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Advances in Physical Organic Chemistry : Volume 42 - John Richard

Advances in Physical Organic Chemistry

Volume 42

Hardcover

Published: 29th November 2007
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Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics.
* Reviews the application of quantitative and mathematical methods towards understanding chemical problems
* Multidisciplinary volumes cover organic, organometallic, bioorganic, enzymes and materials topics

Editor's Prefacep. ix
Contributors to Volume 42p. xi
Cycloaromatization reactions: the testing ground for theory and experimentp. 1
Introduction: bonds lost and bonds formed, or chemical bookkeepingp. 1
Cycloaromatization reactions: breaking [pi]-bonds and breaking the rulesp. 2
The diversity of cycloaromatization reactionsp. 3
The relative role of [sigma]- versus [pi]-effects at the early reaction stagep. 6
[sigma]-Effects on reactant stabilityp. 10
[pi]-Effects on reactant stabilityp. 22
Transition state effects: communication of orthogonal orbitals in the transition state of radical-anionic cyclizationsp. 23
Effects on product stabilityp. 27
Conclusionp. 31
Referencesp. 31
N-Acyloxy-N-alkoxyamides - structure, properties, reactivity and biological activityp. 35
Introductionp. 35
Synthesisp. 39
Structurep. 43
Chemical reactivityp. 59
Biological activity of N-acyloxy-N-alkoxyamidesp. 97
Conclusionsp. 115
Acknowledgementsp. 116
Referencesp. 117
The Interplay between experiment and theory: computational NMR spectroscopy of carbocationsp. 125
Introductionp. 125
Alkyl and cycloalkylmethyl cationsp. 126
Vinyl cationsp. 133
Cycloalkyl cationsp. 142
[mu]-Hydrido-bridged carbocationsp. 144
Bicyclic and polycyclic carbocationsp. 145
[pi]-Stabilized carbocationsp. 150
Heteroatom stabilized carbocationsp. 156
Final remarksp. 158
Conclusionsp. 160
Acknowledgmentsp. 160
Referencesp. 160
Dynamics of guest binding to supramolecular systems: techniques and selected examplesp. 167
Introductionp. 167
Techniquesp. 169
Examples of supramolecular dynamics studiesp. 185
Conclusionsp. 216
Acknowledgementsp. 217
Referencesp. 217
Mechanisms of oxygenations in zeolitesp. 225
Introductionp. 225
Zeolitesp. 226
Experimental considerationsp. 230
Intrazeolite photooxygenationsp. 232
Acknowledgementp. 261
Referencesp. 262
Metal-catalyzed alcoholysis reactions of carboxylate and organophosphorus estersp. 271
Introductionp. 271
Background theoryp. 274
Titrations in alcoholp. 276
Metal ion alcoholysis and titration in alcoholp. 278
Transition metal ion and Ln[superscript 3+] catalysts of transesterifications of neutral carboxylate and organophosphate estersp. 284
Transition metal ion and La[superscript 3+]-catalysis of the alcoholysis of phosphate diestersp. 308
Conclusionsp. 324
Acknowledgementsp. 325
Referencesp. 325
Author Indexp. 333
Cumulative Index of Authorsp. 351
Cumulative Index of Titlesp. 353
Subject Indexp. 363
Table of Contents provided by Ingram. All Rights Reserved.

ISBN: 9780123740939
ISBN-10: 0123740932
Series: Advances in Physical Organic Chemistry : Book 42
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 382
Published: 29th November 2007
Publisher: Elsevier Science Publishing Co Inc
Country of Publication: US
Dimensions (cm): 24.0 x 16.5  x 2.13
Weight (kg): 0.84
Edition Number: 1