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Catalytic Selective Oxidation : ACS Symposium Series - S. Ted Oyama

Catalytic Selective Oxidation

ACS Symposium Series

By: S. Ted Oyama (Editor), Joe W. Hightower (Editor)

Hardcover

Published: 5th May 1993
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Discusses the most recent advances in the theories and concepts of selective oxidation technology. Examines the synthesis, characterization, and performance of new catalytic materials used in the oxidation of hydrocarbons in the range of C[1 to C[4. Highlights the use of transition metal oxides in one of several redox states in industrial oxidation processes. Also presents state-of-the-art developments in engineering and applications to new processes.

Preface
Research Challenges in Selective Oxidationp. 1
Adsorbate Bonding and Selectivity in Partial Oxidationp. 16
Surface Oxide-Support Interactions in the Molecular Design of Supported Metal Oxide Selective Oxidation Catalystsp. 31
Silica-Supported MoO[subscript 3] and V[subscript 2]O[subscript 5] Catalysts in Partial Oxidation of Methane to Formaldehyde: Factors Controlling Reactivityp. 43
Oxygenation Reactions Catalyzed by Supported Sulfonated Metalloporphyrinsp. 58
Principles and New Approaches in Selective Catalytic Homogeneous Oxidationp. 67
Nature of the Co-Mn-Br Catalyst in the Methylaromatic Compounds Process: Kinetic and Thermodynamic Studiesp. 81
Reactivity of Oxygen Adatoms on the Au(111) Surfacep. 90
Control of the Methanol Reaction Pathway by Oxygen Adsorbed on Mo(112)p. 110
Structure Sensitivity in Selective Oxidation of Propene over Cu[subscript 2]O Surfacesp. 122
Structure and Reactivity of Alkali-Promoted NiO Model Catalysts: Surface Vibrational Spectroscopic Characterizationp. 133
Active Crystal Face of Vanadyl Pyrophosphate for Selective Oxidation of n-Butanep. 156
Selective and Nonselective Pathways in Oxidation and Ammoxidation of Methyl-Aromatic Compounds over Vanadia-Titania Catalysts: Fourier Transform Infrared Spectroscopic Studiesp. 168
Activation of Silver Powder for Ethylene Epoxidation at Vacuum and Atmospheric Pressuresp. 183
Structure and Reactivity of Tin Oxide-Supported Vanadium Oxide Catalystsp. 204
V-P-O Catalysts in n-Butane Oxidation to Maleic Anhydride: Study Using an In Situ Raman Cellp. 217
Vanadium Catalysts Supported on Titanium (Anatase) Characterized by Ammonia and Low-Temperature Oxygen Chemisorptionp. 231
Hydrocarbon Partial Oxidation Catalysts Prepared by the High-Temperature Aerosol Decomposition Process: Crystal and Catalytic Chemistryp. 244
Synergy Effect of Multicomponent Co, Fe, and Bi Molybdates in Propene Partial Oxidationp. 262
Selective Oxidation of Alkanes, Alkenes, and Phenol with Aqueous H[subscript 2]O[subscript 2] on Titanium Silicate Molecular Sievesp. 273
Nature of Vanadium Species in Vanadium-Containing Silicalite and Their Behavior in Oxidative Dehydrogenation of Propanep. 281
Oxidation of Highly Dispersed Platinum on Graphite Catalysts in Gaseous and Aqueous Mediap. 298
Promotion and Deactivation of Platinum Catalysts in Liquid-Phase Oxidation of Secondary Alcoholsp. 308
Toward Catalysis of Selective Epoxidation and Its Applicability to Multistage Organic Synthesisp. 318
Oxidative Coupling of Methane over Praseodymium Oxide in the Presence and Absence of Tetrachloromethanep. 326
Oxidative Coupling of Methane over Alkali-Promoted Simple Molybdate Catalystsp. 340
Methane-Selective Oxidation of Silica-Supported Molybdenum(VI) Catalysts: Structure and Catalytic Performancep. 354
Partial Oxidation of Ethane over Silica-Supported Molybdate Catalystsp. 368
Selective Oxidative Dehydrogenation of Propane on Promoted Niobium Pentoxidep. 380
Factors That Determine Selectivity for Dehydrogenation in Oxidation of Light Alkanesp. 389
Optimal Distribution of Silver Catalyst for Epoxidation of Ethylenep. 410
Synthesis Gas Formation by Direct Oxidation of Methane over Monolithsp. 416
Partial Oxidation Using Membrane Reactorsp. 427
Selective Oxidation of Hydrocarbons by Supercritical Wet Oxidationp. 438
Author Indexp. 449
Affiliation Indexp. 450
Subject Indexp. 450
Table of Contents provided by Blackwell. All Rights Reserved.

ISBN: 9780841226371
ISBN-10: 0841226377
Series: ACS Symposium Series
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 460
Published: 5th May 1993
Publisher: American Chemical Society
Country of Publication: US
Dimensions (cm): 23.4 x 15.7  x 2.7
Weight (kg): 0.76