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Catalytic Activation of Dioxygen by Metal Complexes : CATALYSIS BY METAL COMPLEXES - Laszlo I. Simandi

Catalytic Activation of Dioxygen by Metal Complexes

CATALYSIS BY METAL COMPLEXES

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Published: 31st July 1992
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The activation of dioxygen by metal ions has both synthetic potential and biological relevance. Dioxygen is the cleanest oxidant for use in emission-free technologies to minimize pollution of the environment. The book gives a survey of those catalyst systems based on metal complexes which have been discovered and studied in the last decade. They activate molecular oxygen and effect the oxidation of various organic compounds under mild conditions. Much of the recent progress is due to a search for biomimetic catalysts that would duplicate the action of metalloenzymes. Mechanistic aspects are emphasized throughout the book. An introductonary chapter reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed. Separate chapters are devoted to oxidation of saturated, unsaturated and aromatic hydrocarbons, phenols, catechols, oxo-compounds, phosphorus, sulfur and nitrogen compounds.

`The book is logically organized and contains a wealth of useful information together with an extensive bibliography (more than 1500 literature references). ... I heartily recommend this book to both academic and industrial researchers involved in the area of catalytic oxidation in particular and transition metal catalysis in general. ' applied catalysis A: General, 97:1 `Overall, this book is a useful source of information in the topic of catalytic activation of dioxygen by metal complexes and related organic oxidation reactions, and in this context gives ...where platinum metals can de used for selective oxidation/dehydrogenation reactions.' Platinum Metals Rev., 37:1 (1993)

Preface
Dioxygen complexesp. 1
Introductionp. 1
The O[subscript 2] moleculep. 4
Structure and bonding in dioxygen complexesp. 10
Spectroscopy of dioxygen complexesp. 24
Equilibria of dioxygen complexesp. 37
Kinetics and mechanisms of dioxygen complex formation and decompositionp. 48
Referencesp. 61
Catalytic oxidation of saturated hydrocarbons with O[subscript 2]p. 74
Introductionp. 74
Metal-free systemsp. 74
Metal complexes as catalystsp. 80
Summaryp. 102
Referencesp. 103
Catalytic oxidation of alkenes with O[subscript 2]p. 109
Introductionp. 109
Epoxidationsp. 110
Catalytic oxidation of olefins to ketones and aldehydesp. 134
Allylic oxidationp. 160
Formation of glycols and carbonatesp. 161
Redox hydration or oxygenation under reductive conditionsp. 162
Effect of O[subscript 2] on olefin metathesisp. 165
Catalytic oxidation of alkynesp. 166
Summaryp. 169
Referencesp. 171
Catalytic hydroxylation of aromatic hydrocarbons with O[subscript 2]p. 181
Introductionp. 181
Benzene hydroxylationp. 181
Mechanism of benzene hydroxylationp. 185
Hydroxylation of m-xylene derivativesp. 188
Summaryp. 192
Referencesp. 193
Catalytic oxidation of phenolsp. 196
Base-catalyzed oxidation of substituted phenolsp. 196
Metal complexes as catalysts for oxidation of alkyl-substituted phenolsp. 200
Catalytic oxidative coupling of phenolsp. 229
Catalytic hydroxylation of phenols (tyrosinase models)p. 233
Summaryp. 241
Referencesp. 243
Catalytic oxidation of catecholsp. 249
Discovery and types of oxygenasesp. 249
Catalytic oxidative dehydrogenation of catechols to o-quinonesp. 252
Catalytic oxidative cleavage of catecholsp. 257
Summaryp. 291
Referencesp. 292
Catalytic oxidation of alcohols with O[subscript 2]p. 297
Dehydrogenation of alcohols without O[subscript 2]p. 297
Oxidative dehydrogenations with O[subscript 2]p. 298
Summaryp. 305
Referencesp. 306
Catalytic oxidation of diols and polyols with O[subscript 2]p. 308
Ascorbic acidp. 308
Diolsp. 312
Polyols and sugarsp. 315
Summaryp. 316
Referencesp. 317
Catalytic oxidation of aldehydes and ketones with O[subscript 2]p. 318
Aldehydesp. 318
Acetalsp. 321
Ketonesp. 321
Acyloinsp. 324
Summaryp. 329
Referencesp. 329
Catalytic oxidation of nitrogen compounds with O[subscript 2]p. 332
Dehydrogenation of nitrogen-containing compoundsp. 332
Oxygen insertions into nitrogen-containing compoundsp. 346
Summaryp. 359
Referencesp. 360
Oxidation and co-oxidation of tertiary phosphinesp. 363
Summaryp. 368
Referencesp. 369
Oxidation of sulfur compoundsp. 371
Catalytic oxidation of thioethersp. 371
Catalytic oxidation of thiolsp. 374
Summaryp. 383
Referencesp. 384
Abbreviationsp. 387
Subject indexp. 393
Table of Contents provided by Blackwell. All Rights Reserved.

ISBN: 9780792318965
ISBN-10: 079231896X
Series: CATALYSIS BY METAL COMPLEXES
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 397
Published: 31st July 1992
Publisher: Springer
Country of Publication: NL
Dimensions (cm): 23.5 x 15.88  x 3.18
Weight (kg): 0.77