I. Electron Transfer Reactions.- 1. Electron Transfer: General and Theoretical.- 1.1. Overview of Reactions in Fluid Media.- 1.2. The Electronic Coupling Problem (Ke/).- 1.2.1. The Distance Dependence of Electron Transfer Rates.- 1.2.2. The "Inverted Region".- 1.2.3. Related Excited-State Energy-Transfer Processes.- 1.3. Medium Effects: Thermodynamic.- 1.4. Medium Effects: Kinetic.- 1.4.1. Conformational Effects.- 1.4.2. Slow and Fast Solvation: Theory.- 1.4.3. Effects of "Slow" Solvent Relaxation Processes.- 1.4.4. Effects of "Fast" Solvent Relaxation Processes.- 1.5. Optical Electron Transfer (Intervalence Transitions).- 1.5.1. Medium Effects on Intervalence Charge Transfer.- 1.6. Charge-Transfer Excited-State Relaxation and Excited State Reactions.- 1.7. Gas Phase Reactions.- 1.7.1. Atom-Atom Reactions.- 1.7.2. Reactions Involving Molecules.- 1.8. Electron Transfer in the Solid State.- 2. Redox Reactions between Two Metal Complexes.- 2.1. Introduction.- 2.2. Reactions of Metal Aqua and Oxo Ions.- 2.2.1. Titanium(III) and (IV).- 2.2.2. Vanadium(IV) and (V).- 2.2.3. Chromium(II).- 2.2.4. Manganese(VI).- 2.2.5. Iron(II) and Ruthenium(II).- 2.2.6. Uranium(IV) and (VI).- 2.2.7. Miscellaneous Reactions.- 2.3. Reactions of Metal Ion Complexes.- 2.3.1. Manganese(III).- 2.3.2. Iron(II) and Ruthenium(II).- 2.3.3. Cobalt(-I), (II), and (III).- 2.3.4. Nickel(II) and Platinum(II).- 2.3.5. Copper(I) and (II).- 2.3.6. Stereoselective Electron Transfer.- 2.3.7. Excited State Reactions.- 2.3.8. Miscellaneous Reactions.- 2.4. Reactions with Metalloproteins.- 2.4.1. Introduction.- 2.4.2. Blue Copper Proteins.- 2.4.3. Hemoglobin and Myoglobin.- 2.4.4. Cytochromes.- 2.4.5. Iron-Sulfur Proteins.- 2.4.6. Hemerythrins.- 3. Metal-Ligand Redox Reactions.- 3.1. Introduction.- 3.2. Oxygen, Peroxide. Water. and Other Oxygen Compounds.- 3.2.1. Dioxygen.- 3.2.2. Hydrogen Peroxide.- 3.2.3. Alkyl Hydroperoxides, Peroxyl Acids. and Metal Peroxides.- 3.2.4. Water and Other Oxygen-Containing Compounds.- 3.3. Nitrogen Compounds and Oxyanions.- 3.3.1. Hydrazine, Azide. Hydroxylamine. and Derivatives.- 3.3.2. Nitrous Oxide, Nitrite. Nitrosonium, Trioxodinitrate Ions, and Nitric Acid.- 3.3.3. N-Oxide Compounds.- 3.3.4. Organic Amines.- 3.3.5. Bipyridinium Ions.- 3.3.6. Aryldiazonium Ions.- 3.4. Halogens. Halides, and Halogen Oxyacids.- 3.4.1. Halogens.- 3.4.2. Halides.- 3.4.3. Oxyhalides.- 3.4.4. Oscillating Reactions.- 3.5. Sulfur Compounds and Oxyanions.- 3.5.1. Peroxodisulfate.- 3.5.2. Sulfur Dioxide and Sulfite Ions.- 3.5.3. Dithionites.- 3.5.4. Thiosulfates.- 3.5.5. Sulfides, Thiols, and Disulfides.- 3.5.6. Sulfoxides.- 3.6. Phosphorus, Arsenic, and Oxycompounds.- 3.6.1. Phosphines/ Arsines.- 3.6.2. Phosphorus Oxyanions.- 3.6.3. Arsenious Compounds.- 3.7. Inorganic Radicals.- 3.8. Hydrogen.- 3.9. Ascorbic Acid, Quinols, Catechols, and Diols.- 3.9.1. Ascorbic Acid.- 3.9.2. Quinols and Catechols.- 3.9.3. Diols, Aliphatic and Aromatic Alcohols.- 3.10 Carboxylic Acids, Carboxylates, Carbon Dioxide, and Carbon Monoxide.- 3.10.1. Carboxylic Acids.- 3.10.2. Carbon Dioxide.- 3.10.3. Carbon Monoxide.- 3.1 1. Alkyl and Aryl Halides.- 3.12. Organic Radicals.