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Nuclear Spectroscopy on Charge Density Wave Systems : Physics and Chemistry of Materials with Low-Dimensional Stru - Tilman Butz

Nuclear Spectroscopy on Charge Density Wave Systems

Physics and Chemistry of Materials with Low-Dimensional Stru

By: Tilman Butz (Editor)

Hardcover Published: 31st August 1992
ISBN: 9780792317791
Number Of Pages: 328

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Nuclear magnetic resonance (NMR), nuclear quadrupole resonance (NQR), time differential perturbed angular correlations (TDPAC), and the Mossbauer effect (ME) have been applied to the study of charge density wave (CDW) systems. These hyperfine techniques provide unique tools to probe the structure and symmetry of commensurate CDWs, give a clear fingerprint of incommensurate CDWs, and are ideally suited for CDW dynamics.
This book represents a new attempt in the series `Physics and Chemistry of Materials with Low-dimensional Structures' to bring together a consistent group of scientific results obtained by nuclear spectroscopy related to CDW phenomena in pseudo-one- and two-dimensional systems.
The individual chapters contain: the theory of CDWs in chain-like transition metal tetrachalcogenides; NMR, NQR, TDPAC, and ME investigations of layered transition metal dichalcogenides; NMR studies of CDW-transport in chain-like NbSe3 and molybdenum bronzes; multinuclear NMR of KCP; high resolution NMR of organic conductors.
This book is of interest to graduate students and all scientists who want to acquire a broader knowledge of nuclear spectroscopy techniques applied to CDW systems.

Preface
Introductionp. 1
Phenomenological Theory of Charge-Density-Wave Phase Transitions in the NbTe[subscript 4] - TaTe[subscript 4] Series of Compoundsp. 7
Introductionp. 7
A Prototypical Model of Charge-Density-Wave Formationp. 8
Modulated Structures of the NbTe[subscript 4] Series of Compoundsp. 21
Conclusionsp. 31
Layered Transition Metal Dichalcogenidesp. 35
Hyperfine Techniquesp. 35
Structure of Layered Transition Metal Dichalcogenidesp. 54
Compounds with Octahedral Metal Coordinationp. 56
Compounds with Trigonal Prismatic Metal Coordinationp. 85
Compounds with Mixed Metal Coordinationp. 106
Nuclear Spectroscopy Studies of Quasi-one-dimensional Transition Metal Chalcogenidesp. 113
Introductionp. 113
NbSe[subscript 3]p. 125
Monoclinic TaS[subscript 3]p. 155
FeNb[subscript 3]Se[subscript 10]p. 160
Tetrachalcogenidesp. 165
Conclusionsp. 169
Nuclear Spectroscopy of Charge Density Waves in Molybdenum Bronzesp. 177
Introductionp. 177
Physical Properties of the Blue Bronzesp. 178
NMR in the Normal Statep. 187
Nuclear Spectroscopy of Pinned CDWp. 190
Dynamics in the Pinned CDWp. 202
NMR in the Sliding CDW Statep. 206
Conclusionp. 222
NMR Studies of the Quasi One-dimensional Inorganic Complex Salt K[subscript 2]Pt(CN)[subscript 4]Br[subscript 0.3]3.2H[subscript 2]0 (KCP)p. 229
Introductionp. 229
Properties of KCPp. 230
NMR Investigations in KCPp. 237
Conclusionsp. 270
High Resolution NMR on Organic Radical Saltsp. 275
Introductionp. 275
Solid State Theory of Radical Saltsp. 276
High Resolution Techniquesp. 280
Magnetic Electron Nuclear Interactionp. 283
Experimental Resultsp. 288
Summaryp. 307
Indexp. 313
Table of Contents provided by Blackwell. All Rights Reserved.

ISBN: 9780792317791
ISBN-10: 0792317793
Series: Physics and Chemistry of Materials with Low-Dimensional Stru
Audience: General
Format: Hardcover
Language: English
Number Of Pages: 328
Published: 31st August 1992
Publisher: SPRINGER VERLAG GMBH
Country of Publication: NL
Dimensions (cm): 23.39 x 15.6  x 2.06
Weight (kg): 0.66

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