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Cyclization Reactions : New Directions in Organic and Biological Chemistry - C. Thebtaranonth

Cyclization Reactions

New Directions in Organic and Biological Chemistry

Hardcover Published: 1st May 1993
ISBN: 9780849378614
Number Of Pages: 384

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Cyclization Reactions provides a quick update of the latest advances in cyclization reactions. It covers the basic principles of cyclization chemistry, emphasizing practical applications. Chapters are organized according to the different cyclization intermediates-cationic, radical, anionic, and metal complex intermediates. The last chapter covers macrolactonization, vicinal tricarbonal, and Bergman (enediyne) reactions, which are of particular interest today.
More than 2,600 structures illustrate key concepts throughout the book. Various cyclizations are organized into mechanistic groups to help researchers choose and change between methods when searching for maximum efficiency in synthesis. Critical coverage of the literature up to 1992 is provided.
Cyclization Reactions is essential reading for anyone involved in the synthesis of ring compounds or who is seeking a rapid overview of the field. Newcomers as well as experienced researchers will benefit from this book. It also is excellent reference material for students at the advanced undergraduate and graduate levels.

Cyclization Reactionsp. 1
Cationic Cyclization
Cyclization of Carbocationsp. 6
Cyclization of Iminium Ionsp. 17
Cyclization of Oxonium and Thionium Ionsp. 38
Cyclization of Vinyl-, Allyl-, Propargyl- and Allenylsilanesp. 50
Radical Cyclization
Cyclization to Unactivated Alkenes and Alkynesp. 77
Cyclization to Activated Olefins and Carbonyl Functionsp. 103
Tandem Cyclizationp. 120
Cyclization Involving Atom or Group Transfer, Radical Translocation, Rearrangement, or Fragmentation Processesp. 134
Anionic Cyclization
Cyclization via S[subscript N] 2 and S[subscript N] 2' Displacementsp. 169
Cyclization via Addition to Carbonyl, Imine, Iminium, Oxonium and Thionum Functionsp. 182
Cyclization via Conjugate Additionp. 199
Cyclization of Allylsilanes and Allylstannanesp. 225
Cyclization Involving Addition to Unactivated Olefinic Bondsp. 232
Metal-Catalyzed Cyclization
Palladium-catalyzed cyclizationp. 255
Metal-Catalyzed Carbonylative Cyclizationp. 282
Metal-Catalyzed Carbon-Heteroatom Bond Formationp. 298
Samarium(II) Iodide-Catalyzed Cyclizationp. 312
Miscellaneous Cyclizations
Macrolactonizationp. 331
Vicinal Tricarbonyl Cyclizationp. 337
Indexp. 365
Table of Contents provided by Blackwell. All Rights Reserved.

ISBN: 9780849378614
ISBN-10: 0849378613
Series: New Directions in Organic and Biological Chemistry
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 384
Published: 1st May 1993
Publisher: CRC PR INC
Country of Publication: US
Dimensions (cm): 24.77 x 16.51  x 2.54
Weight (kg): 0.75
Edition Number: 1

Earn 1198 Qantas Points
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