
Advanced Physicochemical Treatment Processes
By: Lawrence K. Wang (Editor), Yung-Tse Hung (Editor), Nazih K. Shammas (Editor)
Hardcover | 23 August 2006
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712 Pages
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| Preface | p. v |
| Contributors | p. xix |
| Potable Water Aeration | p. 1 |
| Introduction | p. 1 |
| Types of Aeration Process | p. 1 |
| Applications | p. 2 |
| Taste and Odor Removal | p. 2 |
| Iron and Manganese Oxidation | p. 2 |
| Hydrogen Sulfide and Carbon Dioxide Removal | p. 3 |
| Ammonia Removal | p. 4 |
| Aesthetic or Decorative Aeration | p. 4 |
| Reservoir De-stratification and Oxygenation of Water | p. 4 |
| Dissolved Air Flotation for Flocculation/Flotation | p. 5 |
| Trihalomethanes Removal | p. 5 |
| Volatile Organics Removal | p. 5 |
| Hazardous Waste Cleanup | p. 5 |
| Radionuclides Removal | p. 6 |
| Unit Processes for Organic Contaminant Removal | p. 6 |
| Packed Column Aeration | p. 10 |
| System Design Considerations | p. 20 |
| Additional System Design Considerations | p. 24 |
| PTA Pilot Testing for VOC Removal | p. 26 |
| Other Types of Tower | p. 29 |
| Diffused Aeration | p. 33 |
| Design Criteria | p. 34 |
| Mechanical Aeration | p. 35 |
| System Performance | p. 35 |
| System Costs | p. 36 |
| Case Study of Packed Tower Aeration | p. 40 |
| Scottsdale, AZ | p. 40 |
| Naples, FL | p. 40 |
| Nomenclature | p. 44 |
| References | p. 44 |
| Air Stripping | p. 47 |
| Introduction | p. 47 |
| Henry's Law and the Mass-Transfer Coefficient | p. 48 |
| Analytical Requirements for an Air-Stripping Program | p. 49 |
| Features and Designs | p. 50 |
| Features of the Countercurrent Air Stripper | p. 50 |
| Air-Stripper Design Parameters | p. 50 |
| Packing Material | p. 54 |
| Pilot Studies | p. 55 |
| Ammonia Stripping | p. 58 |
| Water Quality Problems | p. 69 |
| Off-Gas Emissions | p. 70 |
| Capital and Operational Cost Analysis | p. 71 |
| Minimizing Power Costs | p. 71 |
| Comparisons of Capital and Operational Costs | p. 72 |
| Recent Advancements | p. 74 |
| Conclusions | p. 75 |
| Nomenclature | p. 77 |
| References | p. 78 |
| Adsorptive Bubble Separation and Dispersed Air Flotation | p. 81 |
| Introduction | p. 81 |
| General Description | p. 81 |
| Adsorptive Bubble Separation | p. 82 |
| Bubble Separation Process Descriptions and Definitions Based on the Techniques Used for Bubble Generation | p. 85 |
| Dissolved Air Flotation | p. 85 |
| Dispersed Air Flotation | p. 85 |
| Vacuum Flotation | p. 85 |
| Electrolytic Flotation | p. 87 |
| Biological Flotation | p. 87 |
| Deep-Shaft Flotation | p. 88 |
| Bubble Separation Process Descriptions and Definitions According to the Techniques Used for Solids Separation | p. 88 |
| Foam Separation | p. 88 |
| Nonfoaming Adsorptive Bubble Separation | p. 91 |
| Bubble Separation Process Descriptions and Definitions According to the Operational Modes | p. 93 |
| Continuous Adsorption Bubble Separation | p. 93 |
| Sequencing Batch Reactor Adsorptive Bubble Separation | p. 93 |
| Surface Adsorption | p. 93 |
| Bubble Phenomena | p. 96 |
| Multiphase Flow | p. 97 |
| Material Balances | p. 98 |
| Foam Separation by Dispersed Air Flotation Cell | p. 100 |
| Chemical Reagents for Adsorptive Bubble Separation | p. 105 |
| Laboratory Foam Separation Tests | p. 106 |
| Sequencing Batch Reactor Foam Separation | p. 106 |
