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Activation of Unreactive Bonds and Organic Synthesis : Topics in Organometallic Chemistry, 3 - Shinji Murai

Activation of Unreactive Bonds and Organic Synthesis

Topics in Organometallic Chemistry, 3

By: Shinji Murai (Editor)

Hardcover Published: May 1999
ISBN: 9783540648628
Number Of Pages: 267

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In the last few years a large repetoire of methods for the activation of unreactive organic functionalities & for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage & formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy & create new opportunities for innovative organic transformations, for both industry & academia. This is the first book that provides a thorough & timely coverage of both inorganic & organic synthetic aspects of bond activation, thus giving a broad overview of the field & allowing both inorganic & organic chemists ready access to the methodologies involved.

A General Survey and Recent Advances in the Activation of Unreactive Chemical Bonds by Metal Complexesp. 1
Activation of C-H Bonds. Stoichiometric Reactionsp. 9
Activation of C-H Bonds: Catalytic Reactionsp. 47
Catalytic Activation of Methane and Ethane by Metal Compoundsp. 81
Cleavage of Carbon-Carbon Single Bonds by Transition Metalsp. 97
Activation of Si-Si Bonds by Transition-Metal Complexesp. 131
Activation of C-O Bonds: Stoichiometric and Catalytic Reactionsp. 161
Activation of Otherwise Unreactive C-Cl Bondsp. 193
Activation of the N-N Triple Bond in Molecular Nitrogen: Toward its Chemical Transformation into Organo-Nitrogen Compoundsp. 227
Metal Reagents for Activation and Functionalization of Carbon-Fluorine Bondsp. 243
Author Indexp. 271
Table of Contents provided by Publisher. All Rights Reserved.

ISBN: 9783540648628
ISBN-10: 3540648623
Series: Topics in Organometallic Chemistry, 3
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 267
Published: May 1999
Publisher: Springer-Verlag Berlin and Heidelberg Gmbh & Co. Kg
Country of Publication: DE
Dimensions (cm): 24.77 x 17.15  x 2.54
Weight (kg): 0.57