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Controlled/Living Radical Polymerization : Progress in Atrp, Nmp and Raft - Krzysztof Matyjaszewski

Controlled/Living Radical Polymerization

Progress in Atrp, Nmp and Raft

Hardcover Published: 20th July 2000
ISBN: 9780841237070
Number Of Pages: 496

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This book examines recent progress in controlled/living radical polymerization. The volume focuses on three synthetic methods: atom transfer radical polymerization, nitroxide mediated polymerization and degenerative transfer via addition fragmentation. In addition, the volume covers the preparation and characterization of many never before seen materials using ATRP, NMP and RAFT.

Prefacep. xi
Advances in Conventional and Controlled Radical Polymerization
Comparison and Classification of Controlled/Living Radical Polymerizationsp. 2
Kinetics of Living Radical Polymerizationp. 27
Initiation and Termination Rates Associated with Free-Radical Polymerization in Extended Ranges of Temperature and Pressurep. 39
Stereochemistry in Radical Polymerization of Vinyl Estersp. 57
Electron Paramagnetic Resonance Study of Conventional and Controlled Radical Polymerizationsp. 68
Models for Free-Radical Copolymerization Propagation Kineticsp. 82
Topochemical Polymerization of Diene Monomers in the Crystalline State to Control the Stereochemistry of the Polymersp. 93
Nitroxide-Mediated Polymerization
Use of Phosphonylated Nitroxides and Alkoxyamines in Controlled/"Living" Radical Polymerizationp. 108
Progress Toward a Universal Initiator for Nitroxide Mediated 'Living' Free Radical Proceduresp. 123
Nitroxide-Mediated Controlled Free-Radical Emulsion and Miniemulsion Polymerizations of Styrenep. 138
Triazolinyl Radicals: Toward a New Mechanism in Controlled Radical Polymerizationp. 152
Atom Transfer Radical Polymerization
Living Radical Polymerization of Styrene: RuCl[subscript 2](PPh[subscript 3])[subscript 3] and Alkyl Iodide-Based Initiating Systemsp. 168
Copper-Mediated Living Radical Polymerization Utilizing Biological and End Group Modified Poly(ethylene-co-butylene) Macroinitiatorsp. 182
Atom Transfer Radical Copolymerization of Styrene and Butyl Acrylatep. 197
The Copper Catalyst in Atom Transfer Radical Polymerizations: Structural Observationsp. 211
Atom Transfer Radical Polymerization Mediated by Ruthenium(II)-Arene Complexesp. 223
Polychloroalkanes as ATRP Initiators: Fundamentals and Application to the Synthesis of Block Copolymers from the Combination of Conventional Radical Polymerization and ATRPp. 234
Controlled Radical Polymerization Utilizing Preformed Metal Complexes Based on Substituted Bipyridines and Terpyridinesp. 248
Reverse Atom Transfer Radical Polymerization Using AIBN or BPO as Initiatorp. 263
Synthesis of Defined Polymers by Reversible Addition-Fragmentation Chain Transfer: The RAFT Processp. 278
Preparation of Macromonomers via Chain Transfer with and without Added Chain Transfer Agentp. 297
End-Group Control in Catalytic Chain Transfer Polymerizationp. 313
New Materials by Controlled Radical Polymerization
Synthesis of Polystyrene-Polyacrylate Block Copolymers by Nitroxide-Mediated Radical Polymerizationp. 334
Functionalized Polymers by Atom Transfer Radical Polymerizationp. 347
Copolymerization of n-Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers by Conventional and Atom Transfer Radical Copolymerizationp. 361
Quantitative Derivatizations of 1-Chloro-1-phenylethyl Chain End of Polystyrene Obtained by Quasiliving Atom Transfer Radical Polymerizationp. 372
Synthesis of Alternating Copolymers of N-Substituted Maleimides with Styrene via Atom Transfer Radical Polymerizationp. 384
Controlled Radical Copolymerization of Styrene and Acrylonitrilep. 394
Synthesis of Oligomers by Stable Free Radical Polymerization of Acrylates, Methacrylates, and Styrene with Alkoxyamine Initiatorsp. 408
Potential Impact of Controlled Radical Polymerization on Markets for Polymeric Materialsp. 427
Indexes
Author Indexp. 443
Subject Indexp. 445
Table of Contents provided by Syndetics. All Rights Reserved.

ISBN: 9780841237070
ISBN-10: 0841237077
Series: ACS Symposium Series
Audience: General
Format: Hardcover
Language: English
Number Of Pages: 496
Published: 20th July 2000
Publisher: AMER CHEMICAL SOC
Country of Publication: US
Dimensions (cm): 23.47 x 16.31  x 3.96
Weight (kg): 0.92

Earn 457 Qantas Points
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