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Metal Ion Separation and Preconcentration : Progress and Opportunities - Andrew H. Bond

Metal Ion Separation and Preconcentration

Progress and Opportunities

By: Andrew H. Bond (Editor), Mark L. Dietz (Editor), Robin D. Rogers (Editor)

Hardcover Published: 1st January 1999
ISBN: 9780841235946
Number Of Pages: 400

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Metal ion separation and preconcentration constitute the pivotal step in numerous analytical, purification, and waste treatment processes. Increasing environmental regulations and growing economic incentives imply that separation science will be essential to the future of industrial processing. This volume offers a broad perspective of advances in the field while also including up-to-date work in a number of specialized areas. It begins with an overview which describes the objectives the book, summarizes each chapter, and presents some immediate challenges for the future. Two review chapters then address the status of metal ion separations in nuclear energy and defense-related programs. These are followed by twenty chapters covering a range of topics, including aqueous phases in separations, extractant design and synthesis, solvent extraction, solid-liquid distribution, separations using membranes, centrifugal partition and countercurrent chromatography, and supercritical fluid extraction systems. Together the essays provide a fine balance of fundamental and applied research, making the book invaluable for both novice and experienced practitioners.

"A volume containing 23 contributions, divided into seven sections: overviews; aqueous systems; extractant design and synthesis; separations using liquid-liquid systems; separations using solid- liquid systems; separations using membranes; and separations using chromatographic and supercritical fluid extraction systems. Topics include both novel separations media and methodology and recent developments in established separation techniques, with an emphasis on providing a picture of the state-of-the-art in the field. Suitable for the novice and experienced practitioner, as well as basic researchers who work in metal ion complexation and separation. Also of likely interest to those interested in the application of metal ion separations methods to problems in waste treatment, environmental remediation, and chemical analysis."--SciTech Book News"New technologies and concepts in the field of metal-ion separations are explored in this volume in the Symposium Series. The book is directed toward both new and experienced practitioners of separation science as well as scientists interested in the application of metal-ion separations to environmental problems. The book is organized into six sections: Aqueous Systems, Extractant Design and Synthesis, Separations Using Liquid-Liquid Systems, Separations Using Solid-Liquid Systems, Separations Using Membranes, and Separations Using Chromatographic and Supercritical Fluid Extraction Systems. Three overview chapters are also included."--Journal of the American Chemical Society "A volume containing 23 contributions, divided into seven sections: overviews; aqueous systems; extractant design and synthesis; separations using liquid-liquid systems; separations using solid- liquid systems; separations using membranes; and separations using chromatographic and supercritical fluid extraction systems. Topics include both novel separations media and methodology and recent developments in established separation techniques, with an emphasis on providing a picture of the state-of-the-art in the field. Suitable for the novice and experienced practitioner, as well as basic researchers who work in metal ion complexation and separation. Also of likely interest to those interested in the application of metal ion separations methods to problems in waste treatment, environmental remediation, and chemical analysis."--SciTech Book News"New technologies and concepts in the field of metal-ion separations are explored in this volume in the Symposium Series. The book is directed toward both new and experienced practitioners of separation science as well as scientists interested in the application of metal-ion separations to environmental problems. The book is organized into six sections: Aqueous Systems, Extractant Design and Synthesis, Separations Using Liquid-Liquid Systems, Separations Using Solid-Liquid Systems, Separations Using Membranes, and Separations Using Chromatographic and Supercritical Fluid Extraction Systems. Three overview chapters are also included."--Journal of the American Chemical Society "A volume containing 23 contributions, divided into seven sections: overviews; aqueous systems; extractant design and synthesis; separations using liquid-liquid systems; separations using solid- liquid systems; separations using membranes; and separations using chromatographic and supercritical fluid extraction systems. Topics include both novel separations media and methodology and recent developments in established separation techniques, with an emphasis on providing a picture of the state-of-the-art in the field. Suitable for the novice and experienced practitioner, as well as basic researchers who work in metal ion complexation and separation. Also of likely interest to those interested in the application of metal ion separations methods to problems in waste treatment, environmental remediation, and chemical analysis."--SciTech Book News "New technologies and concepts in the field of metal-ion separations are explored in this volume in the Symposium Series. The book is directed toward both new and experienced practitioners of separation science as well as scientists interested in the application of metal-ion separations to environmental problems. The book is organized into six sections: Aqueous Systems, Extractant Design and Synthesis, Separations Using Liquid-Liquid Systems, Separations Using Solid-Liquid Systems, Separations Using Membranes, and Separations Using Chromatographic and Supercritical Fluid Extraction Systems. Three overview chapters are also included."--Journal of the American Chemical Society "A volume containing 23 contributions, divided into seven sections: overviews; aqueous systems; extractant design and synthesis; separations using liquid-liquid systems; separations using solid- liquid systems; separations using membranes; and separations using chromatographic and supercritical fluid extraction systems. Topics include both novel separations media and methodology and recent developments in established separation techniques, with an emphasis on providing a picture of the state-of-the-art in the field. Suitable for the novice and experienced practitioner, as well as basic researchers who work in metal ion complexation and separation. Also of likely interest to those interested in the application of metal ion separations methods to problems in waste treatment, environmental remediation, and chemical analysis."--SciTech Book News "New technologies and concepts in the field of metal-ion separations are explored in this volume in the Symposium Series. The book is directed toward both new and experienced practitioners of separation science as well as scientists interested in the application of metal-ion separations to environmental problems. The book is organized into six sections: Aqueous Systems, Extractant Design and Synthesis, Separations Using Liquid-Liquid Systems, Separations Using Solid-Liquid Systems, Separations Using Membranes, and Separations Using Chromatographic and Supercritical Fluid Extraction Systems. Three overview chapters are also included."--Journal of the American Chemical Society "A volume containing 23 contributions, divided into seven sections: overviews; aqueous systems; extractant design and synthesis; separations using liquid-liquid systems; separations using solid- liquid systems; separations using membranes; and separations using chromatographic and supercriticalfluid extraction systems. Topics include both novel separations media and methodology and recent developments in established separation techniques, with an emphasis on providing a picture of the state-of-the-art in the field. Suitable for the novice and experienced practitioner, as well as basicresearchers who work in metal ion complexation and separation. Also of likely interest to those interested in the application of metal ion separations methods to problems in waste treatment, environmental remediation, and chemical analysis."--SciTech Book News"New technologies and concepts in the field of metal-ion separations are explored in this volume in the Symposium Series. The book is directed toward both new and experienced practitioners of separation science as well as scientists interested in the application of metal-ion separations toenvironmental problems. The book is organized into six sections: Aqueous Systems, Extractant Design and Synthesis, Separations Using Liquid-Liquid Systems, Separations Using Solid-Liquid Systems, Separations Using Membranes, and Separations Using Chromatographic and Supercritical Fluid ExtractionSystems. Three overview chapters are also included."--Journal of the American Chemical Society

