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Analytical and Physical Electrochemistry

By: Hubert Girault

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Paperback | 5 February 2021 | Edition Number 1

At a Glance

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450 Pages

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24.13 x 15.87 x 3.04

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The study of electrochemistry is pertinent to a wide variety of fields, including bioenergetics, environmental sciences, and engineering sciences. In addition, electrochemistry plays a fundamental role in specific applications as diverse as the conversion and storage of energy and the sequencing of DNA.
Intended both as a basic course for undergraduate students and as a reference work for graduates and researchers, Analytical and Physical Electrochemistry covers two fundamental aspects of electrochemistry: electrochemistry in solution and interfacial electrochemistry. By bringing these two subjects together into a single volume, the author clearly establishes the links between the physical foundation and the analytical applications of electrochemistry.
The philosophy of Analytical and Physical Electrochemistry has been to publish all the mathematical derivations in detail, allowing you, if you so desire, to follow the calculations that lead to the main results. With this rigorous approach, the author has provided a book of reference constructed from first principles. In this respect, the nomenclature and standards of the IUPAC (International Union of Pure and Applied Chemistry) are observed.

Industry Reviews

"[A]n innovative textbook [T]his new edition gathers the physical bases of electroanalytical techniques, including electrophoretic methods, in a single volume. The strength of the book is its excellent illustrative presentation, which includes 272 figures and schematic diagrams. This book covers both fundamental and current aspects of analytical and physical electrochemistry. It is suitable for use in a basic undergraduate course and as an advanced reference for graduate students, researchers, and electrochemical engineers. This book should serve as a popular reference for both the English and French communities of electrochemistry." - Analytical Chemistry

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Preface	p. vii
Preface to the Original French Version	p. viii
Electrochemical Potential	p. 1
Electrochemical potential of ions	p. 1
Electrochemical potential of electrons	p. 23
Electrochemical Equilibria	p. 33
Redox reactions at metallic electrodes	p. 33
Cells and accumulators	p. 50
Pourbaix diagrams	p. 54
Electrochemical equilibria at the interface between two electrolytes	p. 57
Analytical applications of potentiometry	p. 63
Ion exchange membranes	p. 78
The respiratory chain	p. 82
Electrolyte Solutions	p. 83
Liquids	p. 83
Thermodynamic aspects of solvation	p. 85
Structural aspects of ionic solvation	p. 100
Ion-ion interactions	p. 105
Ion pairs	p. 123
Computational methods	p. 129
Appendix	p. 131
Transport in Solution	p. 133
Transport in electrolyte solutions	p. 133
Conductivity of electrolyte solutions	p. 138
Influence of concentration on conductivity	p. 145
Dielectric friction	p. 152
Thermodynamics of irreversible systems	p. 160
Statistical aspects of diffusion	p. 163
Elements of fluid mechanics	p. 171
Electrified Interfaces	p. 177
Interfacial tension	p. 177
Interfacial thermodynamics	p. 180
Thermodynamics of electrified interfaces	p. 184
Spatial distribution of polarisation charges	p. 194
Structure of electrochemical interfaces	p. 215
Electrokinetic Phenomena and Electrochemical Separation Methods	p. 221
Electrokinetic phenomena	p. 221
Capillary electrophoresis	p. 229
Electrophoretic methods of analytical separation	p. 239
Electrophoretic separation of biopolymers	p. 244
Ion chromatography	p. 256
Industrial methods of electrochemical separation	p. 261
Steady State Amperometry	p. 265
Electrochemical kinetics	p. 265
Current controlled by the kinetics of the redox reactions	p. 268
Reversible systems: Current limited by diffusion	p. 275
Electrodes with a diffusion layer of controlled thickness	p. 280
Quasi-reversible systems: Current limited by kinetics and diffusion	p. 288
Irreversible systems: Current limited by kinetics and diffusion	p. 294
Quasi-reversible systems: Current limited by diffusion, migration and kinetics	p. 295
Experimental aspects of amperometry	p. 296
Pulse Voltammetry	p. 301
Chronoamperometry following a potential step	p. 301
Polarography	p. 311
Square wave voltammetry	p. 319
Stripping voltammetry
Thin layer voltammetry	p. 333
Amperometric detectors for chromatography	p. 337
Electrochemical Impedance	p. 339
Transfer function	p. 339
Elementary circuits	p. 343
Impedance of an electrochemical system	p. 351
AC voltammetry	p. 368
Cyclic Voltammetry	p. 375
Electrochemically reversible reactions with semi-infinite linear diffusion	p. 375
Influence of the kinetics	p. 382
EC reactions	p. 385
Electron transfer at liquid [vertical bar] liquid interfaces	p. 396
Assisted ion transfer at liquid [vertical bar] liquid interfaces	p. 399
Surface reactions	p. 402
Hemi-spherical diffusion	p. 404
Voltabsorptometry	p. 407
Semi-integration	p. 408
Vector Analysis	p. 411
Coordinate systems	p. 411
Circulation of the field vector	p. 412
The vector gradient	p. 413
Flux of the field vector	p. 414
The Green-Ostrogradski theorem	p. 414
Work functions and standard redox potentials	p. 417
Symbols	p. 425
Index	p. 429
Table of Contents provided by Rittenhouse. All Rights Reserved.

Analytical and Physical Electrochemistry

At a Glance

Paperback

Industry Reviews

Shipping

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