Surface Properties of Layered Structures

By: Giorgio Benedek (Editor)

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Hardcover | 30 November 1992

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348 Pages

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23.39 x 15.6 x 2.06

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Layered crystals, characterized by a quasi-two-dimensional character of certain physical properties, play an interesting role in surface science. First of all they provide excellent inert substrates for epitaxial deposition and physisorption studies. The surfaces of layered crystals, however, are interesting in their own right because they make a relevant class of low-dimensional phenomena accessible to surface probes. Change density waves, incommensurate structures, phonon anomalies and high T_c superconductivity are well known examples.
This book collects a series of review articles written by outstanding specialists on the structural assessment and spectroscopy of layered structures with surface-sensitive probes such as scanning microscopy and helium atom scattering, the theoretical analysis of their electronic and vibrational surface states, and the investigation of physisorbed overlayers.

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Preface
STM and AFM Studies of Layered Materials: General	p. 1
STM and AFM Studies of the surface properties of graphite	p. 5
STM and AFM studies of graphite intercalation compounds	p. 10
STM and AFM studies of compound layered materials	p. 15
STM and AFM of Layered Transition Metal Compounds	p. 27
Charge-density wave formation	p. 28
Experimental techniques	p. 30
STM and AFM of 1T phase layer structure crystals	p. 34
CDW defects	p. 60
Mechanisms for STM amplitude enhancement	p. 68
STM and AFM of 2H phase layer structure crystals	p. 71
4Hb phase transition metal dichalcogenides	p. 79
Spectroscopy of layer structure dichalcogenides	p. 83
Electronic Structure and Properties of Layered Structures	p. 97
Computational approach	p. 99
Free-electron interlayer states and related surface states in layered materials	p. 105
Compounds with the AlB[subscript 2] structure	p. 119
Semiconductor interfaces and heterojunctions	p. 134
Helium Atom Scattering Studies of the Surface Phonons of Layered Materials	p. 151
Helium atom scattering experimental techniques	p. 153
Graphite	p. 158
2H-TaSe[subscript 2]	p. 170
1T-TaS[subscript 2]	p. 184
GaSe	p. 196
[actual symbol not reproducible] high temperature superconductor	p. 206
Rare Gases on Graphite	p. 219
Interaction potentials and low coverage adsorption	p. 222
The phases of rare gases on graphite	p. 232
Experimental Review	p. 248
Monolayer adsorption of Ar, Kr, Xe and CH[subscript 4] on Layered Halides	p. 261
Historical	p. 261
Thermodynamic analysis of stepwise adsorption isotherms	p. 264
Layered dihalides as substrates for adsorption	p. 268
Corrugation-independent adsorption	p. 275
Sitewise adsorption	p. 292
Monolayer structure and corrugation: an overview	p. 303
Appendix: Semi-empirical estimation of the corrugation amplitude	p. 310
Subject Index	p. 317
Table of Contents provided by Blackwell. All Rights Reserved.

Surface Properties of Layered Structures

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Hardcover

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