| Continuous Foam Separation | p. 106 |
| Engineering Applications | p. 107 |
| De-inking Process for Waste Paper Purification and Recycle | p. 107 |
| Flotation Process for Calcium Carbonate Recovery from Water Treatment Sludges | p. 110 |
| Analytical Methods Available for Process Monitoring | p. 112 |
| Glossary | p. 112 |
| Nomenclature | p. 114 |
| References | p. 116 |
| Powdered Activated Carbon Adsorption | p. 123 |
| Introduction | p. 123 |
| Properties of Activated Carbon | p. 125 |
| Adsorption Isotherm Models | p. 127 |
| Design Consideration of PAC Systems | p. 131 |
| Design Considerations | p. 131 |
| Laboratory Procedures for Batch Adsorption Study | p. 133 |
| Regeneration | p. 133 |
| Factors Affecting Performance | p. 134 |
| Variables for the Combined Activated Carbon-Activated Sludge Process | p. 134 |
| Factors Affecting Adsorption | p. 135 |
| Performance and Case Studies | p. 136 |
| Economics of Powdered Activated Carbon System | p. 138 |
| Design Examples | p. 138 |
| Example 1 (Langmuir and Freundlich Isotherms Constants) | p. 138 |
| Example 2 (Powdered Activated Carbon Adsorption Tests) | p. 142 |
| Example 3 (Design and Applications of Physicochemical PAC Process Systems) | p. 146 |
| Example 4 (Design and Applications of Combined Biological and Physicochemical PAC Process Systems) | p. 148 |
| Nomenclature | p. 150 |
| References | p. 151 |
| Diatomaceous Earth Precoat Filtration | p. 155 |
| Introduction | p. 155 |
| Process Description | p. 156 |
| Diatomaceous Earth | p. 156 |
| Diatomaceous Earth Filtration and Filter Aid | p. 156 |
| Diatomaceous Earth Filtration System Design | p. 163 |
| Diatomaceous Earth Filtration System Operation | p. 163 |
| Precoating Operation | p. 163 |
| Filtration Operation | p. 164 |
| Filter Cake Removal | p. 167 |
| Diatomaceous Earth Filtration System Maintenance | p. 168 |
| Types of Precoat Filters | p. 169 |
| Plate and Frame Filters | p. 169 |
| Tubular Filters | p. 170 |
| Vertical Tank-Vertical Leaf Filters | p. 170 |
| Horizontal Tank-Vertical Leaf (""H"" Style) Filters | p. 171 |
| Rotating Leaf Filters | p. 171 |
| Horizontal Leaf Filters | p. 173 |
| Specialty Filters | p. 173 |
| Vacuum Leaf Filters | p. 173 |
| Rotary Vacuum Precoat Filters | p. 174 |
| Auxiliary Parts and Equipment | p. 176 |
| Precoat Filter Leaves | p. 176 |
| Filter Feed Pumps | p. 177 |
| Precoat and Body Feed Tanks | p. 177 |
| Body Feed Systems | p. 177 |
| Automation Equipment | p. 178 |
| Bulk Filter Aid Handling | p. 178 |
| Precoat Filtration Applications, Advantages, and Disadvantages | p. 179 |
| Municipal and Military Applications | p. 179 |
| Industrial Applications | p. 180 |
| Advantages and Disadvantages | p. 182 |
| Summary | p. 183 |
| Glossary of Diatomaceous Earth Filtration (Precoat Filtration) | p. 184 |
| Acknowledgments | p. 187 |
| References | p. 188 |
| Tertiary Microscreening | p. 191 |
| Introduction | p. 191 |
| Microscreening Process | p. 192 |
| Design Criteria | p. 192 |
| Backwashing | p. 195 |
| Design of Microscreens | p. 196 |
| Input Data | p. 196 |
| Design Parameters | p. 196 |
| Design Procedure | p. 196 |
| Output Data | p. 197 |
| Energy and Costs | p. 197 |
| Design Example | p. 197 |
| Nomenclature | p. 200 |
| References | p. 200 |
| Appendix | p. 202 |
| Membrane Filtration | p. 203 |
| Introduction | p. 203 |
