
Magnetism
From Fundamentals to Nanoscale Dynamics
By:Â Hans Christoph Siegmann, Joachim Stohr
Hardcover | 15 September 2006
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844 Pages
24.3 x 16.1 x 3.3
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This text book gives a comprehensive account of magnetism, one of the oldest yet most vibrant fields of physics. Perhaps uniquely, it discusses spin transport and magnetization dynamics phenomena associated with atomically and spin engineered nano-structures. It does this against the backdrop of spintronics and magnetic storage and memory applications. In addition to summarizing developments in this new field of research the book also discusses magnetism applying synchrotron radiation. In short, the book reviews the fundamental physical concepts of the subject and uses them in a coherent fashion to explain some of the problems and applications at the forefront of magnetism. The book is written for undergraduate and graduate level students, and it should also serve as a state-of-the-art reference for scientists in academia and research laboratories.
| Introduction | p. 1 |
| Magnetism: Magical yet Practical | p. 1 |
| History of Magnetism | p. 3 |
| Magnetism, Neutrons, Polarized Electrons, and X-rays | p. 12 |
| Spin Polarized Electrons and Magnetism | p. 15 |
| Polarized X-rays and Magnetism | p. 22 |
| Developments in the Second Half of the 20th Century | p. 25 |
| Some Thoughts about the Future | p. 30 |
| About the Present Book | p. 32 |
| Fields and Moments | |
| Electric Fields, Currents, and Magnetic Fields | p. 39 |
| Signs and Units in Magnetism | p. 39 |
| The Electric Field | p. 39 |
| The Electric Current and its Magnetic Field | p. 40 |
| High Current Densities | p. 45 |
| Magnetic and Electric Fields inside Materials | p. 47 |
| The Relation of the Three Magnetic Vectors in Magnetic Materials | p. 49 |
| Stray and Demagnetizing Fields of Thin Films | p. 52 |
| Applications of Stray and Demagnetizing Fields | p. 54 |
| Symmetry Properties of Electric and Magnetic Fields | p. 57 |
| Parity | p. 57 |
| Time Reversal | p. 59 |
| Magnetic Moments and their Interactions with Magnetic Fields | p. 61 |
| The Classical Definition of the Magnetic Moment | p. 61 |
| From Classical to Quantum Mechanical Magnetic Moments | p. 64 |
| The Bohr Magneton | p. 65 |
| Spin and Orbital Magnetic Moments | p. 66 |
| Magnetic Dipole Moments in an External Magnetic Field | p. 68 |
| The Energy of a Magnetic Dipole in a Magnetic Field | p. 69 |
| The Force on a Magnetic Dipole in an Inhomogeneous Field | p. 72 |
| The Stern-Gerlach Experiment | p. 74 |
| The Mott Detector | p. 79 |
| Magnetic Force Microscopy | p. 83 |
| The Torque on a Magnetic Moment in a Magnetic Field | p. 84 |
| Precession of Moments | p. 85 |
| Damping of the Precession | p. 87 |
| Magnetic Resonance | p. 91 |
| Time-Energy Correlation | p. 97 |
| The Heisenberg Uncertainty Principle | p. 97 |
| Classical Spin Precession | p. 98 |
| Quantum Mechanical Spin Precession | p. 99 |
| Time Dependent Fields | p. 105 |
| Overview | p. 105 |
| Basic Concepts of Relativistic Motion | p. 106 |
| Length and Time Transformations Between Inertial Systems | p. 106 |
| Electric and Magnetic Field Transformations between Inertial Systems | p. 107 |
| Fields of a Charge in Uniform Motion: Velocity Fields | p. 109 |
| Characteristics of Velocity Fields | p. 109 |
| Creation of Large Currents and Magnetic Fields | p. 112 |
| Creation of Ultrashort Electron Pulses and Fields | p. 115 |
| The Temporal Nature of Velocity Fields | p. 118 |
