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Novel Metathesis Chemistry : Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications - Y. Imamoglu

Novel Metathesis Chemistry

Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications

By: Y. Imamoglu (Editor), L. Bencze (Editor)

Hardcover Published: 30th November 2003
ISBN: 9781402015700
Number Of Pages: 354

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A comprehensive discussion of the theory, practice and application of catalytically active transition metal species and their application in the production of specialist polymeric materials. The material is presented in a progressive manner, suitable for non-experts and those seeking an introduction to the field. The bibliographies supplied are complete and up to date, making the book an indispensable guide to the primary literature for the more theoretical background to the topics discussed.
After a comprehensive discussion of initiating systems for speciality chemical synthesis the book goes on to deal with a wide range of topics in materials science, including: alkenamers, polyacetylenes, industrial applications and liquid rocket engine fuels.

Prefacep. xi
List of Participantsp. xiii
Initiating Systems for Specialty Chemical Synthesis
The Alkene Metathesis Ruthenium Catalyst Sagap. 1
Ruthenium Carbenes as Catalysts for Alkene Metathesisp. 23
Metathetical Conversion and Silylative Coupling of Alkadienes and Cycloalkenes with mono- and di-Vinylsilicon Compoundsp. 43
Synthesis of Organosilicon Reagents of Vinylsilicon Functionality via Cross-Metathesis and Silylation of Alkenesp. 51
Catalytic Properties and Chemical Transformations of cis-W(CO)[subscript 4](C[subscript 5]H[subscript 5]N)[subscript 2] Initiator in Ring Opening Metathesis Polymerizationp. 65
The Impact of Well-Defined Transition Metal Initiators on ROMPp. 73
Dual Activity of Ruthenium Catalysts in Controlled Radical Reactions and Olefin Metathesisp. 87
O,N- Bidentate Ligands Co-Ordinated on Ru-Based Olefin Metathesis Catalystsp. 101
Catalytic Activity of W-Sn and Mo-Sn Bimetallic Compounds in Metathesis and Related Reactionsp. 121
Polymerizations Catalyzed with Rhodium Complexesp. 131
Mesoporous Molecular Sieves Immobilized Catalysts for Polymerization of Phenylacetylene and its Derivativesp. 155
Study of the Stability and Activity of Electrochemically Produced Tungsten-Based Metathesis Catalyst with Symmetrical Alkenesp. 167
Immobilized Tungsten-Containing Catalysts for the Metathesis of Linear and Functionalized Olefinsp. 173
The Range of Topics Covered in Material Science
The Incorporation of Amino Acids into Polymers via ADMETp. 179
Graft Copolymers Attained by ATRP and ADMETp. 191
Synthesis, Conformation, and Functions of Helical Poly(N-Propargylamides)p. 203
Synthesis of Block Copolymers and Star Polymers through Living Polymerization of Substituted Acetylenesp. 215
Well-Defined Linear and Crosslinked Materials via ROMP and RTM Processingp. 229
Ring Opening Metathesis Polymerisation (ROMP) of Cyclooctene and Substituted Norbornene Derivatives Using a Ruthenium Catalyst Containing a Triazol-5-Ylidene Ligandp. 237
Acyclic Diene Metathesis (ADMET) Polymerization by Electrochemically Generated Tungsten-Based Active Catalyst System: Optimization of Reaction Conditionsp. 243
Probing the Tacticity of Ring-Opened Metathesis Polymers of Norbornene and Norbornadiene Diesters by NMR Spectroscopyp. 249
Metathesis and Polyolefin Growth on Cadmium Selenide Surfaces Using Ruthenium-Based Catalystsp. 263
Acyclic Diene Metathesis Condensation (ADMET) of 1,2-Divinylferrocene (DVFC)p. 271
Acyclic Diyne Metathesis Condensation of 3-Alkyl-2,5-di(1-propynyl)-thiophenesp. 277
Ring Closing Versus Cyclic Isomerization of 1,6-Dienes by Ruthenium Allenylidene Complexesp. 285
Application of Uniform-Macroporous Polystyrene Particles as Support In W(CO)[subscript 6]/CCl[subscript 4]/hv Photocatalytic Olefin Metathesis Systemp. 295
Reactions of Atomic Carbon with 2-Norbornenep. 303
Intramolecular Trapping of Strained Bicyclic Allene in Carbon Atom Reactionsp. 309
Indusrial Aspects
Industrial Applications of Olefin Metathesisp. 313
Synthesis of Cyclobutane Hydrocarbons by Combination of (2+2)[subscript Pi]-Cycloaddition and Olefin Metathesis. Their Abilities as Effective Propellantsp. 323
Directional Synthesis of Membrane Materials by ROMP of Silyl-Substituted Norbornadienes and Norbornenesp. 341
Subject Indexp. 351
Table of Contents provided by Ingram. All Rights Reserved.

ISBN: 9781402015700
ISBN-10: 1402015704
Series: NATO Science Series II:
Audience: General
Format: Hardcover
Language: English
Number Of Pages: 354
Published: 30th November 2003
Publisher: SPRINGER VERLAG GMBH
Country of Publication: NL
Dimensions (cm): 24.74 x 16.76  x 2.39
Weight (kg): 0.73

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