| Membrane and Membrane-Separation Processes for Water Treatment | p. 204 |
| Basics of Membrane and Membrane-Separation Systems | p. 204 |
| Membrane-Separation Processes for Water Treatment | p. 205 |
| Case Studies on Membrane Applications in Water Treatment | p. 213 |
| Membrane Materials: Preparation and Modification | p. 216 |
| Membrane Materials | p. 216 |
| Types of Membrane and Their Formation | p. 216 |
| Membrane Characterization | p. 220 |
| Porous Membrane | p. 220 |
| Nonporous Membrane | p. 220 |
| Mass Transport in Membranes | p. 221 |
| The Solution-Diffusion Model | p. 222 |
| The Pore Model | p. 226 |
| Membrane Module and Process Design | p. 228 |
| Introduction | p. 228 |
| Typical Membrane Modules | p. 228 |
| Design Considerations | p. 232 |
| Engineering Design | p. 236 |
| Membrane Testing | p. 240 |
| Economics of Membrane Processes | p. 241 |
| Membrane Fouling and Prevention | p. 242 |
| Mechanisms | p. 242 |
| Feed Pretreatment | p. 244 |
| Membrane Cleaning and Flux Restoration | p. 248 |
| Chemical Cleaning Methods | p. 248 |
| Physical Cleaning Methods | p. 251 |
| Summary | p. 252 |
| Acknowledgment | p. 252 |
| Abbreviations | p. 252 |
| Nomenclature | p. 253 |
| References | p. 255 |
| Ion Exchange | p. 261 |
| Introduction | p. 261 |
| Characterization of Ion Exchangers | p. 263 |
| Physical Properties | p. 263 |
| Chemical Properties | p. 265 |
| Ion-Exchange Calculations | p. 271 |
| Equilibrium | p. 272 |
| Kinetics | p. 277 |
| Fixed-Bed Operation | p. 278 |
| Applications | p. 279 |
| Water Softening | p. 280 |
| Deionization nd High-Quality Water Supply | p. 281 |
| Removal and Recovery of Heavy Metals | p. 283 |
| Removal of Nitrogen | p. 284 |
| Removal of Phosphorous | p. 285 |
| Organic-Chemical Removal | p. 286 |
| Operations | p. 289 |
| Nomenclature | p. 289 |
| References | p. 290 |
| Fluoridation and Defluoridation | p. 293 |
| Introduction | p. 293 |
| Natural Fluoridation | p. 296 |
| Controlled Fluoridation | p. 298 |
| Dry Feeders | p. 299 |
| Example of Dry Feeders | p. 300 |
| Checking Particle Size | p. 300 |
| Example of Sieve Analysis | p. 301 |
| Feeding System | p. 301 |
| Meters | p. 302 |
| Auxiliary Equipment | p. 302 |
| Saturators | p. 305 |
| Downflow Saturators | p. 306 |
| Upflow Saturators | p. 309 |
| Common Operational Problems in Preparation of Fluoride Solution | p. 310 |
| Calculations Involving Solutions | p. 311 |
| Example 1 | p. 311 |
| Example 2 | p. 311 |
| Example 3 | p. 312 |
| Example 4 | p. 313 |
| Defluoridation | p. 314 |
| References | p. 314 |
| Ultraviolet Radiation for Disinfection | p. 317 |
| Introduction | p. 317 |
| Historical Background and Technology Development | p. 317 |
| UV Radiation Process Description | p. 320 |
| Pathogens in the Environment | p. 321 |
| Disinfection Mechanisms | p. 322 |
| Chemistry of DNA and RNA | p. 323 |
| Physical Properties of UV Light | p. 324 |
| Inactivation of Pathogens | p. 325 |
| Reactivation of Pathogens | p. 327 |
| Mathematical Description of UV Disinfection Process | p. 328 |
| UV Dose | p. 328 |
| Effect of UV Dose on Pathogen Inactivation | p. 330 |
| Collimated Beam Test | p. 332 |
| Design of UV Unit for Aqueous-Phase Disinfection | p. 336 |
| Empirical Design Approach | p. 336 |
| Probabilistic Design Approach | p. 339 |
| Model-Based Design Approach | p. 339 |
| Professional Engineering Design Approach | p. 340 |
