
Evolution's Destiny
Co-evolving Chemistry of the Environment and Life
By: R J P Williams, Ros Rickaby
Hardcover | 25 January 2012
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344 Pages
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This book is written as an addition to Darwin's work and that of molecular biologists on evolution so as to include views of it from the point of view of chemistry rather than just from our knowledge of the biology and genes of organisms. By concentrating on a wide range of chemical elements, not just those in traditional organic compounds, we show that there is a close relationship between the geological or environmental chemical changes from the formation of Earth and those of organisms from the time of their origin. These are considerations which Darwin or other scientists could not have explored until very recent times since sufficient analytical data were not available. They lead us to suggest that there is a combined geo- and bio-chemical evolution, that of an ecosystem, which has had a systematic chemical development. In this development the arrival of new very similar species is shown to be by random Darwinian competitive selection processes such that a huge variety of species coexist with only minor differences in chemistry and advantages. This is in agreement with previous studies. On the large scale of evolution of very different organisms, and over greater timescales, by way of contrast, we observe that groups of species have special, different, chemical features and function. It is more difficult to understand how they evolved and therefore we examine their chemical development in detail. Overall there is a cooperative evolution of a chemical system driven by capture of energy, mainly from the sun, and its degradation in which the chemistry of both the environment and organisms are facilitating intermediates. We shall suggest that the overall drive of the whole joint system is to optimise the rate of this energy degradation. Since the environmental changes are inorganic and relatively fast they move inevitably to equilibrium. The living part of the system, the organisms, under the influence of this inevitable environmental change are forced to follow but as they are increasingly energised and their reactions are slow, they move further away from equilibrium. We are able to explore the ways in which this chemical system evolved, recognising that as complexity of the chemistry of organisms increased, they had to be formed from more and more compartments and to become part of a chemically cooperative overall activity. They could not remain as isolated species. Only in the last chapter do we attempt to make a connection between the changing chemistry of organisms with the coded molecules of each cell which have to exist to explain reproduction.
Evolution's Destiny describes how biology and geochemistry have continually influenced each other in the co-evolution of the Earth and all life. Anyone with an interest in evolution, the environment, or natural history will find this a fascinating and inspiring read.Industry Reviews
| Glossary | p. xv |
| Abbreviations | p. xix |
| About the Authors | p. xxi |
| Outline of the Main Chemical Factors in Evolution | |
| Introduction to the Chemistry of the Ecosystem | p. 1 |
| The Involvement of the Elements in Evolution | p. 4 |
| Equilibrium and Steady State Conditions | p. 10 |
| Solubility | p. 14 |
| Complex Ion Formation | p. 15 |
| Standard Oxidation/Reduction Potentials | p. 17 |
| Rate Controls and Catalysis | p. 20 |
| The Dangers of Catalysis | p. 26 |
| Diffusion | p. 27 |
| Irreversibility, Chaos and Predictability | p. 28 |
| Summary | p. 29 |
| References | p. 31 |
| Geological Evolution with Some Biological Intervention | |
