
Surface Electrochemistry : A Molecular Level Approach
By: John O'M. Bockris, Shahad U.M. Khan
Hardcover
At a Glance
1052 Pages
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| Some Experimental Techniques | p. 1 |
| Electrochemical Techniques | p. 2 |
| Ex Situ Spectroscopic Techniques | p. 32 |
| In Situ Spectroscopic Techniques | p. 37 |
| Prospects | p. 51 |
| Evolutionary Goal | p. 53 |
| The Interphasial Structure | p. 59 |
| Thermodynamics | p. 61 |
| Potentials | p. 69 |
| The Potential of Zero Charge | p. 87 |
| Some Dielectric Aspects of Matter in Interphases | p. 95 |
| Excess Entropy in the Double Layer | p. 101 |
| Solvent Structure at the Interface | p. 109 |
| The Emersed Double Layer | p. 127 |
| Electric Imaging at Solid-Liquid Interfaces | p. 128 |
| Isoconcs | p. 132 |
| Partial Charge Transfer | p. 152 |
| Interfacial Structure Experiments Made on Specific Faces of Single Crystals | p. 157 |
| The Interface between a Metal and a Pure Electrolyte | p. 163 |
| The Semiconductor-Solution Interphase | p. 167 |
| Insulator-Solution Interface | p. 189 |
| Phases Moving Relative to Each Other (Electrokinetics) | p. 193 |
| Appendix 2.1. Heterogeneity | p. 199 |
| Appendix 2.2. The Partition Function Approach to the Deduction of Adsorption Isotherms | p. 201 |
| Appendix 2.3. The Bond Strength in Adsorption from Solution | p. 203 |
| Phenomenological Electrode Kinetics | p. 211 |
| The Nature of Electrochemical Reactions | p. 212 |
| The Rate versus Potential Relation at Constant Temperature and Pressure | p. 213 |
| Pre-Exponential Factors | p. 216 |
| Multistep Steady-State Electrode Kinetics | p. 218 |
| Potential-Sweep Kinetics | p. 223 |
| Electrochemical Reaction Orders | p. 242 |
| Electrochemical Reaction Rates as a Function of Temperature | p. 242 |
| Electrode Kinetics as a Function of Pressure | p. 244 |
| Electrode Kinetics as a Function of the Solvent | p. 247 |
| The Effects of the Structure of the Interface upon Electrode Kinetics | p. 250 |
| Reaction Intermediates | p. 255 |
| Electrode Kinetics in Relation to the Isotherm Applicable to an Intermediate Radical | p. 261 |
| The Electronic Work Function in Electrode Kinetics | p. 267 |
| Potential Energy Curves | p. 269 |
| The Symmetry Factor | p. 272 |
| Transfer Coefficient | p. 277 |
| "Activationless" and "Barrierless" Processes | p. 278 |
| Abnormal Relations of Rate to Potential | p. 280 |
| Determination of Mechanisms | p. 283 |
| Electrocatalysis | p. 290 |
| The Hydrogen Evolution Reaction | p. 310 |
| Oxygen Evolution and Reduction Reaction | p. 319 |
| Electrocrystallization | p. 349 |
| Deposition of Metals from Nonaqueous Solutions | p. 380 |
| Semiconductor Electrode Reactions | p. 383 |
| Quantum-Oriented Electrochemistry | p. 407 |
| Quantum Aspects of the Electric Double Layer | p. 408 |
| Some History of Quantum Electrode Kinetics | p. 421 |
| Proton Transfer at Interfaces | p. 423 |
| The Temperature Coefficient of [beta] | p. 438 |
| The Transfer Coefficient and Its Temperature Dependence: Quantum-Mechanical Calculations | p. 440 |
| Derivation of Free Energy of Activation from the Inner Shell, [Delta]G[actual symbol not reproducible], and the Force Constants of Ion-Ligand Bonds | p. 442 |
| Electron Transfer at Interfaces | p. 446 |
| Stochastic (Solvent Dynamical) Theory of Electron Transfer Reactions | p. 461 |
| Electrode Kinetics in the Superconducting State | p. 463 |
| Appendix 4.1. Deduction of the Born-Marcus Expression for the Outer-Sphere Continuum Contribution to the Free Energy of Activation, [Delta]G[actual symbol not reproducible](continuum) | p. 466 |
