NATO Science Series E

Towards an Understanding of Microscopic Processes in Catalysis

By: R.M. Lambert (Editor), Gianfranco Pacchioni (Editor)

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Hardcover | 28 February 1997

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544 Pages

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24.77 x 17.15 x 3.81

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Heterogeneous catalysis provides the backbone of the world's chemical and oil industries. The innate complexity of practical catalytic systems suggests that useful progress should be achievable by investigating key aspects of catalysis by experimental studies on idealised model systems. Thin films and supported clusters are two promising types of model system that can be used for this purpose, since they mimic important aspects of the properties of practical dispersed catalysts. Similarly, appropriate theoretical studies of chemisorption and surface reaction clusters or extended slab systems can provide valuable information on the factors that underlie bonding and catalytic activity. This volume describes such experimental and theoretical approaches to the surface chemistry and catalytic behaviour of metals, metal oxides and metal/metal oxide systems.
An introduction to the principles and main themes of heterogeneous catalysis is followed by detailed accounts of the application of modern experimental and theoretical techniques to fundamental problems. The application of advanced experimental methods is complemented by a full description of theoretical procedures, including Hartree-Fock, density functional and similar techniques. The relative merits of the various approaches are considered and directions for future progress are indicated.

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Non-Fiction Engineering & Technology Mechanical Engineering & Materials Materials Science Science Chemistry Analytical Chemistry Industrial Chemistry & Manufacturing Technologies Industrial Chemistry Physical Chemistry Catalysis

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Published: 4th December 2010

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Preface
Introduction to Heterogeneous Catalysis
Thin Films as Model Catalysts
Metal Deposits on Thin Well Ordered Oxide Films: Morphology
Adsorption and Reactivity
The Growth and Stability of Ultrathin Films on Metal and Oxide Surfaces
Size Effects in Heterogeneous Catalysis: A Surface Science Approach
Supported Clusters, Structure, Reactivity and Microscopic Processes in Catalysis
Quantitative Determination of Molecular Adsorbate Structures
The Structure and Reactivity of TiO2(110) Supported Palladium and Rhodium
Angle-Scanned Photoelectron Diffraction: A Structural Probe for Near-Surface: Atomic Layers
Co-Adsorption on Metal-Oxide Crystal Surfaces: Cases of CO/Cu/ZnO(0001) and CO2/Na/TiO2(110)
Theory of Adsorption and Surface Reactions
Density Functional Cluster Calculations on Metal Deposition at Oxide Surfaces
Theory of Heterogeneous Catalytic Reactivity Using the Cluster Approximation
Cluster Modelling of Oxide Surfaces: Structure
Adsorption and Reactivity
Theoretical Modelling of Chemisorption and Reactions on Metal-Oxide Surfaces
Stability of Polar Oxide Surfaces: Oxygen Vacancies and Non-Stoichiometric Reconstructions
Computer Simulation of Structural, Defect and Surface Properties of Solids
Index
Table of Contents provided by Publisher. All Rights Reserved.

NATO Science Series E

Towards an Understanding of Microscopic Processes in Catalysis

At a Glance

Hardcover

Shipping

How to return your order

Defective items

You Can Find This Book In

Other Editions and Formats

Paperback

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