| Some Aspects of Structure and Bonding in Main Group Chemistry | p. 1 |
| Introduction | p. 1 |
| Ionization Energy, Electron Affinity and Electronegativity | p. 2 |
| Periodic Trends among the Main Group Elements | p. 5 |
| Valence Shell Electron Pair Repulsion Theory | p. 7 |
| Molecular Orbital Theory | p. 15 |
| The Chemistry of Hydrogen | p. 20 |
| Introduction | p. 20 |
| The Element | p. 21 |
| The Chemistry of Hydrogen | p. 23 |
| Hydrides | p. 24 |
| Compounds containing Hydrogen formally as H[superscript +] | p. 27 |
| The Hydrogen Bond | p. 28 |
| The Group 1 (Alkali Metal) Elements: Lithium, Sodium, Potassium, Rubidium, Caesium and Francium | p. 33 |
| Introduction and Oxidation State Survey | p. 33 |
| The Elements | p. 34 |
| Chemistry of the Alkali Metals | p. 35 |
| Simple Salts of the Alkali Metals | p. 36 |
| Compounds with Oxygen and Sulfur | p. 39 |
| Compounds with Nitrogen | p. 40 |
| Hydrides | p. 41 |
| Compounds with Carbon | p. 41 |
| Alkali Metal Complexes | p. 42 |
| Similarities in the Chemistry of Lithium and Magnesium | p. 43 |
| The Group 2 Elements: Beryllium, Magnesium, Calcium, Strontium, Barium and Radium | p. 46 |
| Introduction and Oxidation State Survey | p. 46 |
| The Elements | p. 47 |
| Simple Compounds and Salts | p. 47 |
| Compounds with Oxygen and Sulfur | p. 50 |
| Compounds with Nitrogen | p. 51 |
| Hydrides | p. 52 |
| Compounds with Carbon | p. 52 |
| Group 2 Metal Complexes | p. 54 |
| Similarities in the Chemistry of Beryllium and Aluminium | p. 55 |
| The Group 13 Elements: Boron, Aluminium, Gallium, Indium and Thallium | p. 57 |
| Introduction and Oxidation State Survey | p. 57 |
| The Elements | p. 58 |
| Chemistry of the Elements | p. 59 |
| Borides | p. 59 |
| Halides | p. 60 |
| Hydrides and Organometallic Compounds | p. 63 |
| Oxides, Hydroxides and Oxyanions | p. 69 |
| Compounds with Groups 15 and 16 Elements | p. 71 |
| Aquated and Related Complex Cations | p. 73 |
| The Group 14 Elements: Carbon, Silicon, Germanium, Tin and Lead | p. 76 |
| Introduction and Oxidation State Survey | p. 76 |
| The Elements | p. 77 |
| Chemistry of the Elements | p. 80 |
| Group 14 Hydrides and Organometallic Compounds | p. 81 |
| Group 14 Halides | p. 82 |
| Carbides and Silicides | p. 84 |
| Oxides | p. 85 |
| Sulfides, Selenides and Tellurides | p. 88 |
| Polyatomic Anions of the Group 14 Elements | p. 88 |
| The Group 15 (Pnictogen) Elements: Nitrogen, Phosphorus, Arsenic, Antimony and Bismuth | p. 92 |
| Introduction and Oxidation State Survey | p. 92 |
| The Elements | p. 93 |
| Hydrides | p. 95 |
| Oxides | p. 98 |
| Sulfides | p. 102 |
| Oxyanions and Oxyacids | p. 103 |
| Halides | p. 105 |
| Nitrides and Phosphides | p. 107 |
| The Group 16 (Chalcogen) Elements: Oxygen, Sulfur, Selenium, Tellurium and Polonium | p. 110 |
| Introduction and Oxidation State Survey | p. 110 |
| The Elements | p. 111 |
| Hydrides and Related Species | p. 113 |
| Halides | p. 118 |
| Oxides | p. 120 |
| Oxyhalides of Sulfur, Selenium and Tellurium | p. 121 |
| Oxyacids of Sulfur, Selenium and Tellurium | p. 122 |
| Polychalcogen Cations | p. 124 |
| The Group 17 (Halogen) Elements: Fluorine, Chlorine, Bromine, Iodine and Astatine | p. 128 |
| Introduction and Oxidation State Survey | p. 128 |
| The Elements | p. 129 |
| Chemistry of the Elements | p. 130 |
| Hydrogen Halides, HX, and Halide Salts, X[superscript -] | p. 131 |
| Halogen Oxides | p. 132 |
| Oxyacids and Oxyanions of the Halogens | p. 134 |
| Interhalogen Compounds | p. 137 |
| The Chemistry of Astatine | p. 142 |
| The Group 18 (Noble Gas) Elements: Helium, Neon, Argon, Krypton, Xenon and Radon | p. 146 |
| Introduction and Oxidation State Survey | p. 146 |
| The Elements | p. 148 |
| Noble Gas Halides | p. 149 |
| Reactions of Noble Gas Fluorides with Fluoride Ion Acceptors and Donors | p. 151 |
| Xenon-Oxygen Compounds | p. 152 |
| Xenon and Krypton Compounds with Bonds to Elements other than O and F | p. 154 |
| The Group 12 Elements: Zinc, Cadmium and Mercury | p. 157 |
| Introduction | p. 157 |
| The Elements | p. 158 |
| Chemistry of the Elements | p. 158 |
| Halides | p. 158 |
| Chalcogenides and Related Compounds | p. 159 |
| Oxygen Compounds | p. 160 |
| Formation of Coordination Complexes | p. 161 |
| Low-valent Compounds | p. 162 |
| Selected Polymeric Main Group Compounds | p. 165 |
| Introduction | p. 165 |
| Polyphosphates | p. 165 |
| Silicates | p. 168 |
| Silicone Polymers | p. 173 |
| Polyphosphazenes | p. 174 |
| Further Reading | p. 177 |
| Answers to Problems | p. 179 |
| Subject Index | p. 194 |
| Table of Contents provided by Syndetics. All Rights Reserved. |