
At a Glance
444 Pages
24.0 x 16.5 x 3.2
Hardcover
$504.75
or 4 interest-free payments of $126.19 with
 orÂShips in 10 to 15 business days
The field of microporous solids in solid state chemistry has seen a huge expansion over the last decades with new developments in a diverse range of directions and applications. Drawing upon nature as an inspiration, scientists are continually extending known families and preparing porous solids with novel structures. In turn, the novel properties that these possess stimulate further research and applications. Microporous Framework Solids describes fundamental principles and experimental practices of the synthetic chemistry and physical characterisation of crystalline microporous solids. It also provides a clear and up to date discussion of different types of microporous materials, their applications and emerging areas of current interest, written from a personal research perspective. Topics include the different types of solids and their properties with key emphasis placed on the relationship between properties and structure. Structural methods are also discussed including the role of diffraction, NMR and computational studies. Finally, applications for catalysis are reviewed. This book is ideal for new researchers in the field of microporous solids both in academia and industry who require a detailed and informative overview of the subject. It provides a comprehensive review of microporous materials in an easily accessible style offering a valuable source of references over a wide range of topics.
Industry Reviews
"...fills a gap in the available literature.""First the author is to be congratulated for having had the courage to write a book on this complex subject. In my opinion the most important benefit of that bold initiative is that this book, unlike some multi-volume handbooks on this calss of materials, which often consist of an edited collection of review articles by different authors, has been written by a single author, in fact that contributes greatly to its understandability and clarity.""...the scientific content is up-to-date..""...chocie of literature on the whole is very good.!"...the bookshould be in the everyday collections of all research groups whose work is focussed on porous materials or who sometimes deal with them."
* Angewandte Chemie, International Edition *"The author has created an excellent text for both experiencedresearchers and those new to the area of zeolites and molecularsieves.""In summary, it is difficult to think of another monograph thattreats both the basic aspects of zeolites and their advancedapplications together in such a descriptive manner. The depthto which the author describes the known chemistry andimportance of these materials is another strength of this book."" it is ideal for anyoneinterested in or researching nanoporous and mesoporous materials. This includes zeolites/zoetypes as well as the rapidly expanding area of mesoporous materials and metal organicframeworks."
* Journal of the American Chemical Society, 25th June 2008 (Scott R. J. Oliver) *An excellent text for both experienced researchers and those new to the area.Excellent treatment of the traditional established areas - synthesis structures, and properties-as well as up to date references and developments on applications.An easy compliment or perhaps replacement of classic older texts on zeolites and molecular sieves.Its difficult to think of another monograph that treats the basic aspects of zeolites and their advanced applications togethter in such a descriptive manner.Ideal for anyone interested in researching nanoporous and mesoporous materials. This includes zeolites/zoetypes as well as the rapidly expanding area of mesoporous materials and metal organic frameworks.
