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Polyoxometalate Chemistry From Topology via Self-Assembly to Applications - Michael T. Pope

Polyoxometalate Chemistry From Topology via Self-Assembly to Applications

By: Michael T. Pope (Editor), Achim Muller (Editor)

Hardcover Published: 30th June 2001
ISBN: 9780792370116
Number Of Pages: 427

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Polyoxometalates constitute an extensive class of compounds with an unmatched range of structures, properties, and applications. This book incorporates contributions from polyoxometalate scientists, and presents a summary of research developments in this dynamic field. It provides an introduction for academic and industrial chemists, biochemists, structural biologists, surface scientists, mathematicians, and others interested in new applications and devices. Topics discussed include synthetic strategies leading to functionalized organic polyoxometalate derivatives, oxothioanions, and supramolecular assemblies; solution equilibria pertinent to the bleaching of kraft pulp; molecular growth from discrete anions to framework materials, nano-devices and thin films via self-assembly processes; energy transfer solid-state optical and magnetic properties, selective homogeneous and nanocluster-based catalytic applications; photocatalytic decontamination of water resources; and structural crystallography of the ribosome.

Introduction to Polyoxometalate Chemistry: From Topology via Self-Assembly to Applicationsp. 1
Synthetic Strategies
Rational Approaches to Polyoxometalate Synthesisp. 7
Functionalization of Polyoxometalates: Achievements and Perspectivesp. 23
From the First Sulfurated Keggin Anion to a New Class of Compounds Based on the [M[subscript 2]O[subscript 2]S[subscript 2 superscript 2+] Building Block M=Mo, Wp. 39
Organometallic Oxometal Clustersp. 55
Structures: Molecular and Electronic
Spherical (Icosahedral) Objects in Nature and Deliberately Constructable Molecular Keplerates: Structural and Topological Aspectsp. 69
Syntheses and Crystal Structure Studies of Novel Selenium- and Tellurium-Substituted Lacunary Polyoxometalatesp. 89
Vibrational Spectroscopy of Heteropoly Acidsp. 101
Bond-Stretch Isomerism in Polyoxometalates?p. 117
Quantum-Chemical Studies of Electron Transfer in Transition-Metal Substituted Polyoxometalatesp. 135
Solution Equilibria and Dynamics
Aqueous Peroxoisopolyoxometalatesp. 145
Molybdate Speciation in Systems Related to the Bleaching of Kraft Pulpp. 161
NMR Studies of Various Ligands Coordinated to Paramagnetic Polyoxometalatesp. 175
From Discrete Clusters to Networks and Materials
Molecular Aspect of Energy Transfer from Tb[superscript 3+] to Eu[superscript 3+] in the Polyoxometalate Lattices: An Approach for Molecular Design of Rare-Earth Metal-Oxide Phosphorsp. 187
Conducting and Magnetic Organic / Inorganic Molecular Materials Based on Polyoxometalatesp. 205
Molecular Materials From Polyoxometalatesp. 231
Framework Materials Composed of Transition Metal Oxide Clustersp. 255
Perspectives in the Solid State Coordination Chemistry of the Molybdenum Oxidesp. 269
Polyoxometalate Clusters in a Supramolecular Self-Organized Environment: Steps Towards Functional Nanodevices and Thin Film Applicationsp. 301
Polyoxometalate Chemistry: A Source for Unusual Spin Topologiesp. 319
Heteropolyanions: Molecular Building Blocks for Ultrathin Oxide Filmsp. 329
Applications: Catalysis, Biological Systems, Environmental Studies
Selective Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Iron-substituted Silicotungstatesp. 335
Aerobic Oxidations Catalyzed by Polyoxometalatesp. 347
Polyoxoanions in Catalysis: From Record Catalytic Lifetime Nanocluster Catalysis to Record Catalytic Lifetime Catechol Dioxygenase Catalysisp. 363
Ribosomal Crystallography and Heteropolytungstatesp. 391
Photocatalytic Decontamination by Polyoxometalatesp. 417
Indexp. 425
Table of Contents provided by Syndetics. All Rights Reserved.

ISBN: 9780792370116
ISBN-10: 0792370112
Audience: Tertiary; University or College
Format: Hardcover
Language: English
Number Of Pages: 427
Published: 30th June 2001
Publisher: Springer
Country of Publication: NL
Dimensions (cm): 24.13 x 16.51  x 2.03
Weight (kg): 0.74