| Appendix 4.2. Limitations of the Continuum Solvent Reorganization Theory | p. 470 |
| Appendix 4.3. The Physical Model for Outer-Sphere Activation | p. 474 |
| Appendix 4.4. The Born Equation for the Energy to Charge Up Conducting Spheres: A Prequantal Concept | p. 474 |
| Photoelectrochemistry | p. 483 |
| Frequently Measured Quantities | p. 485 |
| The Vacuum Scale of Potentials | p. 490 |
| The Relation of the Chemical Potential Description of "Electrons in Solution" to the Concept of Their Energy States | p. 493 |
| The Distribution of Electronic States in Solution | p. 496 |
| The Traditional Theory of the Photocurrent: Butler's Original Schottky Barrier Calculation | p. 500 |
| Evidence for the Presence of Rate-Controlling Interfacial Reactions in Photoelectrochemical Kinetics | p. 503 |
| Surface States | p. 506 |
| Photoelectrocatalysis | p. 527 |
| The Photoelectrochemical Reduction of Carbon Dioxide | p. 533 |
| The Photoelectrolysis of H[subscript 2]S | p. 541 |
| Oxides as Electrodes | p. 542 |
| Photoluminescence and Electroluminescence | p. 543 |
| Time Responses in Photoelectrode Kinetics | p. 544 |
| Quantization Effects in Photoelectrochemistry | p. 545 |
| The Photosplitting of Water Using Colloidal Suspensions | p. 549 |
| Hydrogen and Electricity from Water and Light | p. 554 |
| Photoelectrochemical and Photovoltaic Cells in Water Splitting | p. 563 |
| The Photoelectrochemical Nature of Photosynthesis | p. 565 |
| The Evolution of Concepts at the Interface | p. 567 |
| About Some Consequences of Semiconductor Electrochemistry for Electrochemical Science | p. 569 |
| Organoelectrochemistry | p. 577 |
| Some History | p. 578 |
| The Classification of Organic Electrochemical Reactions | p. 580 |
| Features Which Encourage the Use of an Electrochemical Pathway for Synthesis | p. 581 |
| The Importance of Adsorption Isotherms in Understanding Organoelectrochemical Reactivity | p. 582 |
| Organoelectrochemical Kinetics | p. 585 |
| Mechanisms: Principles and Simple Examples | p. 587 |
| Organoelectrochemical Mechanisms Involving Larger Molecules | p. 616 |
| Some Difficulties of Using Organoelectrochemical Methods for Synthesis | p. 625 |
| Cyclic Voltammetry When Surface Processes Are Involved | p. 626 |
| The Contribution of Polarographic Measurements to Organoelectrochemistry | p. 627 |
| Electrocatalysis in Organoelectrochemical Reactions | p. 628 |
| Aromatic Hydrocarbons and Anodic Substitution | p. 636 |
| Electroreduction of Nitro Compounds | p. 637 |
| The Electrochemical Hydrodimerization of Substituted Olefins | p. 639 |
| Toward an Anodic Liquefaction of Coal | p. 642 |
| Photoelectrooxidation of Toxic Wastes | p. 647 |
| Electrochemical Initiation of Polymerization | p. 647 |
| Cell Designs in Electro-organic Chemistry | p. 651 |
| About the Prospects of a Larger Organoelectrochemical Industry | p. 656 |
| Bioelectrochemistry | p. 663 |
| Biological Cells and Their Membranes | p. 666 |
| Anomalies Faced by Classical Bioelectrochemistry | p. 666 |
| The Buildup of Evidence in Favor of a Surface-Oriented Bioelectrochemistry: 1960-1990 | p. 669 |
| Electronic Conductivity in Biology | p. 674 |
| Proton Conductivity in Biological Materials | p. 676 |
| The Double Layer at the Bioelectrochemical Interphase | p. 678 |
| Models of Electron Transfer to and from Protein in Contact with Solution | p. 678 |
| Heterogeneous Electron Transfer Reactions between Metal Substrates and Proteins in Solution | p. 682 |
| Enzymes on Electrodes | p. 688 |
| Semi-Electrodic Metabolic Theories Due to Mitchell and to Williams | p. 690 |
