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Metalloporphyrins Catalyzed Oxidations : Catalysis by Metal Complexes - F. Montanari

Metalloporphyrins Catalyzed Oxidations

Catalysis by Metal Complexes

By: F. Montanari (Editor), L. Casella (Editor)

Hardcover

Published: 28th February 1994
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Oxidative catalysis by metalloporphyrin systems occupies a prominent role in the current research in the fields of chemical and biological catalysis. Our particular interest and approach has been to collect in the same volume papers dealing with both the chemical and biological aspects of the reactivity of heme systems because of the realization that a better understanding of the complementary discipline can be extremely useful for the researchers from either field. The current progress of the research on synthetic metalloporphyrin catalysts has led to the development of several systems that are able to reproduce the heme-enzyme mediated oxygenation and oxidation reactions, at least in terms of reaction types, mechanisms and often rates. These achievements have stimulated the of creating metalloporphyrin catalysts which are both ambitious project efficient and stable enough to become competitive for large-scale industrial processes. Although this project is still far from being realized, the efforts in this direction parallel those aimed at the application of heme enzymes to chemical technologies, e. g. for the mild, selective oxidation of organics or the detoxification of pollutants. Both the two approaches will be advantageous because while the enzyme systems can achieve selectivities which are probably unattainable by synthetic catalysts, the latter can be active under experimental conditions that would readily inactivate the enzymes.

General Overview on Oxidations Catalyzed by Metalloporphyrins
The Synthesis of Meso-Substituted Porphyrins
Oxidation of Alkanes
Oxidations Catalyzed by Ruthenium Porphyrins
T. Mlodnicka
Oxygenation Reactions under Two-Phase Conditions
Nitrene and Carbene Transfer Catalyzed by Metalloporphyrins
On the Electronic Structure of Oxo-Metalloporphyrins and Mechanistic Aspects of Oxygen-Transfer Reactions
Biological Oxidations: Stereochemical Aspects
Index
Table of Contents provided by Publisher. All Rights Reserved.

ISBN: 9780792326571
ISBN-10: 0792326571
Series: Catalysis by Metal Complexes
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 354
Published: 28th February 1994
Publisher: Springer
Country of Publication: NL
Dimensions (cm): 23.4 x 15.6  x 2.54
Weight (kg): 1.54