| Introduction | p. 32 |
| Physical Evolution from the Earliest Times to Today | p. 33 |
| The Value of Isotope Studies: Indicators of Chemical Changes and Geochemical Dates | p. 39 |
| The Early Chemical Development of the Environment before 3.0 Ga | p. 40 |
| Energy Capture and Surface Geochemical Changes: The Beginning of Organic Chemistry and Oxygen in the Atmosphere | p. 42 |
| The Environment after 3.0 Ga: Revolution in Redox Chemistry before 0.54 Ga | p. 45 |
| Sulfur Isotope Fractionation from 3.5 to 0.5 Ga; Dominance of Iron/Sulfur Buffering | p. 48 |
| Evolving Mineral outputs from the Ocean: Further Evidence for Redox Chemistry before 0.54 Ga | p. 49 |
| Banded Iron Formations and the State of Iron in Solution | p. 49 |
| Uranium and Thorium Minerals | p. 49 |
| Quantitative Analysis of Oxidation Conditions | p. 50 |
| Geochemical Changes of Trace Elements | p. 52 |
| Rare Earth Probes of the Environment | p. 52 |
| Trace Transition Metals in the Sea | p. 54 |
| The Non-Uniform Sea | p. 57 |
| Summary of Weathering from 3.5 Ga to 0.75 Ga | p. 58 |
| Weathering and Chemical Conditions from 0.75 Ga | p. 60 |
| Changes in Major Non-Redox Mineral Elements in the Sea from 0.54 Ga | p. 63 |
| Carbon Isotopes | p. 65 |
| Oxygen Isotopes | p. 66 |
| Summary of Geological 'Inorganic' Chemistry Evolution | p. 67 |
| A Note: The Relationship between Metal Structures in Organisms, Minerals and Chemicals Models | p. 70 |
| References | p. 71 |
| Organism Development from the Fossil Record and the Chemistry of the Nature of Biominerals | |
| Introduction | p. 73 |
| The Fossil Record | p. 75 |
| Extinctions | p. 82 |
| Types of Biominerals | p. 84 |
| The Chemistry of Biominerals: The Handling of Inorganic Elements | p. 87 |
| The Chemistry of Biominerals: Organic Components, Composites | p. 89 |
| Shape of Organisms and Biominerals and Genetics | p. 91 |
| Induced and Controlled Biomineralisation and Genetics | p. 92 |
| Molecular Fossils | p. 94 |
| Carbon and Carbon/Hydrogen Deposits | p. 94 |
| Sulfur Deposits | p. 96 |
| Conclusions | p. 96 |
| Note | p. 98 |
| References | p. 98 |
| Cells: Their Basic Organic Chemistry and their Environment | |
| Introduction | p. 100 |
| The Proposed Beginnings of Life: Anaerobic Prokaryotes | p. 104 |
| Energy Transduction and use | p. 105 |
| Major Features of the Original Anaerobic Organic Chemistry | p. 110 |
| The Genome and the Proteome: Concentration Terms and Controls of Expression | p. 115 |
| Differences between Anaerobic Cell Types | p. 119 |
| Internal Structure of Prokaryotes and Production of New Proteins | p. 120 |
| Prokaryote Cell Walls and Membranes | p. 121 |
| The Essence of the Chemistry of Anaerobic Life | p. 122 |
| A Note on Prokaryote Diversity | p. 125 |
| Resources and the Coming of Oxygen: Micro-Aerobic and Aerobic Prokaryotes | p. 125 |
| The Single-Cell Eukaryotes | p. 130 |
| The Eukaryote Cell Nucleus | p. 135 |
| Filaments in Single-Cell Eukaryotes | p. 137 |
| Vesicles in Single-Cell Eukaryotes | p. 137 |
| Protection in Single-Cell Eukaryotes | p. 138 |
| Genetic Analysis of Unicellular Eukaryotes: Algae and Metazoans | p. 139 |
| Summary of the Evolution of Unicellular Eukaryotes | p. 141 |
| The Multicellular Eukaryotes | p. 142 |
| The Evolution of the Divisions in Space in Multicellular Organisms | p. 146 |
| Control of Growth and Shapes | p. 147 |
| Building Larger Structures: Internal and Extracellular Tissue Proteins | p. 148 |
| The Evolution of Biominerals and their Associated Structures | p. 151 |
| Extracellular Fluids | p. 152 |
| Signalling with Organic Molecules and Electrolytic Gradients in Multicellular Eukaryotes | p. 153 |
| Genetic Analysis of Multicellular Animals | p. 155 |