| Applications of UV Unit for Aqueous-Phase Disinfection | p. 341 |
| Water Treatment | p. 343 |
| Wastewater Treatment | p. 347 |
| Environmental Protection | p. 348 |
| Operation and Maintenance of UV System in Aqueous Environments | p. 348 |
| UV Lamps | p. 348 |
| Operational Factors | p. 352 |
| Maintenance Factors | p. 353 |
| UV Disinfection By-Products and UV Lamp Disposal | p. 354 |
| UV Disinfection of Air Emissions | p. 355 |
| UV Engineering Case History and Applications | p. 357 |
| Engineering Case History | p. 357 |
| UV Engineering Applications | p. 358 |
| Nomenclature | p. 361 |
| References | p. 362 |
| Water Chloridation and Chloramination | p. 367 |
| Introduction | p. 367 |
| Chlorine | p. 368 |
| Monochloramine | p. 368 |
| Potable Water Chlorination | p. 369 |
| Surface Water Treatment Rules | p. 369 |
| Potable Water Chlorination Process Description | p. 370 |
| Design and Operation Considerations | p. 373 |
| Process Equipment and Control | p. 374 |
| Design Example | p. 379 |
| Potable Water Chloramination | p. 383 |
| Potable Water Chloramination Process Description | p. 383 |
| Design and Operation Considerations | p. 384 |
| Process Equipment and Control | p. 385 |
| Application Examples | p. 386 |
| Controlling Disinfection By-Products in Drinking Water | p. 387 |
| Strategies for Controlling Disinfection By-Products | p. 387 |
| Using Alternative Disinfectants | p. 388 |
| Minimizing Precursor Concentrations | p. 390 |
| References | p. 390 |
| Summary of Corrosion Indices | p. 393 |
| CT Values for Inactivation of Giardia and Viruses by Free Chlorine | p. 394 |
| CT Values for Inactivation of Viruses by Free Chlorine | p. 400 |
| CT Values for Inactivation of Giardia Cysts by Chloramine, pH 6-9 | p. 400 |
| CT Values for Inactivation of Viruses by Chloramine | p. 400 |
| On-Site Sodium Hypochlorite Generation System | p. 401 |
| Waste Chlorination and Stabilization | p. 403 |
| Introduction | p. 403 |
| Process Introduction | p. 403 |
| Glossary | p. 404 |
| Wastewater Chlorination | p. 405 |
| Process Description | p. 405 |
| Design and Operation Considerations | p. 406 |
| Process Equipment and Control | p. 409 |
| Design Example-Design of a Wastewater Chlorine Contact Chamber | p. 415 |
| Application Example-Coxsackie Sewage Treatment Plant, Coxsackie, NY, USA | p. 416 |
| Sludge Chlorination and Stabilization | p. 418 |
| Process Description | p. 418 |
| Design and Operation Considerations | p. 419 |
| Process Equipment and Control | p. 421 |
| Application Example-Coxsackie Sewage Treatment Plant, Coxsackie, NY, USA | p. 425 |
| Septic Chlorination and Stabilization | p. 433 |
| Process Description | p. 433 |
| Design and Operation Considerations | p. 434 |
| Process Equipment and Control | p. 435 |
| Design Criteria | p. 436 |
| Safety Considerations of Chlorination Processes | p. 436 |
| Nomenclature | p. 438 |
| Acknowledgments | p. 438 |
| References | p. 438 |
| Dechlorination | p. 441 |
| Background | p. 441 |
| Chlorination of Potable Waters | p. 441 |
| Release of Chlorinated Water and Concerns | p. 442 |
| Dechlorination of Water Releases | p. 442 |
| Non-chemical Methods for Chlorine Dissipation | p. 443 |
| Dechlorination Using Chemicals | p. 446 |
| Field Dechlorination Studies | p. 454 |
| Background | p. 454 |
| Field Dechlorination Tests at Tacoma Waters | p. 454 |
