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Organomagnesium Methods in Organic Chemistry : Best Synthetic Methods - B.J. Wakefield

Organomagnesium Methods in Organic Chemistry

Best Synthetic Methods

Hardcover Published: 26th April 1995
ISBN: 9780127309453
Number Of Pages: 249

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The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized.
The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as hydromagnesiation of alkenes and alkynes.
Systematic coverage is provided on synthetically useful reactions of organomagnesium compounds. Of fundamental importance in organic synthesis are carbon-carbon bond forming reactions; additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur multiple bonds; and nucleophilic substitution at carbon. The formation of carbon-heteroatom bonds in organic compounds is described, where the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds is outlined.
Representative experimental procedures are included throughout the book, and tables with references to well-described examples are provided.
Key Features
* Presents a general overview of the constitution and reactivity of organomagnesium compounds
* Provides coverage on the detection and estimation of organomagnesium compounds
* Emphasizes practical aspects as well as principles
* Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes
* Includes preparations by metallation and metal-halogen exchanges
* Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes
* Outlines information on synthetically useful reactions of organomagnesium compounds
* Describes the formation of carbon-heteroatom bonds in organic compounds
* Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds
* Includes representative procedures and tables with references to well-described examples

Industry Reviews

"This book, like others in the Best Synthetic Methods series, is a compact and practical summary and guide to the application of an area of organic chemistry to the craft of organic synthesis. ...this is a useful book, whichresponds to a real need. In these days of proliferating literature, the student or practicing chemist who has access to this and similar references will have the edge." --JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Introduction and General References
General Considerations in the Application of Organomagnesium Compounds in Organic and Organometallic Synthesis
Preparation of Organomagnesium Compounds
Addition of Organomagnesium Compounds to Carbon-Carbon Multiple Bonds
Addition of Organomagnesium Compounds to Carbon-Nitrogen Multiple Bonds
Addition of Organomagnesium Compounds to Carbonyl Groups
Carbophilic Addition of Organomagnesium Compounds to Thiocarbonyl Groups
Substitution atCarbon by Organomagnesium Compounds
Carbenoid and Arynoid Reactions of Organomagnesium Compounds
Reactions of Organomagnesium Compounds with Proton Donors
Formation of Carbon-Nitrogen Bonds via Organomagnesium Compounds
Formation of Carbon-Oxygen Bonds via Organomagnesium Compounds
Formation of Carbon-Sulfur, Carbon-Selenium, and Carbon-Tellurium Bonds via Organomagnesium Compounds
Formation of Carbon-Halogen Bonds via Organomagnesium Compounds
Synthesis of Organoboron, Organosilicon, and Organophosphorous Compounds from Organomagnesium Compounds
Organomagnesium Compounds in the Synthesis of Other Organometallic Compounds
Index of Compounds and Methods
Table of Contents provided by Publisher. All Rights Reserved.

ISBN: 9780127309453
ISBN-10: 0127309454
Series: Best Synthetic Methods
Audience: General
Format: Hardcover
Language: English
Number Of Pages: 249
Published: 26th April 1995
Publisher: ACADEMIC PR INC
Country of Publication: GB
Dimensions (cm): 23.72 x 15.72  x 2.01
Weight (kg): 0.52

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