Biomimetic Oxidations Catalyzed by Transition Metal Complexes

By: MEUNIER BERNARD

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Hardcover | 1 December 1997

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696 Pages

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Contents: Thermodynamic Influences of C-H Bond Oxidation (J M Mayer); Distinguishing Biomimetic Oxidations from Oxidations Mediated by Freely Diffusing Radicals (K U Ingold & P A MacFaul); Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates (J L McLain et al.); Models of Heme Peroxidases and Catalases (B Meunier); Non-Heme Peroxidases and Catalases: Mechanistic Implications from the Studies of Manganese and Vanadium Model Compounds (C Slebodnick et al.); Methane Monooxygenase Models (Z-B Hu & S M Gorun); Models of Copper Enzymes and Heme-Copper Oxidases (M A Kopf & K D Karlin); Iron-Containing Models of Catechol Dioxygenases (H-J Kr¼ger); Biomimetic Chemistry of Molybdenum (C G Young); Models of Superoxide Dismutases (D E Cabelli et al.); Modeling the Oxygen-Evolving Complex in Photosystem II (J Limburg et al.); Asymmetric Biomimetic Oxidations (A Robert & B Meunier); Bioinspired Oxidations Catalyzed by Ruthenium Complexes (S-I Murahashi & N Komiya); Biocatalytic and Biomimetic Oxidations from an Industrial Perspective (R A Sheldon);

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Non-Fiction Science Chemistry Inorganic Chemistry Biology, Life Sciences Biochemistry Physical Chemistry Catalysis Organic Chemistry Organometallic Chemistry Analytical Chemistry Booktopia Publisher Services

World Scientific Publishing

Acknowledgments
List of Contributors
Introduction
Thermodynamic Influences on C-H Bond Oxidation	p. 1
Distinguishing Biomimetic Oxidations from Oxidations Mediated by Freely Diffusing Radicals	p. 45
Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates	p. 91
Models of Heme Peroxidases and Catalases	p. 171
Non-Heme Peroxidases and Catalases: Mechanistic Implications from the Studies of Manganese and Vanadium Model Compounds	p. 215
Methane Monooxygenase Models	p. 269
Models of Copper Enzymes and Heme-Copper Oxidases	p. 309
Iron-Containing Models of Catechol Dioxygenases	p. 363
Biomimetic Chemistry of Molybdenum	p. 415
Models of Superoxide Dismutases	p. 461
Modeling the Oxygen-Evolving Complex in Photosystem II	p. 509
Asymmetric Biomimetic Oxidations	p. 543
Bioinspired Oxidations Catalyzed by Ruthenium Complexes	p. 563
Biocatalytic and Biomimetic Oxidations from an Industrial Perspective	p. 613
Glossary and Abbreviations	p. 663
Index	p. 669
Table of Contents provided by Blackwell. All Rights Reserved.

Biomimetic Oxidations Catalyzed by Transition Metal Complexes

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