Mechanochemistry Of Solid Surfaces - Emmanuel M Gutman

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Mechanochemistry Of Solid Surfaces

By: Emmanuel M Gutman

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Hardcover | 1 December 1994

At a Glance

Hardcover
332 Pages

Dimensions(cm)
22.86 x 16.51 x 2.54

Hardcover

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This book covers the fundamental relationships between solid surface chemical reactivity and the stressed state of surface layers; developed mainly by the author. Acceleration of chemical reactions by mechanical action (mechanochemical effect) and near-surface plasticity increase caused by chemical reactions (chemomechanical effect) acting simultaneously; open new possibilities for the control of a wide range of processes from corrosion to new materials engineering.This monograph is a unique work on this subject and will be essential reading for undergraduate and postgraduate students engaged in studying surface phenomena in materials science; chemistry and chemical engineering; as well as for scientists and engineers in the industries where these phenomena are important.

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Preface
Table of Contents
Introduction	p. 1
Thermodynamics and kinetics of surface chemical reactions on stressed solids	p. 7
Surface tension and surface layer energy	p. 7
Mechanochemical excitation model for perfect and real solids	p. 13
Symmetry of Gibbs function change under compression and tension	p. 19
Kinetics of mechanochemical and mechanoelectrochemical reactions	p. 22
Mechanochemical dissolution of elastically stressed metals	p. 33
Mechanochemical dissolution of mineral single crystals	p. 39
Mechanochemical activity of solids with structural defects	p. 45
Characterization of solids with structural defects	p. 45
Mechanoelectrical phenomena	p. 52
Chemical potential of dislocations	p. 68
Relationships between local and integral mechanochemical activity of surfaces	p. 79
Surface distribution of electrode potential and anodic current density around a single dislocation and piled-up array	p. 79
Selective dissolution of slip bands and controlled etching	p. 86
Localization of change in the electron work of exit	p. 91
Microelectrochemical heterogeneity	p. 96
Kinetics of mechanochemical effect in solids with dislocations	p. 113
Kinetic equations and dependence of mechanochemical effect on the stages of plastic deformation	p. 113
Inhibition of mechanochemical effect	p. 151
Stress corrosion cracking	p. 161
Electrochemical mechanism of mechanochemical dissolution of iron	p. 174
Chemomechanical effect and conjugate mechanochemical phenomena	p. 187
Irreversible processes of chemical reactions, plastic deformation and dispersing of solids	p. 187
Chemomechanical effect	p. 195
Conjugate phenomena and crossing effects	p. 210
Some applications of mechanochemical phenomena	p. 223
Mechanochemical surface treatment	p. 223
Deep drawing of high-strength alloys	p. 232
Strength and life time prediction of corroding metal structures	p. 236
Mechanochemistry of low-cycling corrosion fatigue	p. 257
Electrochemical protection of corrosion-mechanical crack	p. 269
Mechanochemical heterogeneity of large-scale structures	p. 282
Mechanochemical behavior of welded joints	p. 288
References	p. 307
List of Symbols	p. 313
Table of Contents provided by Blackwell. All Rights Reserved.

Mechanochemistry Of Solid Surfaces

At a Glance

Hardcover

Shipping

How to return your order

Defective items

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