SiP₂, SiAs₂	p. 565
GeAs₂	p. 565
IV_x-VI_y compounds
Crystal structure and electronic structure	p. 566
Germanium sulfide (GeS)	p. 572
Germanium selenide (GeSe)	p. 574
Germanium telluride (GeTe)	p. 576
Tin sulfide (SnS)	p. 578
Tin selenide (SnSe)	p. 580
Tin telluride (SnTe)	p. 582
Lead monoxide (PbO)	p. 585
Lead sulfide (PbS)	p. 586
Lead selenide (PbSe)	p. 588
Lead telluride (PbTe)	p. 590
Germanium dioxide (GeO₂)	p. 593
Germanium disulfide (GeS₂)	p. 595
Germanium diselenide (GeSe₂)	p. 596
Tin dioxide (SnO₂)	p. 597
Tin disulfide (SnS₂)	p. 600
Tin diselenide (SnSe₂)	p. 602
Si₂Te₃	p. 603
Sn₂S₃, PbSnS₃, SnGeS₃, PbGeS₃	p. 605
IV-VII₂ compounds
Crystal structure	p. 606
Lead difluoride (PbF₂)	p. 606
Lead dichloride (PbCl₂)	p. 608
Lead dibromide (PbBr₂)	p. 609
Lead diiodide (PbI₂)	p. 610
V_x-VI_y compounds
Crystal structure and electronic structure	p. 613
Arsenic oxide (As₂O₃)	p. 617
Arsenic sulfide (As₂S₃)	p. 617
Arsenic selenide (As₂Se₃)	p. 619
Arsenic telluride (As₂Te₃)	p. 620
Antimony sulfide (Sb₂S₃)	p. 621
Antimony selenide (Sb₂Se₃)	p. 622
Antimony telluride (Sb₂Te₃)	p. 624
Bismuth oxide (Bi₂O₃)	p. 626
Bismuth sulfide (Bi₂S₃)	p. 627
Bismuth selenide (Bi₂Se₃)	p. 628
Bismuth telluride (Bi₂Te₃)	p. 630
Realgar (As₄S₄)	p. 633
V-VII₃ compounds
Crystal structure and electronic structure	p. 634
Arsenic triiodide (AsI₃)	p. 635
Antimony triiodide (SbI₃)	p. 636
Bismuth triiodide (BiI₃)	p. 637
Further ternary compounds
I_x-IV_y-VI_z compounds
Crystal structure	p. 640
Ag₈GeS₆ (argyrodite)	p. 641
Ag₈SnS₆ (canfieldite)	p. 641
Ag₈SiSe₆	p. 642
Ag₈GeSe₆	p. 642
Ag₈SnSe₆	p. 643
Ag₈GeTe₆	p. 643
Cu₈GeS₆	p. 644
Cu₈GeSe₆	p. 644
Cu₄Ge₃S₅, Cu₄Ge₃Se₅ and Cu₄Sn₃Se₅	p. 644
Cu₄SnS₄	p. 644
I_x-V_y-VI_z compounds
Crystal structure and electronic structure	p. 645
AgAsS₂	p. 646
AgAsSe₂	p. 646
AgAsTe₂	p. 647
AgSbS₂	p. 647
AgSbSe₂	p. 647
AgSbTe₂	p. 648
AgBiS₂	p. 648
AgBiSe₂	p. 649
AgBiTe₂	p. 649
CuSbSe₂	p. 650
CuSbTe₂	p. 650
CuBiSe₂	p. 651
CuBiTe₂	p. 651
Ag₃AsS₃	p. 651
Ag₃SbS₃	p. 652
II_x-III_y-VI_z compounds
Crystal structure of II-III-VI₂ compounds	p. 653
CdInS₂	p. 653
CdInSe₂	p. 654
CdInTe₂	p. 654
CdTlS₂	p. 655
CdTlSe₂	p. 655
CdTlTe₂	p. 656
HgTlS₂	p. 656
III_x-V_y-VI_z compounds
Crystal structure of III-V-VI₂ compounds	p. 657
TlAsS₂	p. 657
TlSbS₂	p. 657
TlBiS₂	p. 658
TlBiSe₂	p. 658
TlBiTe₂	p. 659
Ga₆Sb₅Te	p. 659
In₆Sb₅Te	p. 659
In₇SbTe₆	p. 660
IV_x-V_y-VI_z compounds
Crystal structure	p. 661
Bi₁₂SiO₂₀	p. 661
Bi₁₂GeO₂₀	p. 662
PbSb₂S₄, GeSb₂Te₄, GeBi₂Te₄,SnBi₂Te₄	p. 662
GeBi₄Te₇, GeSb₄Te₇, PbBi₄Te₇	p. 663
V-VI-VII compounds
Crystal structure and electronic structure	p. 665
AsSBr	p. 666
SbSI	p. 666
SbSBr	p. 669
SbSeBr	p. 669
SbSeI	p. 669
SbTeI	p. 670
BiOCl	p. 670
BiOBr	p. 670
BiOI	p. 671
BiSCl	p. 671
BiSBr	p. 671
BiSI	p. 671
BiSeBr	p. 672
BiSeI	p. 672
BiTeBr	p. 672
BiTeI	p. 673
Further ternary compounds
Cu₃In₅Se₉	p. 674
Cu₃Ga₅Se₉	p. 674
Ag₃In₅Se₉	p. 675
Ag₃Ga₅Se₉	p. 675
Cu₂Ga₄Te₇	p. 675
Cu₂In₄Te₇	p. 676
CuIn₃Te₅	p. 676
AgIn₃Te₅	p. 677
AgIn₅S₈	p. 677
AgIn₉Te₁₄	p. 677
Cd₂SnO₄	p. 677
CdSnO₃	p. 678
Li₃CuO₃	p. 678
Hg₃PS₃, Hg₃PS₄	p. 678
Cd₄(P,As)₂(Cl,Br,I)₃	p. 678
Boron, transition metal and rare earth compounds with semiconducting properties (data only on the enclosed CD-ROM)	p. 679
Boron compounds
Boron-hydrogen alloys
Binary boron-lithium compounds
Ternary boron-lithium compounds
Boron-sodium compounds
Boron-potassium compounds
Beryllium-aluminum-boron compounds
Boron-aluminum-magnesium compounds
Boron-alkaline earth compounds
Aluminum-boron compounds
Boron-yttrium compounds
Lanthanide hexaborides
Lanthanide hexaborides of the type LaB₆₆
MgAlB₁₄ type borides with lanthanides
Boron compounds with group IV elements: boron carbide
Boron-silicon compounds
Boron-zirconium compounds
Boron-nitrogen compounds
Boron-phosphorus compounds
Boron-arsenic compounds
Binary transition metal compounds
Compounds with elements of the IVth group
Compounds with elements of the Vth group
Chalcogenides
Binary rare earth compounds
Ternary transition metal compounds
Pnigochalcogenides
Spinels and related compounds
Further chalcogenides
Ternary rare earth compounds
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Semiconductors

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Design Essentials for Robust Systems

Learning Opentelemetry

Setting Up and Operating a Modern Observability System

Managing Innovation 6ed

Integrating Technological, Market and Organizational Change

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