* Journal of the American Chemical Society Scott R.J Oliver, Inversity of California. *| Acknowledgements | p. xiv |
| Introduction | |
| Microporous Framework Solids: Definitions | p. 1 |
| Historical Development of the Subject | p. 1 |
| References | p. 6 |
| Families of Microporous Framework Solids | |
| Introduction | p. 8 |
| Aluminosilicate Zeolites and Silica Polymorphs | p. 11 |
| Structural Chemistry | p. 11 |
| Zeolite Framework Types | p. 13 |
| Substitutional Metallosilicates | p. 25 |
| Aliovalent Substitutions | p. 26 |
| Isovalent Substitutions (M[superscript 4+ left and right double arrow] Si[superscript 4+]) | p. 27 |
| Metallophosphate Zeotypes and Related Materials | p. 28 |
| Aluminophosphates (AlPO[subscript 4]s) | p. 28 |
| Substituted AlPO[subscript 4]s | p. 30 |
| Mixed Coordination Inorganic Frameworks | p. 33 |
| Metallosilicates | p. 33 |
| Metallophosphates | p. 39 |
| Germanates | p. 40 |
| Microporous Metal Oxides-Octahedral Molecular Sieves | p. 41 |
| Non-oxide Microporous Solids | p. 43 |
| Microporous Organic-Inorganic Hybrids | p. 44 |
| Organically-lined Inorganic Frameworks | p. 44 |
| Porous Metal Organic Frameworks | p. 46 |
| Mesoporous Solids | p. 60 |
| Hypothetical Networks | p. 66 |
| Hypothetical Zeolites | p. 67 |
| Nets and MOFs | p. 68 |
| Summary | p. 71 |
| References | p. 71 |
| Structure Determination: Experimental Techniques | |
| Introduction | p. 79 |
| Diffraction-based Methods | p. 80 |
| Single Crystal Diffraction | p. 81 |
| X-ray and Neutron Powder Diffraction | p. 83 |
| Electron Diffraction and Transmission Electron Microscopy | p. 95 |
| Structural Studies of Mesoporous Solids | p. 99 |
| 3D TEM-Electron Tomography | p. 103 |
| Scanning Electron Microscopy and Scanning Probe Microscopy | p. 106 |
| Spectroscopic Methods in Structural Studies | p. 108 |
| Solid State NMR Spectroscopy | p. 108 |
| X-ray Absorption Spectroscopy (XANES and EXAFS) | p. 131 |
| Vibrational Spectroscopy | p. 136 |
| Other Spectroscopies: UV-visible, Electron Spin Resonance | p. 138 |
| Summary | p. 139 |
| References | p. 141 |
| Computer Modelling | |
| Introduction and Definitions | p. 148 |
| Structure Simulation using Interatomic Potentials: Molecular Mechanics | p. 149 |
| Structural Simulation using Pair Potentials: Energy Calculation | p. 151 |
| Energy Minimisation and Simulated Annealing Techniques | p. 153 |
| Application of Monte Carlo Methods to Structure Simulation | p. 154 |
| Application of Pair-potential Methods to the Study of Surfaces | p. 154 |
| Structure Simulation using Quantum Mechanical Methods | p. 156 |
| Quantum Mechanical Methods | p. 156 |
| Density Functional Theory | p. 157 |
| Applications of Modelling to Structure Simulation | p. 158 |
| Structural Studies through Energy Minimisation | p. 158 |
| Bonding in Microporous Solids: Substitutional Behaviour | p. 159 |
| Organic and Inorganic Cation Sites: Monte Carlo/Simulated Annealing Approaches | p. 161 |
| Structure Simulation as an Aid to Structure Solution: Hypothetical Structures | p. 161 |
| Simulating Physisorption in Porous Solids | p. 164 |
| Monte Carlo Methods: Grand Canonical Monte Carlo (GCMC) | p. 166 |
| Configurational Bias GCMC Methods | p. 167 |
| Molecular Dynamics | p. 169 |
| Transition State Theory and Related Methods | p. 170 |
| Modelling Chemical Bonding and Reactivity | p. 172 |
| Nucleation and Crystal Growth | p. 172 |
| Chemisorption | p. 172 |
| Catalytic Activity | p. 174 |
| Summary | p. 175 |
| References | p. 176 |
| Synthesis | |
| Introduction | p. 180 |
| Principles of Hydrothermal Synthesis | p. 181 |
| Synthesis of Zeolites | p. 185 |
| Gel Formation | p. 185 |
| Crystallisation Curves and Sequences | p. 190 |
| The induction Period and Nucleation | p. 190 |
