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Alkoxyl, Carbonyloxyl, Phenoxyl, and Related Radicals : Molecules and Radicals - K.D. Asmus

Alkoxyl, Carbonyloxyl, Phenoxyl, and Related Radicals

Molecules and Radicals

Hardcover Published: 1997
ISBN: 9783540560579
Number Of Pages: 395

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Free radicals, which are key intermediates in many thermal, photochemical and radiation processes, are important for a proper understanding of fundamental natural processes and the successful development of organic syntheses. Volume II/18serves as a supplement and extension to volume II/13and covers rate constants and other kinetic data of free radical reactions in liquids. Furthermore II/18contains new chapters on reactions of radicals in excited states and of carbenes, nitrenes and analogues. Selected species in aqueous solutions for which other compilations are available were deliberately omitted as before, and for the same reason electron transfer equilibria of organic radicals were not covered.

Introductory material
General introduction
Oxyl-, carbonyloxyl and related radicalsp. 1
General introductionp. 1
Alkoxyl radicalsp. 1
Introductionp. 1
Unimolecular reactionsp. 3
Radical-molecule reactionsp. 10
Siloxyl radicalsp. 175
Carbonyloxyl radicalsp. 175
Introductionp. 175
Unimolecular reactionsp. 176
Radical-molecule reactionsp. 183
Phosphinoyloxyl radicalsp. 225
Sulfonyloxyl radicalsp. 226
References for 7p. 228
Phenoxyl and related radicalsp. 231
Introductionp. 231
Radical-radical reactionsp. 232
Self-reactionsp. 232
Radical-dimer equilibriap. 260
Reactions involving different phenoxyl radicalsp. 261
Radical-dimer equilibria involving different phenoxyl radicalsp. 266
Reactions involving a different radicalp. 268
Reactions involving oxygen and O2-p. 269
Reactions involving a peroxyl radicalp. 277
Unimolecular reactionsp. 284
Isomerizationp. 284
Scissionp. 301
Miscellaneous unimolecular reactionsp. 301
Radical-molecule reactionsp. 305
Reactions with alkenesp. 305
Reactions with phenolsp. 311
Reactions with hydroperoxidesp. 348
Electron and proton transfer reactionsp. 357
Reactions with biological moleculesp. 378
References for 8p. 394
Index of substances for Vols.13 and 18
Table of Contents provided by Publisher. All Rights Reserved.

ISBN: 9783540560579
ISBN-10: 3540560572
Series: Molecules and Radicals
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 395
Published: 1997
Publisher: Springer-Verlag Berlin and Heidelberg Gmbh & Co. Kg
Country of Publication: DE
Dimensions (cm): 27.0 x 19.3  x 3.6
Weight (kg): 1.44

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