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Calixarenes for Separations : ACS Symposium Series - Gregg J. Lumetta

Calixarenes for Separations

ACS Symposium Series

By: Gregg J. Lumetta (Editor), Robin D. Rogers (Editor), Aravamudan S. Gopalan (Editor)

Hardcover Published: 10th August 2000
ISBN: 9780841236608
Number Of Pages: 378

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This book is a complete examination of the benefits and uses of calixarenes to provide frameworks for arranging binding functionalities in spatial arrangements that are ideal for binding specific substrates. These selective bindings are used as the basis for chemical separations, and calixarenes can be used for binding both cationic and anionic substrates, making this book a useful addition to any chemist's library.

Prefacep. xi
Calixarenes for Separationsp. 2
Calixarene-Cation Complexation
Extraction of Cesium by Calix[4]arene-crown-6: From Synthesis to Processp. 12
Development of Process Chemistry for the Removal of Cesium from Acidic Nuclear Waste by Calix[4]arene-crown-6 Ethersp. 26
Radiation Stability of Calixarene-Based Solvent Systemp. 45
Behavior of Calix[4]arene-bis-crown-6 under Irradiation: Electrospray-Mass Spectrometry Investigation and Molecular Dynamics Simulations on Cs[superscript +] and Na[superscript +] Complexes of a Degradation Compoundp. 56
Interfacial Features of Assisted Liquid-Liquid Extraction of Uranyl and Cesium Salts: A Molecular Dynamics Investigationp. 71
Benzyl Phenol Derivatives: Extraction Properties of Calixarene Fragmentsp. 86
Calixarene-Containing Extraction Mixture for the Combined Extraction of Cs, Sr, Pu, and Am from Alkaline Radioactive Wastesp. 107
Calix[4]arenes with a Novel Proton-Ionizable Group: Synthesis and Metal Ion Separationsp. 112
Separations of Soft Heavy-Metal Cations by Lower Rim-Functionalized Calix[4]arenesp. 125
CMPO-Substituted Calixarenesp. 135
Binding of Lanthanides(III) and Thorium(IV) by Phosphorylated Calixarenesp. 150
Lanthanide Calix[4]arene Complexes Investigated by NMRp. 165
Bimetallic Lanthanide Supramolecular Edifices with Calixarenesp. 179
Molecular Recognition by Azacalix[3]arenesp. 195
Metal Ion Complexation and Extraction Behavior of Some Acyclic Analogs of tert-Butyl-calix[4]arene Hydroxamate Extractantsp. 208
Calixarenes as Ligands in Environmentally-Benign Liquid-Liquid Extraction Media: Aqueous Biphasic Systems and Room Temperature Ionic Liquidsp. 223
Calixarene-Anion Complexation
Calix[4]pyrrole-Functionalized Silica Gels: Novel Supports for the HPLC-Based Separation of Anionsp. 238
Lower Rim Amide- and Amine-Substituted Calix[4]arenes as Phase Transfer Extractants for Oxyions between an Aqueous and an Organic Phasep. 255
Calixarene Complexation of Neutral Molecules
Deep Cavities and Capsulesp. 270
Calixarene Metalloreceptors: Demonstration of Size and Shape Selectivity Inside a Calixarene Cavityp. 283
Synthesis and Structural Analysis of Thiacalixarene Derivativesp. 296
Synthesis and Fullerene Complexation Studies of p-Allylcalix[5]arenesp. 313
Hydrogen-Bonded Cavities Based upon Resorcin[4]arenes by Designp. 325
Author Indexp. 341
Subject Indexp. 342
Table of Contents provided by Syndetics. All Rights Reserved.

ISBN: 9780841236608
ISBN-10: 0841236607
Series: ACS Symposium Series
Audience: General
Format: Hardcover
Language: English
Number Of Pages: 378
Published: 10th August 2000
Country of Publication: US
Dimensions (cm): 23.52 x 15.19  x 2.29
Weight (kg): 0.63

Earn 349 Qantas Points
on this Book