General Analytical Chemistry

Preface. Acknowledgment. GENERALITIES. Thermodynamics and Equilibrium. Recallings and Definitions Concerning the Electrochemical Cells. Present Views on the Interface Metal/Solution. More on the Potential of an Electrode. Kinetics of the Electrode Reaction. A Qualitative Study of the Current-Potential Curves. Nernstâs Equationâ"Electrode Potentialsâ"Electrochemical Potentials. Equation of Butlerâ"Volmer. Transport Phenomena in Solution: Diffusion. Limiting-Intensity-Real Current-Potential Curves-Consequences of the Stationary State of Activation-Diffusion. Reversible and Irreversible Systems. Electrochemical Indicators. Forecasting Electrochemical Reactions at the Electrodes. Forecasting Electrochemical Reactions in an Electrochemical Cell: Conditions of Electrolysis. Transports by Migration. Current-Potential Curves During a Chemical Reaction. Techniques Based on Concept of Impedance: Impedance Spectroscopy. ELECTROCHEMICAL METHODS OF ANALYSIS. Conventional Polarography. Pulse Voltammetry. Chronoamperometry. Cyclic Voltammetry. Voltammetric Methods by Redissolution: Stripping Analysis. Voltammetry at Ultramicroelectrodes. Amperometry. Conductometry. Generalities on Potentiometry. Definitions and PH Determination. Potentiometry with Chemical Sensors: Ion Selective Electrodes (I.S.E). Potentiometric Titrations. Chronopotentiometry. Electrogravimetryâ"Separation by Electrolysis. Coulometry. Chemical Sensors (Following). Electrochemical Biosensors. Electrochemical Detectors in Liquid Chromatography. APPENDICES. Voltage Measurements. Obtention of the Butlerâ"Volmerâ S Equation. Laplace Transforms. Fickâs Laws of Diffusion. Fresnelâs Rule. Cottrellâs Equation and Extensions. Polarography: Ilkowicâs Equation. Quantitative Relationships in Pulse Differential Polarography. Electrochemical Methods of Analysis Grounded on the Linear Sweeping of Potential Equation of Randlesâ"Sevcik. Elimination of the Migration Current. Potential of Liquid Junction: Eisenmannâ"Nikolskii's Relation. Hendersonâs Equation. Equation of Michaelisâ"Menten. Quantitative Aspects Applying to the Amperometric and Potentiometric Enzymatic Biosensors. General Bibliography. Glossary Electrochemical. Index.