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Ruthenium Catalysts and Fine Chemistry : Topics in Organometallic Chemistry - Christian Bruneau

Ruthenium Catalysts and Fine Chemistry

Topics in Organometallic Chemistry

By: Christian Bruneau (Editor), Pierre H. Dixneuf (Editor)

Hardcover Published: 30th June 2004
ISBN: 9783540205432
Number Of Pages: 337

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Molecular ruthenium catalysts, during the last decade, have provided new indispensable synthetic methods that cannot be promoted by other catalysts, and they now constitute an emerging field for the selective preparation of fine chemicals. The major reaction types for carbon-carbon and carbon-heteroatom bond formation, most of them with atom economy, are comprehensively discussed by leading experts. The authors highlight the most important discoveries in ruthenium catalysis and propose activation processes, some of them being still controversial. They illustrate the innovation and usefulness in organic synthesis of specific reactions including carbocyclization, cyclopropanation, olefin metathesis, carbonylation, oxidation, transformation of silicon containing substrates, and show novel reactions operating via vinylidene intermediates, radical processes, inert bonds activation as well as catalysis in water. Therefore, the reader will receive a balanced view of this rapidly developing field.

Ruthenium-catalyzed C-C bond formationp. 1
Activation of inert C-H bondsp. 45
Cyclopropanation with ruthenium catalystsp. 81
Recent advances in alkene metathesisp. 93
Ruthenium vinylidenes and allenylidenes in catalysisp. 125
Ruthenium-promoted radical processes toward fine chemistryp. 155
Selective carbonylations with ruthenium catalystsp. 173
Synthesis of silicon derivatives with ruthenium catalystsp. 197
Ruthenium-catalyzed synthesis of heterocyclic compoundsp. 249
Oxidations using ruthenium catalystsp. 277
Ruthenium-catalyzed organic synthesis in aqueous mediap. 321
Table of Contents provided by Blackwell. All Rights Reserved.

ISBN: 9783540205432
ISBN-10: 3540205438
Series: Topics in Organometallic Chemistry
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 337
Published: 30th June 2004
Country of Publication: DE
Dimensions (cm): 23.39 x 15.6  x 2.06
Weight (kg): 0.68