| Crystal Growth | p. 193 |
| Issues in Zeolite Synthesis | p. 197 |
| Role of the Structure-directing Agent: Designed 'Templates' | p. 197 |
| The Fluoride Route | p. 201 |
| Incorporation of Aluminium and Other Heteroatoms | p. 202 |
| Modifying Crystallite Size: Nano- and Giant Zeolite Crystals | p. 205 |
| Synthesis of Other Microporous Solids | p. 207 |
| Aluminium and Other Metal Phosphates | p. 207 |
| Metal-organic Frameworks | p. 211 |
| High-throughput Synthesis | p. 212 |
| Synthesis of Ordered Mesoporous Solids | p. 212 |
| A General Synthesis Pathway to Mesoporous Solids | p. 212 |
| Mechanisms of Silicate Mesophase Formation from Aqueous Solution | p. 215 |
| True Liquid Crystal Templating and Evaporation-induced Mesostructure Formation: Non-silica Mesoporous Solids | p. 218 |
| Summary | p. 218 |
| References | p. 220 |
| The Chemistry of Microporous Framework Solids | |
| Introduction | p. 226 |
| Stability and Post-synthetic Modification | p. 226 |
| Thermal Stability of the Framework | p. 226 |
| Chemical Conversions during Calcination | p. 229 |
| Dealumination and the Preparation of 'Ultrastable' Zeolite Y | p. 231 |
| Stability in Aqueous Solution | p. 235 |
| Post-synthetic Modification: Metallation and Pore-size Modification | p. 236 |
| Cation Exchange | p. 236 |
| Cation Exchange in Aqueous Solution | p. 236 |
| Solid State Ion Exchange and Intra-zeolite Cation Migration | p. 242 |
| Inclusion Chemistry | p. 243 |
| Alkali Metals in Zeolites | p. 244 |
| Sulfide Chromophores: The Ultramarine Family | p. 246 |
| Metal Chalcogenides and Other Inclusion Compounds | p. 246 |
| Inclusion of Complexes by MOCVD | p. 246 |
| Reduction and Oxidation Chemistry | p. 247 |
| Reduction of Extra-framework Transition Metal Cations | p. 247 |
| Redox Behaviour of Framework Transition Metal Cations | p. 248 |
| Intra-zeolitic Chemistry | p. 249 |
| Isolated Molecules and Arrays of Molecules | p. 249 |
| Chemistry of Mesoporous Solids | p. 251 |
| Hydrothermal Stability and Post-synthetic Functionalisation | p. 251 |
| Summary | p. 252 |
| References | p. 253 |
| Adsorption and Diffusion | |
| Introduction and Definitions | p. 257 |
| Introduction | p. 257 |
| Definitions | p. 258 |
| Theory and Methods for the Study of Adsorption | p. 264 |
| Adsorption Isotherms | p. 264 |
| Thermodynamics: Microcalorimetry and Thermal Desorption | p. 270 |
| Molecular Motion of Adsorbates | p. 273 |
| Adsorption Sites and Adsorbate-solid Complexes: Vibrational Spectroscopy, NMR and Diffraction | p. 276 |
| Computer Simulation of Adsorption: General Lessons | p. 279 |
| Adsorption Sites and Interactions with Adsorbates | p. 280 |
| Neutral Frameworks | p. 280 |
| Extra-framework Cations | p. 286 |
| Structural Hydroxyls | p. 290 |
| Framework Lewis Acid Sites | p. 291 |
| Basic Sites | p. 293 |
| Metal-Organic Frameworks | p. 294 |
| Diffusion | p. 295 |
| Introduction: Self-diffusion and Transport Diffusion | p. 295 |
| Experimental Methods and Simulations | p. 297 |
| Examples | p. 299 |
| Applications of Adsorption | p. 300 |
| Drying and Impurity Removal | p. 301 |
| Air Separation | p. 302 |
| Hydrocarbon Adsorption and Separation | p. 303 |
| True Molecular Sieving for Small Molecules | p. 304 |
| Summary | p. 305 |
| References | p. 306 |
| Microporous Solid Acid Catalysts and their Applications | |
| Introduction | p. 312 |
| The Chemistry of Acid Catalysis | p. 313 |
| General Features of Solid Acids | p. 317 |
| Acid Site Type, Concentration and Strength | p. 317 |
| Microporous Solids as Acid Catalysts | p. 319 |
| The Competitors: Other Classes of Solid Acids | p. 321 |
| Measurement of Acid Site Concentration and Strength in Microporous Solids | p. 322 |
| Direct Observation of Bronsted Acid Sites | p. 323 |