| Acceleration Fields: Creation of EM Radiation | p. 121 |
| Polarized X-rays: Synchrotron Radiation | p. 125 |
| Brighter and Shorter X-ray Pulses: From Undulators to Free Electron Lasers | p. 133 |
| Polarized Electromagnetic Waves | p. 141 |
| Maxwell's Equations and their Symmetries | p. 142 |
| The Electromagnetic Wave Equation | p. 143 |
| Intensity, Flux, Energy, and Momentum of EM Waves | p. 145 |
| The Basis States of Polarized EM Waves | p. 147 |
| Photon Angular Momentum | p. 147 |
| Linearly Polarized Basis States | p. 148 |
| Circularly Polarized Basis States | p. 149 |
| Chirality and Angular Momentum of Circular EM Waves | p. 153 |
| Summary of Unit Polarization Vectors | p. 154 |
| Natural and Elliptical Polarization | p. 155 |
| Natural Polarization | p. 155 |
| Elliptical Polarization | p. 156 |
| The Degree of Photon Polarization | p. 157 |
| Transmission of EM Waves through Chiral and Magnetic Media | p. 159 |
| History and Concepts of Magnetic Interactions | |
| Exchange, Spin-Orbit, and Zeeman Interactions | p. 167 |
| Overview | p. 167 |
| The Spin Dependent Atomic Hamiltonian or Pauli Equation | p. 169 |
| Independent Electrons in a Central Field | p. 170 |
| Interactions between two Particles - Symmetrization Postulate and Exclusion Principle | p. 172 |
| The Exchange Interaction | p. 175 |
| Electron Exchange in Atoms | p. 175 |
| Electron Exchange in Molecules | p. 180 |
| Magnetism and the Chemical Bond | p. 186 |
| From Molecules to Solids | p. 188 |
| The Heisenberg Hamiltonian | p. 190 |
| The Hubbard Hamiltonian | p. 193 |
| Heisenberg and Hubbard Models for H[subscript 2] | p. 195 |
| Summary and Some General Rules for Electron Exchange | p. 202 |
| The Spin-Orbit Interaction | p. 203 |
| Fine Structure in Atomic Spectra | p. 203 |
| Semiclassical Model for the Spin-Orbit Interaction | p. 204 |
| The Spin-Orbit Hamiltonian | p. 206 |
| Importance of the Spin-Orbit Interaction | p. 209 |
| Hund's Rules | p. 209 |
| The Zeeman Interaction | p. 212 |
| History and Theory of the Zeeman Effect | p. 212 |
| Zeeman Versus Exchange Splitting of Electronic States | p. 218 |
| Importance of the Zeeman Interaction | p. 220 |
| Electronic and Magnetic Interactions in Solids | p. 221 |
| Chapter Overview | p. 221 |
| Localized versus Itinerant Magnetism: The Role of the Centrifugal Potential | p. 223 |
| The Relative Size of Interactions in Solids | p. 230 |
| The Band Model of Ferromagnetism | p. 234 |
| The Puzzle of the Broken Bohr Magneton Numbers | p. 234 |
| The Stoner Model | p. 235 |
| Origin of Band Structure | p. 240 |
| Density Functional Theory | p. 243 |
| Ligand Field Theory | p. 245 |
| Independent-Electron Ligand Field Theory | p. 247 |
| Multiplet Ligand Field Theory | p. 256 |
| The Importance of Electron Correlation and Excited States | p. 261 |
| Why are Oxides often Insulators? | p. 262 |
| Correlation Effects in Rare Earths and Transition Metal Oxides | p. 264 |
| From Delocalized to Localized Behavior: Hubbard and LDA+U Models | p. 271 |
| Magnetism in Transition Metal Oxides | p. 274 |
| Superexchange | p. 274 |
| Double Exchange | p. 279 |
| Colossal Magnetoresistance | p. 282 |
| Magnetism of Magnetite | p. 283 |
| RKKY Exchange | p. 290 |
| Point-like Spins in a Conduction Electron Sea | p. 291 |
| Metallic Multilayers | p. 292 |
| Spin-Orbit Interaction: Origin of the Magnetocrystalline Anisotropy | p. 294 |
| The Bruno Model | p. 295 |
| Description of Anisotropic Bonding | p. 297 |
| Bonding, Orbital Moment, and Magnetocrystalline Anisotropy | p. 299 |