| Field Dechlorination Studies at Bureau of Water Works, Portland | p. 457 |
| Dechlorination Field Studies at EBMUD | p. 458 |
| Summary of Field Dechlorination Studies | p. 460 |
| Acknowledgments | p. 461 |
| References | p. 461 |
| Advanced Oxidation Processes | p. 463 |
| Introduction | p. 463 |
| Mechanisms and Theory | p. 464 |
| Chemical Oxidation | p. 464 |
| Radiation Methods | p. 465 |
| Combination Processes | p. 467 |
| Reaction Kinetics | p. 468 |
| Intermediates and By-Products | p. 469 |
| Process Parameters | p. 469 |
| Characteristics of Wastewater | p. 469 |
| Operating Conditions | p. 470 |
| Reactor Design | p. 471 |
| Reactor Models | p. 471 |
| Light Source | p. 473 |
| Reactor Configurations | p. 473 |
| Commercial Applications | p. 475 |
| Cost and Energy Efficiency of AOP | p. 475 |
| Limitations and Challenges of AOP | p. 476 |
| Recent R&D | p. 476 |
| Summary | p. 477 |
| Nomenclature | p. 478 |
| References | p. 479 |
| Chemical Reduction/Oxidation | p. 483 |
| Chemical Reduction | p. 483 |
| Process Description | p. 483 |
| Chemical Reduction Process Chemistry | p. 484 |
| Process Applications | p. 486 |
| Chemical Reduction Design Considerations | p. 487 |
| Design and Application Examples | p. 488 |
| Chemical Oxidation | p. 490 |
| Process Description | p. 490 |
| Process Chemicals | p. 491 |
| Process Applications | p. 493 |
| Chemical Oxidation Design Considerations | p. 494 |
| Design and Application Examples | p. 495 |
| Recent Developments | p. 501 |
| Liquid-Phase Chemical/Reduction System for Site Remediation | p. 501 |
| Gas-Phase Chemical Reduction Process for Site Remediation | p. 502 |
| References | p. 505 |
| Appendices | |
| Chemical Reduction and Clarification Used in Metal Finishing Industry | p. 509 |
| Chemical Reduction and Filtration Used in Metal Finishing Industry | p. 510 |
| Chemical Reduction and Clarification Used in Aluminum Forming Industry | p. 511 |
| Chemical Reduction and Filtration Used in Inorganic Chemical Industry | p. 512 |
| Chemical Oxidation (Chlorination) Used in Inorganic Chemical Industry (Sodium Bisulfite Manufacturing Industry) | p. 513 |
| Chemical Oxidation (Chlorination) Used in Inorganic Chemical Industry (Hydrogen Cyanide Manufacturing Industry) | p. 514 |
| Chemical Oxidation (Chlorination) Used in Ore Mining and Dressing Industry (Lead/Zinc Industry) | p. 515 |
| Chemical Oxidation (Chlorination) Used in Ore Mining and Dressing Industry (Ferroalloy Industry) | p. 516 |
| Chemical Oxidation (Chlorination) Used in Organic and Inorganic Wastes | p. 517 |
| Chemical Oxidation (Ozonation) Used in Textile Mills (Woven Fabric Finishing) | p. 518 |
| Chemical Oxidation (Ozonation) Used in Adhesive and Sealants Industry | p. 519 |
| Oil Water Separation | p. 521 |
| Introduction | p. 521 |
| Oil Properties | p. 523 |
| Treatment Technology | p. 524 |
| Process Selection | p. 524 |
| Primary Treatment System | p. 525 |
| Secondary Treatment System | p. 530 |
| Engineering Design | p. 537 |
| Gravity Flotation | p. 537 |
| Coalescing Plate Interceptor (CPI) | p. 539 |
| Dissolved Air Flotation (DAF) | p. 540 |
| Ultrafiltration Membrane | p. 541 |
| Design Examples and Questions | p. 543 |
| Example 1 | p. 543 |
| Example 2 | p. 543 |
| Example 3 | p. 544 |
| Nomenclature | p. 545 |
| References | p. 546 |
| Evaporation Processes | p. 549 |
| Introduction | p. 549 |
