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Modern Aspects of Electrochemistry : Modern Aspects of Electrochemistry - John O'M. Bockris

Modern Aspects of Electrochemistry

Modern Aspects of Electrochemistry

By: John O'M. Bockris (Editor), Ralph E. White (Editor), Brian E. Conway (Editor)

Hardcover Published: 31st January 1998
ISBN: 9780306456503
Number Of Pages: 350

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Prof. Jerzy Sobkowski starts off this 31st volume of Modern Aspects of Electrochemistry with a far-ranging discussion of experimental results from the past 10 years of interfacial studies. It forms a good background for the two succeeding chapters. The second chapter is by S. U. M. Khan on quantum mechanical treatment of electrode processes. Dr. Khan's experience in this area is a good basis for this chapter, the contents of which will surprise some, but which as been well refereed. Molecular dynamic simulation is now a much-used technique in physical electrochemistry and in the third chapter Ilan Benjamin has written an account that brings together information from many recent publications, sometimes confirming earlier modeling approaches and sometimes breaking new territory. In Chapter 4, Akiko Aramata's experience in researching single crystals is put to good advantage in her authoritative article on under- tential deposition. Finally, in Chapter 5, the applied side of electrochemistry is served by Bech-Neilsen et al. in the review of recent techniques for automated measurement of corrosion. J. O'M. Bockris, Texas A&M University B. E. Conway, University of Ottawa R. E. White, University of South Carolina Contents Chapter 1 METAL/SOLUTION INTERFACE: AN EXPERIMENTAL APPROACH Jerzy Sobkowski and Maria Jurkiewicz-Herbich I. Introduction.............................................. 1 II. Molecular Approach to the Metal/Solution Interface............. 3 1. Double-Layer Structure: General Considerations .......... 3 2. Solid Metal/Electrolyte Interface.......................... 8 3. Methods Used to Study Properties ofthe Metal/Solution Interface: Role of the Solvent and the Metal............. 15 The Thermodynamic Approach to the Metal/Solution Interface 35 III.

The Potential of Zero Charge
Introductory Concepts
Experimental Aspects
Analysis of the Experimental Data
Conclusions
References
Nonequilibrium Fluctuations in Corrosion Process
Introduction
Active, Passive and Transpassive States of Metals
Nonequilibrum Fluctuations in Corrosion
Conclusion
References
Conducting Polymers, Electrochemistry and Biomimicking Processes
Introduction
Electropolymerization of Conducting polymers
Electrochemical versus Chemical Polymerization of Conducting Polymers
Selfdoped Polymers, Polymeric Composites and Hybrid Materials
Physical Properties of Dry Conducting Polymers
Electrochemical Properties
Electrochemistry and Electrode Structures
Experimental Chronoamperograms and Chronocoulograms Under Conformational Relaxation Control
Polymer-Solvent Interactions from the ESCR Model
Chronocoulograms Under Conformational Relaxation Control
Voltammetry Under Conformational Relxation Control
Experimental and Theoretical Voltammograms
Experimental and Theoretical Coulovoltagrams
Conducting Polymers as Soft and Nonstoichiometric Materials
Electrochemical Evidences
Conducting Polymers as Three-Dimensional Electrodes at Molecular level
Soft, Wet and Complex Materials Mimicking Biological Processes
Technological Applications of the ESCR Model
Microwave (Photo)Electrochemistry
Introduction
Experimental
Theoretical Challenge
Potential Dependent Stationary Microwave Conductivity Measurements
Potential Dependent Time Resolved Measurements
Potential Dependent Periodical Measurements
Oxides and Sensitization Cells
Microwave Phase Measurements
Summary and Discussion
Acknowledgements
References
Figure Legends
Improvements in Fluorine Generations
Introduction
A Caution
The Challenge
Acknowledgements
References
Table of Contents provided by Publisher. All Rights Reserved.

ISBN: 9780306456503
ISBN-10: 0306456508
Series: Modern Aspects of Electrochemistry : Book 31
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 350
Published: 31st January 1998
Publisher: Springer Science+Business Media
Country of Publication: US
Dimensions (cm): 22.86 x 15.24  x 3.18
Weight (kg): 0.61