| Polarized Electron and X-Ray Techniques | |
| Polarized Electrons and Magnetism | p. 313 |
| Introduction | p. 313 |
| Generation of Spin-Polarized Electron Beams | p. 314 |
| Separation of the Two Spin States | p. 314 |
| The GaAs Spin-Polarized Electron Source | p. 315 |
| Spin-Polarized Electrons and Magnetic Materials: Overview of Experiments | p. 318 |
| Formal Description of Spin-Polarized Electrons | p. 319 |
| Quantum Behavior of the Spin | p. 319 |
| Single Electron Polarization in the Pauli Spinor Formalism | p. 320 |
| Description of a Spin-Polarized Electron Beam | p. 324 |
| Description of Spin Analyzers and Filters | p. 327 |
| Incident Beam Polarization: Spin Analyzer | p. 327 |
| Transmitted Beam Polarization: Spin Filter | p. 328 |
| Determination of Analyzer Parameters | p. 329 |
| Interactions of Polarized Electrons with Materials | p. 329 |
| Beam Transmission through a Spin Filter | p. 329 |
| The Fundamental Interactions of a Spin-Polarized Beam with Matter | p. 331 |
| Interaction of Polarized Electrons with Magnetic Materials: Poincare's Sphere | p. 337 |
| Link Between Electron Polarization and Photon Polarization | p. 342 |
| Photon Polarization in the Vector Field Representation | p. 343 |
| Photon Polarization in the Spinor Representation | p. 344 |
| Transmission of Polarized Photons through Magnetic Materials: Poincare Formalism | p. 345 |
| X-ray Faraday Effect and Poincare Formalism | p. 348 |
| Poincare and Stokes Formalism | p. 350 |
| Interactions of Polarized Photons with Matter | p. 351 |
| Overview | p. 351 |
| Terminology of Polarization Dependent Effects | p. 352 |
| SemiClassical Treatment of X-ray Scattering by Charges and Spins | p. 355 |
| Scattering by a Single Electron | p. 355 |
| Scattering by an Atom | p. 360 |
| SemiClassical Treatment of Resonant Interactions | p. 361 |
| X-ray Absorption | p. 361 |
| Resonant Scattering | p. 364 |
| Correspondence between Resonant Scattering and Absorption | p. 368 |
| The Kramers-Kronig Relations | p. 368 |
| Quantum-Theoretical Concepts | p. 370 |
| One-Electron and Configuration Pictures of X-ray Absorption | p. 370 |
| Fermi's Golden Rule and Kramers-Heisenberg Relation | p. 372 |
| Resonant Processes in the Electric Dipole Approximation | p. 374 |
| The Polarization Dependent Dipole Operator | p. 376 |
| The Atomic Transition Matrix Element | p. 378 |
| Transition Matrix Element for Atoms in Solids | p. 381 |
| The Orientation-Averaged Intensity: Charge and Magnetic Moment Sum Rules | p. 385 |
| The Orientation-Averaged Resonance Intensity | p. 385 |
| Derivation of the Intensity Sum Rule for the Charge | p. 386 |
| Origin of the XMCD Effect | p. 389 |
| Two-Step Model for the XMCD Intensity | p. 393 |
| The Orientation Averaged Sum Rules | p. 397 |
| The Orientation-Dependent Intensity: Charge and Magnetic Moment Anisotropies | p. 401 |
| Concepts of Linear Dichroism | p. 401 |
| X-ray Natural Linear Dichroism | p. 401 |
| Theory of X-ray Natural Linear Dichroism | p. 403 |
| XNLD and Quadrupole Moment of the Charge | p. 406 |
| X-ray Magnetic Linear Dichroism | p. 407 |
| Simple Theory of X-ray Magnetic Linear Dichroism | p. 408 |
| XMLD of the First and Second Kind | p. 411 |
| Enhanced XMLD through Multiplet Effects | p. 415 |
| The Orientation-Dependent Sum Rules | p. 421 |
| Magnetic Dichroism in X-ray Absorption and Scattering | p. 424 |
| The Resonant Magnetic Scattering Intensity | p. 425 |
| Link of Magnetic Resonant Scattering and Absorption | p. 427 |
| X-rays and Magnetism: Spectroscopy and Microscopy | p. 431 |
| Introduction | p. 431 |
