Corrosion of Advanced Ceramics Measurement and Modelling

Proceedings of the NATO Advanced Research Workshop, Tubingen, Germany, August 30-September 3, 1993

By: K.G. Nickel (Editor)

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Corrosion behaviour is one of the most poorly understood characteristics of ceramics. A balanced mixture of scientists from material science, metallurgy, physics, chemistry and mineralogy sum up the state of the art of measurement and modelling and reveal future research directions. The book reviews the theory of corrosion of ceramics, including the diffusion of gases and the predictions of thermodynamics; it discusses critically the kinetic models and representation tools for layer growths and material destruction. Corrosion of nitrides, carbides and oxides by simple and complex gases (O₂, H₂O, SO₂, halides) and melts (ionic and metallic) reveal current measurement and modelling methods, advanced experimental techniques, such as laser diagnostics, TV holography, Raman spectroscopy and NDE surface methods. Frontier areas (e.g. the modelling of porous materials corrosion and protection) are revealed.
For scientists and engineers in materials science, dealing with ceramics and their application. A valuable source for research students, solid state physicists and physical chemists.

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Preface
List of Participants
Theory and Experiment in Corrosion of Advanced Ceramics	p. 3
Theoretical Aspects of the Oxidation of Silica-forming Ceramics	p. 23
Oxygen Diffusion in Silica and Corrosion of Ceramics	p. 35
Applicability of Quasi-Steady-State Solutions for the Kinetics of Diffusion Controlled Solid State Reactions	p. 47
Multiple Law Modelling for the Oxidation of Advanced Ceramics and a Model-Independent Figure-of-Merit	p. 59
Non-Parabolic Oxidation Kinetics of Advanced Ceramics	p. 73
Phase Equilibrium Relationships and the Liquid Phase Assisted Oxidative Corrosion of Silicon Nitride	p. 85
Hot Gas Corrosion of Structural Ceramics	p. 99
The Oxidation Process in Silicon Nitride	p. 117
Oxidation Behaviour of Nitrides and Borides as Monolithic and Composite Ceramics	p. 131
Corrosion and Fretting Damage of Non-Oxide Ceramics in Presence of Water Vapour	p. 143
Discontinuous Phase Formation and Selective Attack of SiC Materials Exposed to Low Oxygen Partial Pressure Environments	p. 153
Active to Passive Transition in the High-Temperature Oxidation of CVD SiC and Si[subscript 3]N[subscript 4]	p. 165
Factors Limiting the Application of Silicon Nitride Ceramics in Sulphur-Containing Environments of Low Oxygen Potential at High Temperatures	p. 177
Oxidation of Silicon Based Ceramics in the Presence of Alkali Halides	p. 189
Molten Salt Corrosion of Ceramics	p. 205
Hot Corrosion - the Experience From Metals and Intermetallics	p. 223
Hot Corrosion of Oxide Ceramics	p. 235
Burner-Rig Hot-Salt Corrosion of Si[subscript 3]N[subscript 4] in the Temperature Range [actual symbol not reproducible]	p. 249
Corrosion of Ceramics by Liquid Metals	p. 261
Attempting to Predict the High Temperature Corrosion of Oxide Ceramics by Molten Silicates	p. 285
Corrosion of Ceramics in Special Gas Atmospheres	p. 297
High Temperature Oxidation of Porous Non-Oxide Ceramics: Recent Advances in Modelling and Protection by Coatings	p. 309
Porous Media and the Use of Thermobalances: The Kinetics of Combustion Processes	p. 329
Evaluation of Oxygen Tracer Diffusion Profiles in Two-Stage Oxidation Experiments	p. 341
TV-Holography at High Temperatures: In-situ Observations of the Oxidation of Advanced Materials	p. 351
Vaporization Behavior of Non-Stoichiometric Refractory Carbide Materials and Direct Observations of the Vapor Phase Using Laser Diagnostics	p. 363
Thermal Loading and Corrosion of Ceramics by Light Irradiation	p. 375
Micro-Raman Spectroscopy for Phase Identification and Stress Measurement in Advanced Ceramics	p. 385
Non-destructive Evaluation of Ceramics	p. 399
Advanced Surface Techniques for the Investigation of Corrosion Problems	p. 413
Microstructural Design of Si[subscript 3]N[subscript 4] and SiAlON Ceramics in Relation To Combined Mechanical and Environmental Behaviour	p. 425
Effect of Oxidation on Creep of Silicon-Nitride Based Ceramics	p. 441
Influence of Oxidation on Long Term Reliability of Silicon Nitride	p. 453
Subject Index	p. 465
Table of Contents provided by Blackwell. All Rights Reserved.

Corrosion of Advanced Ceramics Measurement and Modelling

Proceedings of the NATO Advanced Research Workshop, Tubingen, Germany, August 30-September 3, 1993

At a Glance

Hardcover

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