- II. Substitutions and Related Reactions.- 4. Reactions of Compounds of the Nonmetallic Elements.- 4.1. Boron.- 4.2. Carbon.- 4.3. Silicon.- 4.4. Germanium.- 4.5. Nitrogen.- 4.6. Phosphorus.- 4.7. Arsenic and Antimony.- 4.8. Oxygen.- 4.9. Sulfur.- 4.10. Selenium and Tellurium.- 4.11. Halogens and Xenon.- 4.11.1. Fluorine.- 4.11.2. Chlorine.- 4.11.3. Bromine.- 4.11.4. Iodine.- 4.11.5. Xenon.- 4.12. Oscillating Reactions.- 5. Substitution Reactions of Inert-Metal Complexes-Coordination Numbers 4 and 5.- 5.1. Introduction.- 5.2. Ligand Replacement at Square-Planar Platinum(II).- 5.3. Ligand Replacement at Square-Planar Palladium(II).- 5.4. Nickel(II) Complexes.- 5.5. Isomerization Reactions.- 5.6. Trans Effect.- 5.7. Five-Coordinate Compounds.- 5.8. Oxidative Additions.- 5.9. Rhodium(I) and Gold(III) Complexes.- 6. Substitution Reactions of Inert-Metal Complexes-Coordination Numbers 6 and Above: Chromium.- 6.1. Introduction.- 6.2. Aquation and Solvolysis of Chromium(III) Complexes.- 6.2.1. [Cr(III)(L5)X]n+ Systems (L = OH2, NH3).- 6.2.2. Cr(III)-C Bond Rupture.- 6.2.3. Amine Complexes.- 6.2.4. Dechelation/Chelation Processes.- 6.3. Formation of Chromium(III) Complexes.- 6.3.1. The Nature of the Cr3+ Cation in Aqueous Solution.- 6.3.2. Anation Reactions.- 6.4. Base Hydrolysis.- 6.5. Oxidation and Reduction of Cr(III) Complexes.- 6.6. Isomerization and Racemization.- 6.7. Photochemistry and Photophysics of Chromium(III) Complexes.- 6.8. The Solid State.- 6.8.1. Single-Crystal X-Ray Structures.- 6.8.2. Synthesis and Solid State Decomposition.- 6.9. Other Oxidation States.- 6.9.1. Chromium(II).- 6.9.2. Chromium(V).- 6.9.3. Chromium(VI).- 6.10. Catalysis.- 6.1 1. Miscellaneous.- 7. Substitution Reactions of Inert-Metal Complexes-Coordination Numbers 6 and Above: Cobalt.- 7.1. Aquation.- 7.2. Catalyzed Aquation.- 7.3. Base Hydrolysis.- 7.4. Anation.- 7.5. Solvolysis.- 7.6. Isomerization.- 7.7. Carbonato Complexes.- 7.8. Cobaloximes and B12.- 7.9. Photochemistry.- 7.10. Miscellaneous.- 8. Substitution Reactions of Inert-Metal Complexes-Coordination Numbers 6 and Above: Other Inert Centers.- 8.1. Introduction.- 8.2. Molybdenum.- 8.3. Tungsten.- 8.4. Technetium.- 8.5. Rhenium.- 8.6. Iron.- 8.6.1. Pentacyanoferrates and Nitrosyls.- 8.6.2. Diimine Complexes.- 8.6.3. Other Complexes.- 8.7. Ruthenium.- 8.8. Osmium.- 8.9. Rhodium.- 8.10. Iridium.- 8.1 1. Platinum(1V).- 8.11.1. General.- 8.11.2. Intramolecular Processes.- 9. Substitution Reactions of Labile Metal Complexes.- 9.1. General.- 9.2. Complex Formation Involving Unsubstituted Metal Ions: Unidentate Ligand Substitution and Solvent Exchange.- 9.2.1. Bivalent Ions.- 9.2.2. Trivalent Ions.- 9.3. Complex Formation Involving Unsubstituted Metal Ions: Multidentate Ligand Substitution.- 9.3.1. Uni- and Bivalent Ions.- 9.3.2. Trivalent Ions.- 9.4. Complex Formation Involving Substituted Metal Ions: Ligand Substitution and Solvent Exchange.- 9.4.1. Uni- and Bivalent Ions.- 9.4.2. Trivalent Ions and Ions of Higher Valency.- 9.5. Ligand Substitution Processes in Dimeric Metal Complexes.- III. Reactions of Organometallic Compounds.- 10. Substitution and Insertion Reactions.- 10.1. Substitution Reactions.