| Overview of Different Types of X-ray Dichroism | p. 432 |
| Experimental Concepts of X-ray Absorption Spectroscopy | p. 437 |
| General Concepts | p. 437 |
| Experimental Arrangements | p. 441 |
| Quantitative Analysis of Experimental Absorption Spectra | p. 445 |
| Some Important Experimental Absorption Spectra | p. 449 |
| XMCD Spectra of Magnetic Atoms: From Thin Films to Isolated Atoms | p. 451 |
| Sum Rule Analysis of XMCD Spectra: Enhanced Orbital Moments in Small Clusters | p. 454 |
| Measurement of Small Spin and Orbital Moments: Pauli Paramagnetism | p. 457 |
| Magnetic Imaging with X-rays | p. 458 |
| X-ray Microscopy Methods | p. 459 |
| Lensless Imaging by Coherent Scattering | p. 463 |
| Overview of Magnetic Imaging Results | p. 468 |
| Properties of and Phenomena in the Ferromagnetic Metals | |
| The Spontaneous Magnetization, Anisotropy, Domains | p. 479 |
| The Spontaneous Magnetization | p. 480 |
| Temperature Dependence of the Magnetization in the Molecular Field Approximation | p. 481 |
| Curie Temperature in the Weiss-Heisenberg Model | p. 484 |
| Curie Temperature in the Stoner Model | p. 488 |
| The Meaning of "Exchange" in the Weiss-Heisenberg and Stoner Models | p. 491 |
| Thermal Excitations: Spin Waves | p. 494 |
| Critical Fluctuations | p. 499 |
| The Magnetic Anisotropy | p. 504 |
| The Shape Anisotropy | p. 507 |
| The Magneto-Crystalline Anisotropy | p. 508 |
| The Discovery of the Surface Induced Magnetic Anisotropy | p. 510 |
| The Magnetic Microstructure: Magnetic Domains and Domain Walls | p. 511 |
| Ferromagnetic Domains | p. 511 |
| Antiferromagnetic Domains | p. 515 |
| Magnetization Curves and Hysteresis Loops | p. 515 |
| Magnetism in Small Particles | p. 517 |
| Neel and Stoner-Wohlfarth Models | p. 517 |
| Thermal Stability | p. 520 |
| Magnetism of Metals | p. 521 |
| Overview | p. 521 |
| Band Theoretical Results for the Transition Metals | p. 523 |
| Basic Results for the Density of States | p. 523 |
| Prediction of Magnetic Properties | p. 525 |
| The Rare Earth Metals: Band Theory versus Atomic Behavior | p. 530 |
| Spectroscopic Tests of the Band Model of Ferromagnetism | p. 534 |
| Spin Resolved Inverse Photoemission | p. 535 |
| Spin Resolved Photoemission | p. 539 |
| Resistivity of Transition Metals | p. 548 |
| Conduction in Nonmagnetic Metals | p. 548 |
| The Two Current Model | p. 553 |
| Anisotropic Magnetoresistance of Metals | p. 556 |
| Spin Conserving Electron Transitions in Metals | p. 558 |
| Spin Conserving Transitions and the Photoemission Mean Free Path | p. 558 |
| Determination of the Spin-Dependent Mean Free Path using the Magnetic Tunnel Transistor | p. 562 |
| Probability of Spin-Conserving relative to Spin-Non-Conserving Transitions | p. 565 |
| The Complete Spin-Polarized Transmission Experiment | p. 569 |
| Transitions Between Opposite Spin States in Metals | p. 573 |
| Classification of Transitions Between Opposite Spin States | p. 573 |
| The Detection of Transitions between Opposite Spin States | p. 575 |
| Remaining Challenges | p. 582 |
| Topics in Contemporary Magnetism | |
| Surfaces and Interfaces of Ferromagnetic Metals | p. 587 |
| Overview | p. 587 |
| Spin-Polarized Electron Emission from Ferromagnetic Metals | p. 588 |
| Electron Emission into Vacuum | p. 588 |
| Spin-Polarized Electron Tunneling between Solids | p. 593 |
| Spin-Polarized Electron Tunneling Microscopy | p. 598 |
| Reflection of Electrons from a Ferromagnetic Surface | p. 601 |
| Simple Reflection Experiments | p. 603 |
| The Complete Reflection Experiment | p. 608 |
