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368 Pages
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A new rapidly progressing field on the crossroads among chemistry, biochemistry, physics and technology - supramolecular chemistry - has just emerged. You have to be involved, to know what's going on in this
domain and to take part in the development. This book will show you in a condensed form exciting phenomena unthinkable within the realm of classical organic chemistry (for example, alkali metal anions or cyclobutadiene stable
for month at room temperature) that not only provide the basis for revolutionizing numerous branches of industry but also improve our understanding of the functioning of living organisms and of the origin of life. Designing
supramolecular systems with desired properties will among others make chemical industry cleaner and more safe, electronics smaller by developing devices composed of single molecule or molecular aggregate. It will also entirely
change the way we use energy resources. In addition, it will also transform the pharmaceutical industry and medicine by developing new ways of drugs administration and new composite biocompatible materials which will serve as
implants of new generation changing dentistry, surgery, and other branches of medicine. You cannot afford to stand apart.
With its brief but comprehensive and vivid presentation including the latest development,
Introduction to Supramolecular Chemistry is the best method to get into this domain. This book provides an excellent summary of information scattered across the literature. The brief but comprehensive coverage of the whole
field including practically all important group of compounds forming aggregates (in particular crown ethers, cavitands, fullerenes, cyclodextrins and their complexes) provisioning full references for the discussed subjects
make this book of value not only for Ph.D. students and non-specialists in this domain but also for those working in the field. The book has been found to be a particularly useful resource for students and more generally for
those wanting to get the up-to-date concise account of this exciting field.
Industry Reviews
H.T. McKone, Saint Joseph College in Choice, September 2002
| Preface | p. xi |
| Supramolecular Chemistry - What is This? | p. 1 |
| Molecular and Chiral Recognition. Self-Organization, Self-Assembly and Preorganization | p. 21 |
| Molecular and Chiral Recognition | p. 21 |
| Self-Assembly and Self-Organization | p. 25 |
| The Role of Preorganization in the Synthesis of Topological Molecules. Template Reactions | p. 27 |
| 'One-Pot' Reactions. Covalent Self-Assembly Based on Preorganization | p. 35 |
| Inclusion Complexes: Host-Guest Chemistry | p. 43 |
| Early Development of Host-Guest Chemistry. Pedersen's Works on Crown Ethers | p. 43 |
| Nomenclature | p. 50 |
| The Structure of Inclusion Complexes | p. 52 |
| Dynamic Character of Inclusion Complexes | p. 55 |
| The Complexes Involving Induced Fit and Without It: Endo-hedral Fullerene, Hemicarcerand and Soft Rebek's Tennis Ball-Like Hosts | p. 58 |
| Mesoscopic Structures as an Intermediate Stage Between Molecules(Micro Scale) on the One Hand and Biological Cells(Macro Scale) on the Other | p. 65 |
| Introduction | p. 65 |
| Medium Sized Molecular Aggregates | p. 66 |
| Langmuir and Langmuir-Blodgett Films and Other Self-assembling Layers | p. 69 |
| Mono- and Bilayer Lipid Membranes | p. 71 |
| Microemulsions, Micelles and Vesicles | p. 72 |
| Nanotubes | p. 79 |
| Fibers | p. 82 |
| Liquid crystals | p. 84 |
| Between Classical Organic Chemistry and Biology. Understanding and Mimicking Nature | p. 93 |
| Introduction | p. 93 |
| The Role of Self-Organization and Self-Association in the Living Nature | p. 94 |
| Tobacco Mosaic Virus | p. 94 |
| Helical Structure of DNA | p. 96 |
| Cell membranes | p. 97 |
| Modeling Processes in Living Organisms | p. 98 |
| Host-guest Complexes as Analogues of the Interacting Substrate-Receptor Unit in Biochemistry | p. 98 |
| Principles of Molecular Modeling of the Origin of Life | p. 99 |
| Modeling of Self-replication | p. 100 |
| Transport through Membranes. "Transport antibiotics": Valinomycin, Nonactin, Monensin and Their Mimics | p. 102 |