Preface
Progress in Metal Ion Separation and Preconcentration: An Overviewp. 2
Future of Separation Science in U.S. Department of Energy Processing and Remediationp. 13
Solvent Extraction in the Treatment of Acidic High-Level Liquid Waste: Where Do We Stand?p. 20
Aqueous Complexes in f-Element Separation Sciencep. 52
Metal Ion Separations in Aqueous Biphasic Systems and Using Aqueous Biphasic Extraction Chromatographyp. 79
A Molecular Mechanics Method for Predicting the Influence of Ligand Structure on Metal Ion Binding Affinityp. 102
Ligand Design for Small Cations: The Li[superscript +]/14-Crown-4 Systemp. 114
Synthesis of Novel Azamacrocyclic Metal Ion Receptors Using a Modified Mannich Aminomethylation Reactionp. 133
Metal Ion Separations with Proton-Ionizable Lariat Ethersp. 146
Redox-Recyclable Extraction and Recovery of Heavy Metal Ions and Radionuclides from Aqueousp. 156
Structural Basis of Selectivity in Tunnel Type Inorganic Ion Exchangersp. 168
Metal Ion Separations with Lariat Ether Ion-Exchange Resinsp. 183
Design of Novel Polymer-Supported Reagents for Metal Ion Separationsp. 194
Recent Advances in the Chemistry and Applications of the Diphonix Resinsp. 206
Reillex-HPQ Anion Exchange Column Chromatography: Removal of Pertechnetate Ion from DSSF-5 Simulantp. 219
Extraction Chromatography: Progress and Opportunitiesp. 234
Metal-Ion Separations Using SuperLig or AnaLig Materials Encased in Empore Cartridges and Disksp. 251
Biologically Generated Materials for Metal-Ion Binding: Answers to Some Fundamental Chemical Questionsp. 260
Use of Ligand-Modified Micellar-Enhanced Ultrafiltration to Selectively Remove Copper from Waterp. 280
Water-Soluble Metal-Binding Polymers with Ultrafiltrationp. 294
Different Two-Phase Liquid Systems for Inorganic Separations by Countercurrent Chromatographyp. 333
Fundamental Aspects of Metal-Ion Separations by Centrifugal Partition Chromatographyp. 347
Extraction and Separation of Uranium and Lanthanides with Supercritical Fluidsp. 390
Author Indexp. 403
Subject Indexp. 405
Table of Contents provided by Blackwell. All Rights Reserved.

ISBN: 9780841235946
ISBN-10: 0841235945
Series: ACS Symposium Series
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 400
Published: 1st January 1999
Publisher: American Chemical Society
Country of Publication: US
Dimensions (cm): 23.5 x 15.4  x 2.7
Weight (kg): 0.73