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392 Pages
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Industry Reviews
Bruce A. Moyer, PhD, Oak Ridge, TN
`This third book by Max Roundhill in the "Modern Inorganic Chemistry" series provides a thoroughly competent treatment that will serve the needs of both researchers and users of the methods. As well as having a logical and systematic structure, the text is written in an easily readable style so that the contents can be assimilated quickly. The clear arrangement of the material according to the different methods and heavy metals will ensure that the above two groups of users can quickly find information on aspects of special interest. On one hand, by explaining the advantages and disadvantages of the various extraction methods it enables the user to make an informed choice, and also to choose the most suitable ligands, for example with regard to metal selectivity. The researcher, on the other hand, will be able to evaluate his or her own results (using different ligands or extraction methods) by comparing them with the results reported in the book. Thus, the author wisely decided to include not only methods that have already been tested in field trials, but also results from research on other interesting methods which are still only at the laboratory stage.'
Rainer Ludwig, Institut fur Chemie, Freie Universitat Berlin (Germany) in Angewandte Chemie Review in 2002
| Introduction | |
| Occurrence and Remediation Strategies | p. 1 |
| Heavy Metals | p. 2 |
| Precious Metals | p. 4 |
| Strategies for Obtaining Metal Ion Recognition | p. 5 |
| Phase Transfer Extraction and Adsorption Methods | |
| Introduction | p. 9 |
| Liquid-Liquid Systems | p. 11 |
| Equilibria | p. 11 |
| Surfactants | p. 12 |
| Ion Hydration | p. 12 |
| Aqueous Biphasic Systems | p. 15 |
| Liquid Membranes | p. 16 |
| Picrate Method of Analysis | p. 19 |
| Adsorption Methods | p. 20 |
| Ion Exchange Methods | p. 20 |
| Adsorbent and Membrane Methods | p. 23 |
| Polymer Filtration Methods | p. 24 |
| Uncharged Solid Phase Adsorbent Materials | p. 25 |
| Silicates and Zeolites | p. 28 |
| Polymers and Biopolymers | p. 29 |
| Soil Washing Methods and In Situ Stabilization Methods | |
| Introduction | p. 35 |
| Soil Washing and Flooding | p. 36 |
| Soil Washing | p. 37 |
| In Situ Stabilization | p. 39 |
| Analytical Techniques | p. 41 |
| Extraction from Soils | p. 43 |
| Complexant Design for Soil Extraction | p. 44 |
| Electrokinetic Extraction of Metals from Soils | |
| Introduction | p. 47 |
| Electrokinetic Extraction | p. 47 |
| Electrokinetic Transport Model | p. 50 |
| Experimental Method | p. 52 |
| Electrokinetic Extraction of Copper, Lead, Cadmium, and Mercury | p. 54 |
| Electrokinetic Extraction of Uranium and the Other Radionuclides | p. 57 |
| Electrokinetic Extraction of Chromium | p. 58 |
| Selective Extraction with Chelates, Macrocycles, and Calixarenes | |
| Introduction | p. 63 |
| Multidentate Ligands | p. 65 |
| Dithio- and Diselenocarbamates | p. 66 |
| Aminopolycarboxylic Acids, Amides, and Aminimides | p. 68 |
| Oximes and Hydroxyaromatic Derivatives | p. 72 |
| Others | p. 75 |
| Extractants for Supercritical Carbon Dioxide | p. 80 |
| Macrocyclic Ligands | p. 81 |
| Oxygen Macrocycles | p. 82 |
| Azamacrocycles and Thiamacrocycles | p. 84 |
| Calixarenes | p. 95 |
| Limitations of Chelate, Macrocycle, and Calixarene Extractants | p. 100 |
| Phase Transfer Extraction of Mercury | |
| Background | p. 105 |
| Toxicity and Occurrence | p. 106 |
| Complexants | p. 107 |
| Oxygen Donors | p. 108 |
| Nitrogen Donors | p. 109 |
| Sulfur Donors | p. 109 |
| Chelates and Multidentates | p. 109 |
| Sulfur and Nitrogen Donor Chelates | p. 110 |
| Extraction and Detection Techniques | p. 113 |
| Column Materials for Mercury Separation | p. 114 |
| Organic Adsorbents | p. 115 |
| Inorganic Adsorbents | p. 115 |
| Macrocycles and Open Chain Analogs | p. 116 |
| Open Chain Analogs | p. 116 |
| N-Donor Macrocycles | p. 117 |
| S-Donor Macrocycles | p. 117 |
| O-Donor Macrocycles | p. 118 |
| N, O-Donor Macrocycles | p. 119 |
| Chromogenic and Fluorogenic Macrocycles | p. 121 |
| Porphyrins | p. 121 |
| Calixarenes | p. 122 |
| P and S-Donor Calixarenes | p. 122 |
