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ZEKE Spectroscopy - E.W. Schlag

ZEKE Spectroscopy

Hardcover

Published: 13th June 1998
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Since 1984, ZEKE (ZEro Kinetic Energy) spectroscopy has matured into a very high resolution spectroscopy for the study of cations, anions, and indirectly through these species, neutrals--including very short lived intermediates in chemical rections. It has even yielded the first direct spectroscopic data on elusive transition states of chemical reactions. This is the first book to describe ZEKE spectroscopy, a new high resolution spectroscopy of molecular ions, neutral short-lived intermediates, and other species. The author's approach is to use a minimum of equations and large numbers of figures to help the reader toward a basic understanding of the many unique concepts of this new form of spectroscopy and the new spectroscopic information that it provides. This book will be of interest to anyone interested in the spectroscopy of ions or neutrals, particularly short-lived neutrals, formed from these ions. It should also be of interest to reaction kineticists interested in the study of reactions involving such highly state selected species.

'The book is very nicely written and the layout carefully made. The outlook is much better than in most of the newly edited books. It will be of interest to anyone working in the field of spectroscopy of ions or of neutral species, particularly short-lived neutral species. It should also be of interest to reaction kineticists interested in the study of reactions involving such highly state-selected species.' E. P. Nenner, Optik

Foreword
Introduction
Spectroscopy - a historical perspective
Mass analysis
Photoelectron spectroscopy
Threshold spectroscopy
Zero kinetic energy (ZEKE) spectroscopy - an introduction
Threshold ion detection
Basic application
Specific examples of ZEKE spectra in brief
Historical perspectives and principles
Delayed ionization
Mechanism
Ionization potentials for ZEKE spectra
Ion detection in ZEKE spectra
High resolution - benzene
Magnetic field effects
Anion and neutral mass selected spectra
Short lived states
Applications - state selection
Channel interactions and selection rules
Mixing of states by fields
Field effects on the ionization potential
Intensity effects due to electric fields
Examples of systems studied
Lifetimes of ZEKE states at energies above the ionization potential
Concentration effects on ZEKE spectra
Summary
Epilogue
List of acronyms
ZEKE bibliography
Table of Contents provided by Publisher. All Rights Reserved.

ISBN: 9780521581288
ISBN-10: 0521581281
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 288
Published: 13th June 1998
Publisher: Cambridge University Press
Country of Publication: GB
Dimensions (cm): 24.7 x 17.4  x 1.7
Weight (kg): 0.66