Supramolecular Chemistry : Proceedings of the Second NATO Science Forum, Taormina (Sicily), Italy, December 15-18, 1991

By: L. De Cola (Editor), Vincenzo Balzani (Editor), L. De Cola (Editor)

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This volume documents the progress made in the design of complex artificial systems and in the study of intermolecular forces and interactions. It is possible, using appropriate strategies based on building blocks, to obtain very large supramolecular arrays containing several hundered atoms, where specific sites are occupied by the desired chemical functions. Such arrays can be used for such things as molecular recognition, self-organization, self-replication, selective reactivity, selective catalysis, photoinduced energy and electron transfer, signal processing, information storage and drug delivery.

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Non-Fiction Science Physics Applied Physics Biophysics Medical Physics Chemistry Organic Chemistry Physical Chemistry Biology, Life Sciences Biochemistry

Foreword
Foreword
Preface
Organizing Committee
List of Participants and Observers
Self-assembly in chemical systems	p. 1
Hydrogen bonding in supramolecular functions	p. 17
New shapes for selective molecular recognition from calixarenes	p. 31
Calix[4]arenes, molecular platforms for supramolecular structures	p. 51
Molecules with large cavities. Selective complexation of inorganic and organic guests	p. 71
Multi-electron redox activity of supramolecular coordination compounds containing metallocyclam and ferrocene fragments	p. 87
New approaches to anion coordination chemistry. Acyclic quaternary polybipyridinium receptors designed to bind anionic guest species	p. 105
Supramolecular cyclophane chemistry	p. 119
New synthetic receptors for complexation and catalysis	p. 137
Unimolecular Micelles	p. 145
Ru(II) and/or Os(II) trimetallic complexes of tris(bipyridine) bridging ligands. Absorption spectra, luminescence properties, electrochemical behavior, and intercomponent energy transfer	p. 157
Kinetic and spectroscopic investigation of the influence of conformation and orbital-symmetry on long-range intramolecular donor-acceptor interaction	p. 181
Supramolecular arrays for the efficient conversion of light into chemical energy in the solid state	p. 201
Into the third dimension of coordination chemistry: towards starburst arrays	p. 219
Antenna effects and photoinduced electron transfer in polynuclear metal complexes	p. 235
Long-range electron and energy transfer in molecular assemblies	p. 249
Synthetic molecular knots	p. 259
Proton transfer photoreactions in supramolecular systems	p. 279
The optimization of photochemical energy conversion: synthetic supramolecular devices vis a vis photosynthesis	p. 295
Intramolecular electron transfer in donor acceptor systems linked by a flexible chain	p. 313
Attempts to mimic biomembrane processes: function of phospholipase A[subscript 2] at lipid monolayers	p. 325
Photochemistry of crown ether styryl dyes	p. 343
Towards synthetic enzymes based on porphyrins and steroids	p. 359
Photophysical properties of thionine and methylene blue when bound to DNA, polynucleotides or nucleotides	p. 375
Structure and binding for cyclophane-arene complexes in water from Monte Carlo simulations	p. 383
Photoinduced electron transfer between intercalated molecules: using polynucleotides to self-assemble donor-acceptor systems	p. 395
Synthesis and properties of heterometal cubane-type clusters in ferredoxins	p. 403
Binding and catalysis in water	p. 411
Ferrocene as the central unit in novel, redox-sensitive ligands, monomers, and receptors	p. 429
Author index	p. 443
Subject index	p. 445
Table of Contents provided by Blackwell. All Rights Reserved.

Supramolecular Chemistry : Proceedings of the Second NATO Science Forum, Taormina (Sicily), Italy, December 15-18, 1991

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