| Static Magnetic Coupling at Interfaces | p. 613 |
| Magnetostatic Coupling | p. 614 |
| Direct Coupling between Magnetic Layers | p. 615 |
| Exchange Bias | p. 617 |
| Induced Magnetism in Paramagnets and Diamagnets | p. 629 |
| Coupling of Two Ferromagnets across a Nonmagnetic Spacer Layer | p. 632 |
| Electron and Spin Transport | p. 637 |
| Currents Across Interfaces Between a Ferromagnet and a Nonmagnet | p. 637 |
| The Spin Accumulation Voltage in a Transparent Metallic Contact | p. 638 |
| The Diffusion Equation for the Spins | p. 642 |
| Spin Equilibration Processes, Distances and Times | p. 644 |
| Giant Magneto-Resistance (GMR) | p. 647 |
| Measurement of Spin Diffusion Lengths in Nonmagnets | p. 651 |
| Typical Values for the Spin Accumulation Voltage, Boundary Resistance and GMR Effect | p. 654 |
| The Important Role of Interfaces in GMR | p. 655 |
| Spin-Injection into a Ferromagnet | p. 656 |
| Origin and Properties of Spin Injection Torques | p. 657 |
| Switching of the Magnetization with Spin Currents: Concepts | p. 665 |
| Excitation and Switching of the Magnetization with Spin Currents: Experiments | p. 667 |
| Spin Currents in Metals and Semiconductors | p. 672 |
| Spin-Based Transistors and Amplifiers | p. 675 |
| Ultrafast Magnetization Dynamics | p. 679 |
| Introduction | p. 679 |
| Energy and Angular Momentum Exchange between Physical Reservoirs | p. 682 |
| Thermodynamic Considerations | p. 682 |
| Quantum Mechanical Considerations: The Importance of Orbital Angular Momentum | p. 684 |
| Spin Relaxation and the Pauli Susceptibility | p. 687 |
| Probing the Magnetization after Laser Excitation | p. 690 |
| Probing with Spin-Polarized Photoelectron Yield | p. 691 |
| Probing with Energy Resolved Photoelectrons With or Without Spin Analysis | p. 696 |
| Probing with the Magneto-Optic Kerr Effect | p. 702 |
| Dynamics Following Excitation with Magnetic Field Pulses | p. 705 |
| Excitation with Weak Magnetic Field Pulses | p. 712 |
| Excitation of a Magnetic Vortex | p. 715 |
| Switching of the Magnetization | p. 723 |
| Precessional Switching of the In-Plane Magnetization | p. 725 |
| Precessional Switching of the Magnetization for Perpendicular Recording Media | p. 733 |
| Switching by Spin Injection and its Dynamics | p. 744 |
| On the Possibility of All-Optical Switching | p. 751 |
| The Hubner Model of All-Optical Switching | p. 753 |
| All-Optical Manipulation of the Magnetization | p. 757 |
| Dynamics of Antiferromagnetic Spins | p. 759 |
| Appendices | |
| Appendices | p. 763 |
| The International System of Units (SI) | p. 763 |
| The Cross Product | p. 765 |
| s, p, and d Orbitals | p. 766 |
| Spherical Tensors | p. 767 |
| Sum Rules for Spherical Tensor Matrix Elements | p. 768 |
| Polarization Dependent Dipole Operators | p. 769 |
| Spin-Orbit Basis Functions for p and d Orbitals | p. 770 |
| Quadrupole Moment and the X-ray Absorption Intensity | p. 771 |
| Lorentzian Line Shape and Integral | p. 774 |
| Gaussian Line Shape and Its Fourier Transform | p. 774 |
| Gaussian Pulses, Half-Cycle Pulses and Transforms | p. 775 |
| References | p. 777 |
| Index | p. 805 |
| Table of Contents provided by Ingram. All Rights Reserved. |
ISBN: 9783540302827
ISBN-10: 3540302824
Series: Springer Series in Solid-State Sciences
Published: 15th September 2006
Format: Hardcover
Language: English
Number of Pages: 844
Audience: Professional and Scholarly
Publisher: Springer Nature B.V.
Country of Publication: GB
Dimensions (cm): 24.3 x 16.1 x 3.3
Weight (kg): 1.29
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