| Bioenergetics and Metabolism: An Electrodic View | p. 695 |
| The Electrochemistry of NAD[superscript +] and NADH | p. 703 |
| Aspects of the Respiratory Chain | p. 708 |
| The Passage of Electricity through Nerves | p. 710 |
| Approach to a Quantitative Development of an Electrodic Model in Bioelectrochemistry | p. 722 |
| Bone Growth | p. 730 |
| Magnetic Field Effects in Bioelectrochemistry | p. 732 |
| Electrochemical Mechanisms of Disease | p. 732 |
| Electrochemical "Information Transfer" | p. 735 |
| Bioelectrochemical Fuel Cells | p. 736 |
| Retrospect and Prospect | p. 737 |
| Some Electrochemical Aspects of the Stability of Materials | p. 745 |
| Measurement of Corrosion | p. 746 |
| Electrochemical Kinetics as the Basis for Heterogeneous Chemical Reactions | p. 754 |
| On the Mechanism of the Dissolution of Iron | p. 756 |
| The Mechanism of Hydrogen Evolution on Iron in Acid Solution | p. 767 |
| The Oxygen Reduction Reaction on Iron | p. 770 |
| Aspects of Aluminum Corrosion | p. 771 |
| Aspects of the Corrosion of Alloys | p. 775 |
| Passivity | p. 780 |
| Paint | p. 801 |
| Mechanisms of Inhibitor Action | p. 802 |
| Effects of Stress | p. 811 |
| Some Electrochemically Related Aspects of H in Metals | p. 833 |
| Biocorrosion | p. 849 |
| The Slag-Metal Interface in Terms of Steady-State Currentless Electrodes | p. 850 |
| Electrochemical Conversion and Storage of Energy | p. 861 |
| Conversion | p. 861 |
| Storage | p. 894 |
| The Electrochemistry of Cleaner Environments | p. 927 |
| Electrochemical Approaches to Cleaner Environments | p. 928 |
| Conservation as a Solution to Environmental Damage | p. 929 |
| Planetary Warming | p. 930 |
| The Pollution Arising from the Use of Gasoline and Diesel Oil as Fuels | p. 933 |
| The Future Sources of Energy | p. 935 |
| Need for a Medium of Energy in Addition to That of Electricity | p. 939 |
| Electrochemical Water Splitting | p. 940 |
| Hydrogen from H[subscript 2]S and FeS[subscript 2] Electrolysis | p. 951 |
| Electrogenerated Hydrogen | p. 952 |
| Homopolar Generator Approach | p. 952 |
| Developments of Hydrogen-Fueled, Fuel-Cell-Driven Cars | p. 957 |
| The Use of Bifunctional Metal Complexes to Electrocatalyze the Reduction of Greenhouse Gases | p. 958 |
| Removal of SO[subscript 2] and Cl[subscript 2] from Waste Gas Streams | p. 959 |
| Avoidance of SO[subscript 2] Injection into the Atmosphere in Metal Recovery from Sulfides | p. 959 |
| Catalytic Reduction of CO[subscript 2] in an H[subscript 2]-Driven Fuel Cell | p. 960 |
| Industrial Pollutants, Aquifers, and Metal Recoveries | p. 961 |
| Wastewater Treatment | p. 965 |
| The Electrochemical Treatment of Soils | p. 966 |
| The In Situ Electrochemical Production of O[subscript 3]: Its Use in In Situ Organic Oxidation | p. 967 |
| The Electrochemical Incineration of Sewage | p. 968 |
| Potential Use of Enzymes from Bacteria as an Aid to Low-Cost Energy Production | p. 969 |
| Bacteriolysis | p. 970 |
| Expected Decrease of Biotoxins by Increased Use of Electrochemical Methods | p. 971 |
| Biophotoelectrocatalysis | p. 971 |
| Potentiality of Electrochemical Approaches to Prospecting and Mining | p. 972 |
| Appendix 10.1. Economic Aspects of Conversion to New Energy Systems | p. 973 |
| Index | p. 977 |
| Table of Contents provided by Blackwell. All Rights Reserved. |
ISBN: 9780306442988
ISBN-10: 0306442981
Format: Hardcover
Language: English
Number of Pages: 1052
Audience: General Adult
Publisher: Springer Nature B.V.
Country of Publication: US
Dimensions (cm): 26.67 x 19.05 x 5.72
Weight (kg): 2.02
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