- 10.1.1. Mononuclear Complexes.- 10.1.2. Polynuclear Complexes.- 10.2. Insertion Reactions.- 10.2.1. Carbon Monoxide Insertion.- 10.2.2. Alkene Insertion.- 10.2.3. Miscellaneous Insertions.- 11. Metal-Alkyl and Metal-Hydride Bond Formation and Fission; Oxidative Addition and Reductive Elimination.- 11.1. Introduction.- 11.2. Dihydrogen and Trihydrogen Complexes.- 11.3. Metal-Hydride Complexes.- 11.4. C-H Bond Activation.- 11.4.1. Unactivated C-H Bonds.- 11.4.2. Activated C-H Bonds.- 11.4.3. Intramolecular C-H Bonds.- 11.5. Oxidative Addition and Reductive Elimination of Alkyl Halides.- 11.6. Oxidative Addition and Reductive Elimination Involving Two Metal Centers.- 12. Reactivity of Coordinated Ligands.- 12.1. Introduction.- 12.2. Cobalt Complexes.- 12.2.1. Phosphate Esters.- 12.2.2. Carboxylic Acids, Esters, and Amides.- 12.3. Other Metal Complexes.- 12.3.1. Nucleophilic Addition to Nitriles.- 12.3.2. Nucleophilic Addition to Imines.- 12.3.3. Nucleophilic Addition to Carbonyls.- 12.3.4. Reactions of 1, 3-Dicarbonyls and Derivatives.- 12.3.5. Electrophilic Attack at Nitrogen and Oxygen.- 12.3.6. Reactions at Phosphorus.- 12.3.7. Reactions of Sulfur Ligands.- 12.3.8. Reactions of Heterocyclic Ligands.- 12.4. OrganometallicCompounds.- 12.4.1. Reactions with Nucleophiles.- 12.4.2. Reactions with Electrophiles.- 12.4.3. Reactions at Side Chains.- 13. Rearrangements. Intramolecular Exchanges. and Isomerizations of Organometallic Compounds.- 13.1. Introduction.- 13.2. Mononuclear Compounds.- 13.2.1. Isomerizations and Ligand Site Exchange.- 13.2.2. Ligand Rotations about the Metal-Ligand Bond.- 13.2.3. Migration of Metal Atoms between Different Ligand Sites.- 13.2.4. Agostic Bonding and Hydrogen Atom Migrations.- 13.2.5. Internal Ligand Rearrangements.- 13.3. Dinuclear Compounds.- 13.3.1. Rotation about the Metal-Metal Direction.- 13.3.2. Carbonyl Ligand Migrations.- 13.3.3. Migration of Other Ligands between Metal Atoms.- 13.3.4. Other Exchange Reactions.- 13.4. Cluster Compounds.- 13.4.1. Rearrangements Involving the Relative Motion of Metal Atoms in a Cluster.- 13.4.2. Carbonyl Ligand Exchanges.- 13.4.3. Other Exchange Reactions.- 14. Homogeneous Catalysis of Organic Reactions by Transition Metal Complexes.- 14.1. General Reviews.- 14.2. Hydrogenations.- 14.2.1. Asymmetric Hydrogenations.- 14.3. Dehydrogenation and Hydrogen Transfer.- 14.4. Isomerizations.- 14.5. C-H Activation.- 14.6. Olefin Metathesis.- 14.7. Olefin Polymerizations.- 14.8. Alkyne Polymerizations.- 14.9. Hydrosilylations.- 14.10. Catalyzed Addition Reactions.- 14.11. Olefin Oligomerizations.- 14.12. Alkyne Oligomerizations.- 14.13. Carbonylations.- 14.13.1. Carbonylation of Alkenes and Alkynes.- 14.13.2. Hydroformylations.- 14.13.3. Water-Gas Shift Reactions.- 14.13.4. Ethylene Glycol Synthesis.- 14.13.5. Carbonylation of Alcohols and Amines.- 14.13.6. Carbonylation of Organic Halides.- 14.14. C-C Cross-Coupling Reactions.- IV. Compilations of Numerical Data.- 15. Volumes of Activation for Inorganic and Organometallic Reactions: A Tabulated Compilation.- 15.1. Introduction.- 15.2. Data in Tabular Form.- References.
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