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Progress In Organosilicon Chem

Name: Progress In Organosilicon Chem
Brand: Gordon and Breach
Price: 176.75 AUD
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By: Bogdan Marciniec (Editor), Julian Chojnowski (Editor)

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Hardcover | 11 November 2004 | Edition Number 1

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602 Pages

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22.9 x 15.2 x 3.81

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Progress in Organosilicon Chemistry comprises more than thirty papers presented by many of the world's most eminent organosilicon specialists at the Tenth International Symposium on Organosilicon Chemistry held in Poznan, Poland in August 1993. The conference marked the fiftieth anniversary of the discovery and exploration of "direct synthesis." As much attention today is directed beyond silicon polymers, chemists have become involved with the use of elementary silicon and its applications, including ultrapure silicon in transistors and computers, silicon precursors of polymers, and other silicon-based materials as well as fine chemicals.
This book provides an overview of organosilicon chemistry, including organic and inorganic chemistry of silicon, silicon polymers and oligomers; theoretical and structural chemistry of silicon; silicon-based materials and their applications; silicon in organic synthesis; mechanistic organosilicon chemistry; and bio- and environmental organosilicon chemistry. This diverse range of topics makes the book a valuable reference for chemists working in both applied and theoretical chemistry.

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Miscellaneous Items Non-Fiction Science Chemistry Organic Chemistry Organometallic Chemistry Engineering & Technology Industrial Chemistry & Manufacturing Technologies Industrial Chemistry Plastics & Polymers Technology Science in General Sociology & Anthropology

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Preface
Why Silicon?	p. 3
A Journey into the Chemical Country of Overloaded Supersilyl Compounds	p. 19
Sterically Overcrowded Organosilicon Compounds: Structure and Molecular Properties	p. 41
Zwitterionic 5-Organospirosilicates and 5-Organofluorosilicates: Syntheses, Structures and Properties	p. 55
The Structure and Properties of Hypervalent Silicon Compounds with a Soft Coordination Center	p. 69
Air-Stable 1-Silaallenes	p. 83
Hydrogen-Rich Polysilylated Alkenes, Alkynes and Arenes	p. 103
Synthesis and Reactivity of Small Cyclic Silicon Compounds	p. 117
Synthesis and Characterization of Transition Metal Silylene and Silylyne Complexes	p. 133
Substituent Constants of Groups at the Si-atom	p. 147
Steric Factors in [superscript 29]Si NMR Chemical Shifts	p. 177
Coordination and Reactivity in Organosilicon Chemistry	p. 191
The Chemistry of Functional Silyl Anions	p. 209
The Stereochemistry of the S[subscript E]2" Reaction of Dienylmethylsilanes	p. 223
Stereochemistry and Mechanism of Alcohol Addition to Organosilicon Unsaturated Species	p. 233
Frontier Orbital Control of Silylene Addition to Olefins	p. 247
Recent Mechanism Studies on Hydrosilylation	p. 263
Activation of Si-X Bonds by Electron-Deficient Transition Metals	p. 287
The Chemistry of 3,4-Benzo-1,1,2,2-tetraethyl-1, 2-disilacyclobut-3-ene	p. 309
New Results in Sb(III) and Bi(III) Halide-Catalyzed Reactions in Organosilicon Chemistry	p. 325
Some New Silicotropic Rearrangements	p. 345
Recent Achievements in Industrial Silicon Polymer Science	p. 363
Formation of Silicon Oligomers and Polymers from Dehydrocoupling of Primary and Secondary Silanes in the Presence of Combination Catalysts: Cp'[subscript 2]MCl[subscript 2]/nBuLi	p. 387
New Routes to Precursors for the Formation of Silicon Carbide and Silicides	p. 411
Structural Control in Polysilanes Prepared by the Ring Opening Polymerization	p. 429
Preparation of Organosilicon Oligomers and Polymers via the Reaction of Olefin Metathesis	p. 445
A Molecular Building-Block Approach to Silicon Carbonitride	p. 467
Quantum Chemical Analysis and Prediction of Plasma Chemical Vapor Deposition Processes of Silicon Compounds	p. 483
Condensation Vulcanizing Silicone Elastomers - An Overview of Research and Development	p. 503
Development and Application of Silicone Materials for Electrical and Electronics Applications	p. 523
Silicone Microemulsion Concentrates. A New Approach to Aqueous Water Repellents Masonry	p. 539
Recent Development of Metallurgical Silicon for Applications in the Chemical Industry	p. 555
Future Developments in Silicon Chemistry - An Industrial Perspective	p. 571
Index	p. 581
Table of Contents provided by Blackwell. All Rights Reserved.

Progress In Organosilicon Chem

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Hardcover

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