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CRC Handbook of Thermodynamic Data of Copolymer Solutions - Christian Wohlfarth

CRC Handbook of Thermodynamic Data of Copolymer Solutions

Hardcover Published: 26th April 2001
ISBN: 9780849310744
Number Of Pages: 520

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Thermodynamic data are essential to understanding the physical behavior of copolymer solutions, intermolecular interactions, and the molecular nature of mixtures. As such, they form the basis for developing theoretical thermodynamic models, and knowledge of this data is necessary for countless industrial and laboratory processes. Until now, however, accessing this information meant long and tedious searches through the original literature.

The Handbook of Thermodynamic Data of Copolymer Solutions is the world's first comprehensive source of this vital data. Author Christian Wohlfarth, a chemical thermodynamicist specializing in phase equilibria of polymer and copolymer solutions and a respected contributor to the "CRC Handbook of Chemistry and Physics," has gathered up-to-the-minute data from more than 300 literature sources. Fully committed to ensuring the reliability of the data, the author included results in the handbook only if numerical values were published or if authors provided their numerical results by personal communication.

With volumetric, calormetric, and various phase equilibrium data on more than 165 copolymers and 165 solvents, this handbook furnishes

- 250 vapor-pressure isotherms

- 75 tables of Henry's constants

- 50 LLE data sets

- 175 HPPE data sets

- 70 PVT data tables

Carefully organized, clearly presented, and fully referenced, The Handbook of Thermodynamic Data of Copolymer Solutions will prove a cardinal contribution to the open literature and invaluable to anyone working with copolymers.

Industry Reviews

"The authoris known for his experience and his own experimental investigations on polymer and copolymer solutions for more than 20 yearsI am sure that readers interested in the field of thermodynamic properties of polymer solutions will benefit from this handbook and will identify the work that has to be done in the future." - From the Preface by Henry V. Kehiaian, Chariman, IUPAC-CODATA Task Group on Standard Physico-Chemical Data Formats

Introduction
Objectives of the handbookp. 1
Experimental methods involvedp. 2
Guide to the data tablesp. 21
List of symbolsp. 25
Referencesp. 27
Vapor-Liquid Equilibrium (VLE) Data of Binary Copolymer Solutions
Partial solvent vapor pressures or solvent activities for copolymer solutionsp. 29
Classical mass-fraction Henry's constants of solvent vapors in molten copolymersp. 88
Referencesp. 142
Liquid-Liquid Equilibrium (LLE) Data of Quasibinary or Quasiternary Copolymer Solutions
Cloud-point and/or coexistence curves of quasibinary solutionsp. 145
Table of systems where binary LLE data were published only in graphical form as phase diagrams or related figuresp. 160
Cloud-point and/or coexistence curves of quasiternary solutions containing at least one copolymerp. 163
Table of systems where ternary LLE data were published only in graphical form as phase diagrams or related figuresp. 172
Lower critical (LCST) and/or upper (UCST) critical solution temperatures of copolymer solutionsp. 175
Referencesp. 183
High-Pressure Phase Equilibrium (HPPE) Data of Copolymer Solutions in Supercritical Fluids
Experimental data of quasibinary copolymer solutionsp. 187
Table of systems where binary HPPE data were published only in graphical form as phase diagrams or related figuresp. 225
Experimental data of quasiternary solutions containing at least one copolymerp. 229
Table of systems where ternary HPPE data were published only in graphical form as phase diagrams or related figuresp. 264
Referencesp. 266
Enthalpy Changes for Binary Copolymer Solutions
Enthalpies of mixing or intermediary enthalpies of dilution, and copolymer partial enthalpies of mixing (at infinite dilution), or copolymer (first) integral enthalpies of solutionp. 269
Partial molar enthalpies of mixing at infinite dilution of solvents and enthalpies of solution of gases/vapors of solvents in molten copolymers from inverse gas-liquid chromatography (IGC)p. 307
Table of systems where additional information on enthalpy effects in copolymer solutions can be foundp. 333
Referencesp. 337
PVT Data of Molten Copolymers
Experimental data and/or Tait equation parametersp. 341
Referencesp. 430
Second Virial Coefficients (A[subscript 2]) of Copolymer Solutions
Experimental A[subscript 2] datap. 431
Referencesp. 445
Appendices
List of copolymer acronymsp. 447
List of systems and properties in order of the copolymersp. 451
List of solvents in alphabetical orderp. 494
List of solvents in order of their molecular formulasp. 499
Table of Contents provided by Syndetics. All Rights Reserved.

ISBN: 9780849310744
ISBN-10: 0849310741
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 520
Published: 26th April 2001
Publisher: Taylor & Francis Inc
Country of Publication: US
Dimensions (cm): 25.4 x 17.78  x 3.18
Weight (kg): 1.11
Edition Number: 1

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