| Loss of Genes and Organism Collaboration: Internal and External Symbiosis | p. 156 |
| Summary of the Distinctive Features of Biological Organic Chemistry | p. 157 |
| References | p. 163 |
| Other Major Elements in Organism Evolution | |
| Introduction | p. 166 |
| Phosphorus in Cells | p. 168 |
| Sulfur in Cells | p. 171 |
| An Introduction to Magnesium, Calcium and Silicon Chemistry in Organisms | p. 173 |
| Magnesium in Cells | p. 174 |
| Calcium in Organisms | p. 175 |
| Introduction to Signalling | p. 177 |
| Detailed Calcium Protein Signalling and its Evolution in Eukaryotes | p. 180 |
| Weaker Binding Sites in Vesicles | p. 187 |
| Sodium/Potassium Messages | p. 188 |
| The Evolution of Biominerals | p. 193 |
| Calcium and Phosphates: Apatite | p. 195 |
| Silica | p. 196 |
| The Nature of the Matrices Supporting Mineralisation: Summary | p. 198 |
| Conclusions | p. 199 |
| References | p. 201 |
| Trace Elements in the Evolution of Organisms and the Ecosystem | |
| Introduction | p. 203 |
| The Chemistry of the Trace Elements | |
| The Availability of the Trace Elements | p. 208 |
| The Principles of Binding and Transfer of Trace Elements in Cells | p. 211 |
| The Importance of Quantitative Binding Strengths and Exchange in Cells | p. 213 |
| Examples of the Thermodynamic and Kinetic Limitations on Uptake of Metal Ions | p. 221 |
| The Evolution of the Metalloproteins, the Metallosomes and their Functional Value | |
| Introduction | p. 223 |
| The Evolution of the Metalloproteins of Prokaryotes | p. 224 |
| The Evolution of the Metalloproteins of Eukaryotes | p. 227 |
| Survey of the Evolving uses of Trace Elements | p. 230 |
| Effects of Metal Ion Limitations and Excesses on Growth | p. 241 |
| The Value of Zinc and Cadmium: 'Carbonic Anhydrases' | p. 242 |
| The Special Case of Two Non-Metals: Selenium and Iodine | p. 243 |
| Conclusions | p. 244 |
| References | p. 248 |
| The Amalgamation of the Chemical and the Genetic Approaches to Evolution | |
| A Summary of the Chemical Approach | |
| Introduction | p. 251 |
| The Reasons for the Conditions of Earth Before Life Began and its Evolution: Equilibrium, Thermodynamics and Kinetic Limitations | p. 254 |
| The Reasons for the Evolution of Organic Chemistry before Life Began: Kinetic and Energy Controls | p. 257 |
| The Direct and Indirect, Deduced, Evidence for Evolution of the System: Environment and Organisms | p. 261 |
| Anaerobic Cellular Chemistry to 3.0 Ga | p. 263 |
| The Oxidation of the System | p. 264 |
| Summary of the Evolution of the Oxidative Chemistry of the Elements | p. 266 |
| Summary of Why the Chemistry of the Environment/Organism System Arose and Evolved | p. 270 |
| Added Note on a Novel Genetic Analysis Related to Chemical Development | p. 273 |
| The Connections Between the Chemical, the Biological and the Genetic Approaches to Evolution | |
| The Nature of Genes: Gains and Losses of Genes and Inheritance | p. 274 |
| DNA Gene Duplication: A Possible Resolution of the Problem of Gene/Environment Interaction | p. 282 |
| Epigenetics and the Mechanism of Duplication | p. 286 |
| The Definition of Species and Symbiosis | p. 288 |
| Concluding Perspectives | |
| Final Summary of Chemical Evolution with Reproduction | p. 289 |
| The Chemical System and Mankind Today and its Future | p. 299 |
| A Note on Gaia | p. 303 |
| References | p. 305 |
| Subject Index | p. 308 |
| Table of Contents provided by Ingram. All Rights Reserved. |
ISBN: 9781849735582
ISBN-10: 1849735581
Published: 25th January 2012
Format: Hardcover
Number of Pages: 344
Audience: College, Tertiary and University
Publisher: Royal Society Of Chemistry
Country of Publication: GB
Dimensions (cm): 23.7 x 16.2 x 2.4
Weight (kg): 0.78
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