Supramolecular Stereochemistry

By: J.S. Siegel (Editor)

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Hardcover | 30 September 1995

At a Glance

Hardcover
288 Pages

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23.39 x 15.6 x 1.75

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Supramolecular stereochemistry is a topic with enormous breadth, and this book brings together experts in polymer chemistry, bioorganic chemistry, crystallography, materials science, dendrimer science, nanochemistry, conformational analysis, molecular recognition chemistry, and topological stereochemistry.
Contains 19 plenary and 12 poster contributions.

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Preface
Introduction
Macromolecular Stereochemistry: The Differing Roles of a Helix Reversal in Dilute Solution, in a Liquid Crystal, and in a Polymer Blend	p. 1
From Molecular to Supramolecular Chirality	p. 3
Template Induced Control of Stereochemistry for the Synthesis of Polymers	p. 13
Dendrimers - Nanoscopic Supermolecules According to Dendritic Rules and Principles	p. 21
Construction of DNA Polyhedra and Knots Through Symmetry Minimization	p. 27
Molecular Recognition by Catenated Structures	p. 33
Novel Protein Topologies	p. 41
A New Molecular Encoding System	p. 47
Recognition of B vs. Z-Form DNA using Nickel and Cobalt Complexes	p. 57
Principles of Antibody Catalysis	p. 63
Mechanistic Studies on the Formation of BZIP-DNA Interfaces. A Simple Example of Supramolecular Stereochemistry	p. 83
Chiral Discrimination in Crystalline Enantiomer Systems: Facts, Interpretations, and Speculations	p. 91
A Carbohydrate-Carbohydrate Interaction in Water using a Synthetic Model System	p. 111
Design of Host Molecules Capable of Forming Extremely Stable Host-Guest Complexes	p. 117
Structural Control over the Formation of Calcium Carbonate Mineral Phases in Biomineralization	p. 127
Hydrogen Bonding Control of Molecular Self-Assembly	p. 141
Supramolecular Stereochemistry of Supercharged Polycyclic Aromatic Hydrocarbons	p. 147
Enhancement of Electrostatic Binding Through Cooperative Interactions: Enthalpy/Entropy Compensation and Peptide-Peptide Recognition	p. 151
Toward Columns and Channels from Torands and Molecular Coils	p. 161
QMView: As a Supramolecular Visualization Tool	p. 169
Cis-trans-trans-1,2,3,4-Tetracyclohexylcyclohexane: A Monocyclic Unconstrained Cyclohexane Existing in a Twist-Boat Conformation	p. 179
The Conformation of Coumarin-Crown Ethers with Spin-Spin and Site Exchange Simulations	p. 185
Clathration Properties of Propeller-Shaped Molecules	p. 191
Control of Self-Assembly by Acid-Based Chemistry: Reversible Encapsulation of Xenon by Two Indentical Half-Shells	p. 195
Structural Diversity in a Family of Synthetic Oligoamides	p. 199
Diastereospecific Recognition of Dyes by Salt Crystals: A Case of Plundered Stereochemistry in Postwar Europe	p. 203
Selectivity Enhancement by Concave Reagents	p. 223
From p-tert-Butyl-Calix[6]arene to p-tert-Butyl-[l[superscript 6]]metacyclophane. Isolation and Crystal Structure of a Mono Bridged Penta-Phosphoester	p. 227
Two Shells About a Nut: Carceplexes, Hemicarceplexes, and Highly Stable Ternary Complexes	p. 233
Cyclodextrin-Metallocene Inclusion Complexes	p. 239
Dendritic Polyphosphates: Globular Polyelectrolytes?	p. 247
Author Index	p. 255
Subject Index	p. 257
Table of Contents provided by Blackwell. All Rights Reserved.

Supramolecular Stereochemistry

At a Glance

Hardcover

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