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Fluoropolymers 1 : Synthesis - Gareth G. Hougham

Fluoropolymers 1

Synthesis

By: Gareth G. Hougham (Editor), Patrick E. Cassidy (Editor), Ken Johns (Editor), Theodore Davidson (Editor)

Hardcover Published: 31st October 1999
ISBN: 9780306460609
Number Of Pages: 330

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The fluorine atom, by virtue of its electronegativity, size, and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals, and surface modifiers are only a few examples. Fluoropolymers, too, while traditionally associated with extreme hi- performance applications have found their way into our homes, our clothing, and even our language. A recent American president was often likened to the tribology of PTFE. Since the serendipitous discovery of Teflon at the Dupont Jackson Laboratory in 1938, fluoropolymers have grown steadily in technological and marketplace importance. New synthetic fluorine chemistry, new processes, and new apprec- tion of the mechanisms by which fluorine imparts exceptional properties all contribute to accelerating growth in fluoropolymers. There are many stories of harrowing close calls in the fluorine chemistry lab, especially from the early years, and synthetic challenges at times remain daunting. But, fortunately, modern techniques and facilities have enabled significant strides toward taming both the hazards and synthetic uncertainties. In contrast to past environmental problems associated with fluorocarbon refrigerants, the exceptional properties of fluorine in polymers have great environmental value. Some fluoropolymers are enabling green technologies such as hydrogen fuel cells for automobiles and oxygen-selective membranes for cleaner diesel combustion.

Synthesis
Polyacrylates Containing the Hexafluoroisopropylidene Function in the Pendant Groups
Fluorinated Cyanate Ester Resins
Polymers from the Thermal (2[pi] + 2[pi]) Cyclodimerization of Fluorinated Olefins
Functional Fluoromonomers and Fluoropolymers
Use of Original Fluorinated Telomers in the Synthesis of Hybrid Silicones
Chlorotrifluoroethylene Suspension Polymerization
Fluorinated Polymers with Functional Groups: Synthesis and Applications. Langmuir-Blodgett Films from Functional Fluoropolymers
Synthesis of Fluorinated Poly(Aryl Ether)s Containing 1,4-Naphthalene Moieties
Synthesis and Properties of Fluorine-Containing Aromatic Condensation Polymers Obtained from Bisphenol AF and Its Derivatives
Novel Fluorinated Block Copolymers: Synthesis and Application
Synthesis and Structure - Property Relationships of Low-Dielectric-Constant Fluorinated Polyacrylates
Epoxy Networks from a Fluorodiimidediol
Synthesis of Fluoropolymers in Liquid and Supercritical Carbon Dioxide Solvent Systems
Direct Fluorination
Direct Fluorination of Polymers
Surface Fluorination of Polymers Using Xenon Difluoride
New Surface-Fluorinated Products
Modified Surface Properties of Technical Yarns
Vapor Deposition
Vapor Deposition Polymerization as a Route to Fluorinated Polymers
Ultrathin PTEE, PVDF, and FEP Coatings Deposited Using Plasma-Assisted Physical Vapor Deposition
Index
Table of Contents provided by Blackwell. All Rights Reserved.

ISBN: 9780306460609
ISBN-10: 0306460602
Series: Topics in Applied Chemistry
Audience: General
Format: Hardcover
Language: English
Number Of Pages: 330
Published: 31st October 1999
Publisher: SPRINGER VERLAG GMBH
Country of Publication: US
Dimensions (cm): 22.86 x 15.24  x 2.39
Weight (kg): 0.69
Edition Number: 22

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