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Best Synthetic Methods : Acetylenes, Allenes and Cumulenes - Lambert Brandsma

Best Synthetic Methods

Acetylenes, Allenes and Cumulenes

Hardcover

Published: 1st December 2003
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There is a vast and often bewildering array of synthetic methods and reagents available to organic chemists today. The "Best Synthetic Methods" series allows any scientist who is interested in the chemical transformations of molecules to choose between all the alternatives and assess their real advantages and limitations. With the emphasis on laboratory use, these volumes represent a comprehensive and practical guide to modern synthetic organic chemistry.
This book is the product of the author's many years practical experience and reading of the original literature. It contains a valuable distillation and critical evaluation of the "Best Synthetic Methods" for the formation and reaction of molecules containing carbon-carbon triple bonds or cumulative carbon-carbon double bonds. A brief review of each area is provided, but the emphasis in all cases is on describing efficient practical methods to effect the transformations described. The reader can therefore use this book to rapidly review and select the best methods of performing a synthetic conversion to create or modify a molecule containing an acetylene, allene or cumulene functionality. In addition, the documentation of a large number of experimental recipes enables the user to synthesise an unsaturated molecule without the need to access to the original literature.
- Reviews and evaluates the various methods for the formation and reaction of acetylenes, cumulenes and allenes.
- Provides detailed practical experimental for many important reactions.
- General tips and analytical data are provided from the author's own extensive research in this area.

Procedures and Equipment
Preparation, Purification and Storage of Some Solvents and Reagents
Generation of Metallated Acetylenes, Allenes and Cumulenes
Reactions of Metallated Acetylenes and Allenes with Alkylating Agents
Reactions with Aldehydes and Ketones
Carboxylation, Acylation and Related Reactions
Silylation, Stannylation and Phosphorylation
Sulfenylation and Related Reactions
Halogenation of Acetylenes
Acetylenes, Allenes and Cumulenes by Elimination Reactions
Cumulenes by Dehalogenation of Geminal Dihalogenocyclopropanes
Acetylenic and Allenic Derivatives by Substitution on sp- and sp 2 -Carbon
Aminoalkylation of Acetylenic Compounds
Cross-Coupling between 1-Alkynes and 1-Bromo-1-alkynes
Copper Halide-Catalysed Oxidative Coupling of Acetylenes
Transition Metals-Catalysed Couplings of Acetylenes with sp 2 -Halides
Base-Catalysed Isomerisations of Acetylenic Compounds
Allenic Compounds by 2,3- and 3,3-Sigmatropic Rearrangements
Miscellaneous Reactions of Acetylenic and Allenic Compounds
Transformation of Functional Groups in Acetylenic and Allenic Compounds
Table of Contents provided by Publisher. All Rights Reserved.

ISBN: 9780121257514
ISBN-10: 0121257517
Series: Best Synthetic Methods
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 502
Published: 1st December 2003
Publisher: Elsevier Science Publishing Co Inc
Country of Publication: US
Dimensions (cm): 15.2 x 22.9  x 2.54
Weight (kg): 0.92