| Interaction of Bronsted Acid Sites with Probe Molecules | p. 324 |
| Acid Catalysis: Activity Measurement by Catalytic Test Reaction | p. 333 |
| Mechanisms of Acid Catalysed Reactions from in situ NMR and Quantum Mechanical Calculations | p. 335 |
| Trends in Performance of Microporous Solid Acids | p. 338 |
| The Role of Chemical Composition | p. 339 |
| The Role of Local Framework Structure | p. 340 |
| The Role of Lewis Acidity | p. 340 |
| The Role of Pore Structure: The Origin of Shape Selectivity | p. 341 |
| Catalytic Test Reactions: Information on Pore Geometry | p. 344 |
| Reactions over Microporous Solid Acids | p. 347 |
| Acid Catalysis with Reactants that Contain Heteroatoms | p. 349 |
| Hydrocarbon Conversions | p. 356 |
| Bifunctional Catalysis | p. 364 |
| Limitations of Microporous Solid Acid Catalysts | p. 365 |
| Summary | p. 366 |
| References | p. 367 |
| Further Catalytic Applications of Microporous Solids | |
| Introduction | p. 372 |
| Framework Lewis Acids as Selective Oxidation Catalysts | p. 373 |
| Selective Oxidation over Titanosilicates | p. 373 |
| Sn-Beta: a Versatile Catalyst for Baeyer-Villiger Oxidations and Meerwein-Ponndorf-Verley-Oppenauer Conversions | p. 381 |
| Selective Oxidations over AlPO[subscript 4]s Containing Redox-active Framework Cations | p. 383 |
| Catalysis over Extra-framework Metal Species | p. 387 |
| Transformation of Light Hydrocarbons into Aromatics | p. 388 |
| Catalytic Removal of NO[subscript x] Species from Auto-exhaust and Power Plant Emissions | p. 389 |
| Selective Oxidation with N[subscript 2]O over Fe-zeolites | p. 391 |
| Palladium-containing Zeolites for C-C Bond Formation | p. 392 |
| Base Catalysis | p. 392 |
| Supported Metal Complexes in Porous Solids | p. 395 |
| Ship-in-a-bottle Type Catalysts in Zeolitic Solids | p. 395 |
| Summary | p. 399 |
| References | p. 399 |
| Advanced Applications and Current Trends | |
| Introduction | p. 403 |
| Fabricating Porous Solids for Developing Applications | p. 404 |
| Zeolite Membranes | p. 404 |
| Thin films and Low Dielectric Constant Materials | p. 407 |
| Hierarchical Porosity | p. 408 |
| Using Ordered Porous Solids as Hosts in Functional Materials | p. 410 |
| Applications in Medicine: MRI Contrast Agents and Drug Delivery Agents | p. 410 |
| Optical and Electronic Properties | p. 411 |
| Gas Storage and Polymerisation in Responsive Metal-organic Frameworks | p. 412 |
| Summary and Final Remarks | p. 414 |
| References | p. 415 |
| Subject Index | p. 417 |
| Table of Contents provided by Ingram. All Rights Reserved. |
ISBN: 9780854048120
ISBN-10: 085404812X
Series: RSC Materials Monographs
Published: 15th October 2007
Format: Hardcover
Language: English
Number of Pages: 444
Audience: Professional and Scholarly
Publisher: Royal Society Of Chemistry
Country of Publication: GB
Dimensions (cm): 24.0 x 16.5 x 3.2
Weight (kg): 0.83
Shipping
| Standard Shipping | Express Shipping | |
|---|---|---|
| Metro postcodes: | $9.99 | $14.95 |
| Regional postcodes: | $9.99 | $14.95 |
| Rural postcodes: | $9.99 | $14.95 |
Orders over $79.00 qualify for free shipping.
How to return your order
At Booktopia, we offer hassle-free returns in accordance with our returns policy. If you wish to return an item, please get in touch with Booktopia Customer Care.
Additional postage charges may be applicable.
Defective items
If there is a problem with any of the items received for your order then the Booktopia Customer Care team is ready to assist you.
For more info please visit our Help Centre.
You Can Find This Book In

Frontiers Of Solid State Chemistry, Proceedings Of The International Symposium On Solid State Chemistry In China
Hardcover
RRP $419.99
$377.99
OFF