| N-Donor Calixarenes | p. 124 |
| Elemental Mercury | p. 125 |
| Phase Transfer Extraction of Lead and Cadmium | |
| Lead | p. 129 |
| Toxicity and Occurrence | p. 129 |
| Complexants | p. 130 |
| Chelates and Macrocycles | p. 133 |
| Macrocycles | p. 139 |
| Calixarenes | p. 145 |
| Liquid Carbon Dioxide as the Non-Aqueous Phase | p. 146 |
| Biological | p. 148 |
| Ingestion from Paper | p. 148 |
| Analytical Methods for Lead | p. 148 |
| Cadmium | p. 151 |
| Toxicity and Occurrence | p. 151 |
| Chelates and Macrocycles | p. 152 |
| Sulfur Donors | p. 154 |
| Cyclodextrins and Carbohydrates | p. 157 |
| Cadmium Incorporation into the Food Chain | p. 158 |
| Phase Transfer Extraction of Copper, Silver and Gold | |
| Copper | p. 164 |
| Monodentate Ligands | p. 164 |
| Chelate Ligands | p. 166 |
| Macrocycles and Calixarenes | p. 175 |
| Calixarenes | p. 177 |
| Porphyrins | p. 177 |
| Carbon Dioxide | p. 177 |
| Others | p. 178 |
| Silver and Gold | p. 179 |
| Monodentates | p. 179 |
| Chelates | p. 181 |
| Macrocycles | p. 184 |
| Calixarenes | p. 187 |
| Extraction of Actinides and Lanthanides | |
| Actinides | p. 193 |
| Introduction | p. 193 |
| Monodentates | p. 193 |
| Multidentates | p. 197 |
| Lanthanides | p. 206 |
| Monodentates | p. 207 |
| Extraction of Anions and Oxyanions | |
| Introduction | p. 231 |
| Toxicological Effects | p. 233 |
| Analytical Techniques | p. 234 |
| Extraction Methods | p. 234 |
| Complexant Design | p. 237 |
| Acyclic Ligating Sites | p. 237 |
| Amines | p. 238 |
| Calixarenes | p. 240 |
| Poly(ethylene glycol) | p. 243 |
| Extraction from Soils | p. 243 |
| Extraction of Alkali and Alkaline Earth Metals | |
| Introduction | p. 247 |
| Crown Ethers | p. 248 |
| Crown and Bis-Crowns | p. 248 |
| Capped Cleft Molecules | p. 253 |
| Biphasic Media | p. 254 |
| Transport Phenomena | p. 255 |
| Carboxylate Crowns | p. 261 |
| Phosphonate Crowns | p. 261 |
| Lariat Crowns | p. 263 |
| Amino Crowns | p. 264 |
| Aza Crowns and Photocrowns | p. 266 |
| Specialty Crowns | p. 270 |
| Cavitands and Cryptands | p. 273 |
| Other Oxygen Donors | p. 276 |
| Metal Oxides | p. 279 |
| Physical Methods | p. 279 |
| Cesium | p. 281 |
| Phytoremediation and Bioremediation of Soils and Waters | |
| Introduction | p. 289 |
| Phytoremediation | p. 290 |
| Chromium (VI) | p. 292 |
| Cadmium, Lead, Copper, and Zinc | p. 293 |
| Mercury | p. 296 |
| Radionuclides | p. 296 |
| Bioremediation | p. 297 |
| Mercury | p. 298 |
| Cadmium, Copper, and Lead | p. 299 |
| Actinides | p. 300 |
| Chromium | p. 301 |
| Optical and Redox Sensors with Metal Ions | |
| Introduction | p. 307 |
| Optical Reporter Molecules | p. 308 |
| Redox Reporter Molecules | p. 310 |
| Chemiluminescence | p. 310 |
| Chelate Complexants | p. 311 |
| Nitrogen and Oxygen Donors | p. 311 |
| Conformational and Steric Effects | p. 316 |
| Sulfur Donors | p. 317 |
| Ruthenium Bipyridyl Complexes as Sensors | p. 319 |
| Calixarene Complexants | p. 320 |
| Optical Reporters on Calixarenes | p. 320 |
| Redox Reporters on Calixarenes | p. 326 |
| Lanthanide Reporters on Calixarenes | p. 326 |
| Macrocyclic Complexants | p. 327 |
| N, O, and S-Donors | p. 328 |
| Azamacrocycles | p. 332 |
| Cryptands | p. 334 |
| Porphyrins and Pyrroles | p. 336 |
| Crown Ethers and Cryptands for Alkali and Alkaline Earth Chemosensors | p. 338 |
| Naphthalene and Anthracene Reporters | p. 339 |
| Iron Sulfur Cluster Reporters | p. 344 |
| Structural Features | p. 344 |
| Sensors for Biological Applications | p. 345 |
| Sodium | p. 346 |
| Potassium | p. 347 |
| Calcium | p. 347 |
| Zinc | p. 349 |
| Lanthanides | p. 351 |
| Signal Transmission | p. 352 |
| Solid State Sensors | p. 353 |
| Sensors for Anions | p. 355 |
| Acyclic Ligating Sites | p. 355 |
| Calixarenes | p. 357 |
| Molecular Computation | p. 359 |
| Index | p. 365 |
| Table of Contents provided by Syndetics. All Rights Reserved. |
ISBN: 9780306467226
ISBN-10: 0306467224
Series: Modern Inorganic Chemistry
Published: 31st December 2001
Format: Hardcover
Language: English
Number of Pages: 392
Audience: General Adult
Publisher: Springer Nature B.V.
Country of Publication: US
Dimensions (cm): 23.39 x 15.6 x 2.24
Weight (kg): 0.79
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