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Molecular Magnetism

From Molecular Assemblies to the Devices

By: Eugenio Coronado (Editor), P. Delhaes (Editor), Dante Gatteschi (Editor), Joel S. Miller (Editor)

Hardcover

Published: 30th June 1996
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Molecular Magnetism: From Molecular Assemblies to the Devices reviews the state of the art in the area. It is organized in two parts, the first of which introduces the basic concepts, theories and physical techniques required for the investigation of the magnetic molecular materials, comparing them with those used in the study of classical magnetic materials. Here the reader will find: (i) a detailed discussion of the electronic processes involved in the magnetic interaction mechanisms of molecular systems, including electron delocalization and spin polarization effects; (ii) a presentation of the available theoretical models based on spin and Hubbard Hamiltonians; and (iii) a description of the specific physical investigative techniques used to characterize the materials. The second part presents the different classes of existing magnetic molecular materials, focusing on the possible synthetic strategies developed to date to assemble the molecular building blocks ranging from purely organic to inorganic materials, as well as on their physical properties and potential applications. These materials comprise inorganic and organic ferro- and ferrimagnets, high nuclearity organic molecules and magnetic and metallic clusters, spin crossover systems, charge transfer salts (including fulleride salts and organic conductors and superconductors), and organized soft media (magnetic liquid crystals and Langmuir-Blodgett films).

William E. Hatfield, 1937-1995p. 1
Magnetic Phenomena in Molecular Materialsp. 5
Exchange Interactions I. Mechanismsp. 65
Exchange Interactions II. Spin Hamiltoniansp. 85
Localization vs. Delocalization in Molecules and Clusters. Electronic and Vibronic Interactions in Mixed-Valence Systemsp. 105
Magnetic Resonances and Spin Dynamics in Molecular Magnetsp. 141
Optical Spectroscopyp. 173
Neutron Scattering: Magnetic Structures and Magnetic Densitiesp. 199
Inelastic Neutron Scatteringp. 229
Bimetallic Molecular-Based Magnetic Materialsp. 243
New Magnetic Properties Emerging from Zero- and One-Dimensional Molecular Materialsp. 289
Metal Cluster Compounds. Model Systems for Nano-Sized Metal Particlesp. 309
Spin Transitions in Iron(II) Complexes. An Introductionp. 327
Magnets Based Upon Electron-Transfer Saltsp. 379
Disorder and Dimensionality in Molecule-Based Magnetsp. 415
Organic Magnetic Materials. Intramolecular Magnetic Exchangep. 425
Organic Magnetic Materials with Cooperative Magnetic Propertiesp. 449
Magnetic Properties of Organic Conductors and Superconductorsp. 473
Electronic and Magnetic Organized Soft Mediap. 503
The Photomagnetic and Magneto-Optic Effectsp. 521
Applications of Molecular Magnetism to Biomedicine. New Contrast Media for Magnetic Resonance Imagingp. 553
Opportunities for New Physics in Molecular Magnetismp. 561
Design, Synthesis and Processing of Molecular-Organic and Inorganic-Magnetic Materialsp. 571
Subject Indexp. 583
Table of Contents provided by Blackwell. All Rights Reserved.

ISBN: 9780792341307
ISBN-10: 0792341309
Series: NATO Science Series E:
Audience: Professional
Format: Hardcover
Language: English
Number Of Pages: 601
Published: 30th June 1996
Dimensions (cm): 23.4 x 15.6  x 3.3
Weight (kg): 1.023