| Cyclodextrins as Enzyme Mimics | p. 104 |
| Porphyrins Involving Systems Modeling Photosynthesis | p. 105 |
| Light Driven Proton Pump | p. 107 |
| Iron Sequestering Agents Promoting Microbial Growth Siderophores | p. 109 |
| On the Border Between Chemistry and Technology - Nanotechnology and Other Industrial Applications of Supramolecular Systems | p. 115 |
| Introduction | p. 115 |
| Between Chemistry and Solid State Physics - Crystal Engineering. Obtaining Crystals With Desired Properties | p. 116 |
| Nanotechnology and Other Industrial Applications of Supramolecular Systems | p. 125 |
| Molecules in motion: towards machines and motors consisting of a single molecule or molecular aggregate | p. 127 |
| Electronics on the basis of organic molecules or their aggregates chemionics | p. 128 |
| The need for miniaturization of electronic devices | p. 128 |
| (Supra)molecular wires, conductors, semi- and super-conductors, and so forth | p. 129 |
| Sensors and switches | p. 133 |
| Photochemical devices | p. 136 |
| Pharmaceutical, cosmetic, and food industries | p. 141 |
| Environmental protection | p. 143 |
| Microemulsions in cleaning processes | p. 145 |
| Cation extracting systems ionophores | p. 148 |
| Other applications of supramolecular systems | p. 148 |
| Supramolecular Catalysis | p. 149 |
| Introduction | p. 149 |
| Enzyme mimics | p. 152 |
| Macrocyclic host molecules, medium-sized aggregates (microemulsions, micelles, vesicles, etc.) and mesoporous materials as catalysts | p. 155 |
| Concluding Remarks | p. 157 |
| The Most Interesting Macrocyclic Ligands Which are Hosts for Inclusion Complexes | p. 165 |
| Crown Ethers and Coronands, Cryptates and Cryptands | p. 165 |
| Introduction | p. 165 |
| Crown ethers and cryptands syntheses | p. 169 |
| Alkalides and Electrides | p. 173 |
| Miscellaneous molecules involving crown ethers, cryptands and related moieties | p. 177 |
| Calixarenes [1], Hemispherands, and Spherands | p. 183 |
| Calixarenes syntheses | p. 183 |
| Calixarene conformations | p. 187 |
| Calixarenes as complexing agents | p. 188 |
| Spherands, hemispherands, and other similar macrocycles capable of inclusion complex formation | p. 191 |
| Carcerands, Hemicarcerands and Novel 'Molecular Flasks' Enabling Preparation and Stabilization of Short-lived Species | p. 196 |
| Cyclodextrins, and Their Complexes | p. 207 |
| Introduction | p. 207 |
| CD complexes as one of the few supramolecular systems that have found numerous applications | p. 215 |
| Predicting molecular and chiral recognition of CDs on the basis of model calculations | p. 216 |
| Endohedral Fullerene Complexes, Nanotubes and Other Fullerene-based Supramolecular Systems | p. 220 |
| Dendrimers | p. 236 |
| Cyclophanes and Steroids That May Form Inclusion Complexes | p. 249 |
| Cyclophanes | p. 249 |
| Steroids | p. 251 |
| Anion Binding Receptors and Receptors with Multiple Binding Sites | p. 254 |
| Cationic receptors for anions | p. 254 |
| Neutral receptors for anions | p. 258 |
| Receptors with multiple binding sites | p. 262 |
| Porphyrin-based Hosts | p. 267 |
| Other Exciting Supramolecular Systems | p. 273 |
| Introduction | p. 273 |
| Making Use of the Preorganization Phenomenon: Topological Molecules | p. 275 |
| Multiple Hydrogen-bonded Systems | p. 287 |
| Rosettes, tapes (ribbons), fibers and two-dimensional networks | p. 287 |
| Hydrogen-bonded capsules and other higher architectures | p. 293 |
| Clathrate hydrates of gases | p. 294 |
| Organic Zeolite | p. 300 |
| Metal-directed Self-assembly of Complex Supramolecular Architecture: Chains, Racks, Ladders, Grids, Macrocycles, Cages, Nanotubes and Self-intertwining Strands (Helicates) | p. 307 |
| Chains, racks, ladders, grids, macrocycles and cages | p. 307 |
| Helicates | p. 313 |
| The Prospects of Future Development of Supramolecular Chemistry | p. 321 |
| Index | p. 325 |
| Table of Contents provided by Syndetics. All Rights Reserved. |
ISBN: 9781402002144
ISBN-10: 1402002149
Published: 31st December 2001
Format: Hardcover
Language: English
Number of Pages: 368
Audience: General Adult
Publisher: Springer Nature B.V.
Country of Publication: NL
Dimensions (cm): 23.5 x 16.51 x 1.91
Weight (kg): 0.69
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