| Drying and Evaporation Processes | p. 549 |
| Natural Sludge Evaporation Lagoons and Evaporation Process Reactor | p. 550 |
| Sludge Evaporation Lagoons (Sludge Drying Lagoons) | p. 551 |
| Process Description | p. 551 |
| Process Applications and Limitations | p. 552 |
| Design Considerations | p. 553 |
| Costs | p. 555 |
| Evaporators | p. 556 |
| Process Description | p. 556 |
| Process Applications and Limitations | p. 559 |
| Design Considerations | p. 559 |
| Design Examples | p. 563 |
| Example 1 | p. 563 |
| Example 2 | p. 564 |
| Example 3 | p. 565 |
| Example 4 | p. 566 |
| Example 5 | p. 566 |
| Example 6 | p. 567 |
| Example 7 | p. 567 |
| Example 8 | p. 567 |
| Example 9 | p. 570 |
| Example 10 | p. 570 |
| Nomenclature | p. 575 |
| References | p. 576 |
| Appendix | p. 579 |
| Solvent Extraction, Leaching, and Supercritical Extraction | p. 581 |
| Introduction | p. 581 |
| General Applications | p. 582 |
| Process Description | p. 582 |
| The Extractor or Extraction Step | p. 582 |
| Solvent Recovery | p. 582 |
| Technology Status and Reliability | p. 583 |
| Equipment Types and Modifications | p. 584 |
| Chemicals Required | p. 584 |
| Residuals Generated | p. 584 |
| Applications | p. 584 |
| Advantages and Limitations | p. 585 |
| Cost | p. 585 |
| Design Criteria | p. 586 |
| Part 1-Equilibrium Conditions | p. 586 |
| Estimating Korg/w Values | p. 587 |
| Environmental Factors Affecting Organic Liquid/Water Distribution Coefficients | p. 591 |
| Part 2-Governing Equations and Relationships | p. 591 |
| Type 2 Liquid/Liquid Extraction | p. 594 |
| Leaching | p. 595 |
| Solubility and Mass-Transfer Factors | p. 595 |
| Equipment and Applications | p. 597 |
| Extraction and Destruction of Hazardous Materials by Supercritical Fluids | p. 598 |
| Principles | p. 599 |
| Applications | p. 601 |
| Example Problems | p. 602 |
| Example 1-Preliminary Design of the Minimum Solvent Flow Rate and Number of Extraction Stages | p. 602 |
| Example 2-Extraction of Phenol with Caustic Water Recovery | p. 603 |
| Example 3-Selecting an Extraction Solvent | p. 609 |
| Example 4-Performance of Solvent Extraction | p. 610 |
| Nomenclature | p. 611 |
| References | p. 613 |
| Appendix: Conversion Factors for Environmental Engineers | p. 615 |
| Constants and Conversion Factors | p. 617 |
| Basic and Supplementary Units | p. 673 |
| Derived Units and Quantities | p. 674 |
| Physical Constants | p. 676 |
| Properties of Water | p. 677 |
| Periodic Table of the Elements | p. 678 |
| Index | p. 679 |
| Table of Contents provided by Publisher. All Rights Reserved. |
ISBN: 9781588293619
ISBN-10: 1588293610
Series: Handbook of Environmental Engineering : Book 4
Published: 23rd August 2006
Format: Hardcover
Language: English
Number of Pages: 712
Audience: Professional and Scholarly
Publisher: Springer Nature B.V.
Country of Publication: US
Dimensions (cm): 26.04 x 17.78 x 3.18
Weight (kg): 1.42
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- Non-FictionEngineering & TechnologyEnvironmental ScienceSanitary & Municipal EngineeringWater Supply & Treatment
- Non-FictionEngineering & TechnologyMechanical Engineering & MaterialsMaterials ScienceMechanics of FluidsHydraulics & Pneumatics
- Non-FictionEngineering & TechnologyEnvironmental SciencePollution Control
- Non-FictionEarth Sciences, Geography, Environment, PlanningThe Environment
























