Thoroughly updated, Introduction to Polymers, Third Edition presents the science underpinning the synthesis, characterization and properties of polymers. The material has been completely reorganized and expanded to include important new topics and provide a coherent platform for teaching and learning the fundamental aspects of contemporary polymer science.
New to the Third Edition
Part I
This first part covers newer developments in polymer synthesis, including 'living' radical polymerization, catalytic chain transfer and free-radical ring-opening polymerization, along with strategies for the synthesis of conducting polymers, dendrimers, hyperbranched polymers and block copolymers. Polymerization mechanisms have been made more explicit by showing electron movements.Part II
In this part, the authors have added new topics on diffusion, solution behaviour of polyelectrolytes and field-flow fractionation methods. They also greatly expand coverage of spectroscopy, including UV visible, Raman, infrared, NMR and mass spectroscopy. In addition, the Flory-Huggins theory for polymer solutions and their phase separation is treated more rigorously.Part III
A completely new, major topic in this section is multicomponent polymer systems. The book also incorporates new material on macromolecular dynamics and reptation, liquid crystalline polymers and thermal analysis. Many of the diagrams and micrographs have been updated to more clearly highlight features of polymer morphology.Part IV
The last part of the book contains major new sections on polymer composites, such as nanocomposites, and electrical properties of polymers. Other new topics include effects of chain entanglements, swelling of elastomers, polymer fibres, impact behaviour and ductile fracture. Coverage of rubber-toughening of brittle plastics has also been revised and expanded.
While this edition adds many new concepts, the philosophy of the book remains unchanged. Largely self-contained, the text fully derives most equations and cross-references topics between chapters where appropriate. Each chapter not only includes a list of further reading to help readers expand their knowledge of the subject but also provides problem sets to test understanding, particularly of numerical aspects.
The second edition of this book is currently the recommended text for a second year undergraduate lecture course I deliver. In future I will recommend the third edition for both this course and a fourth year (Masters) lecture course on advanced polymer synthesis. Moreover, not only have Young and Lovell produced an excellent text (again) for supporting undergraduate teaching, this book is also a superb entry level text for postgraduates students with limited experience of polymers. -Chemistry World, 2012
| Concepts, Nomenclature And Synthesis Of Polymers | |
| Concepts and Nomenclature | |
| The Origins of Polymer Science and the Polymer Industry | |
| Basic Definitions and Nomenclature | |
| Molar Mass and Degree of Polymerization | |
| Principles of Polymerization | |
| Introduction | |
| Classification of Polymerization Reactions | |
| Monomer Functionality and Polymer Skeletal Structure | |
| Functional Group Reactivity and Molecular Size: The Principle of Equal Reactivity | |
| Step Polymerization | |
| Introduction | |
| Linear Step Polymerization | |
| Non-Linear Step Polymerization | |
| Radical Polymerization | |
| Introduction to Radical Polymerization | |
| The Chemistry of Conventional Free-Radical Polymerization | |
| Kinetics of Conventional Free-Radical Polymerization | |
| Free-Radical Polymerization Processes | |
| Reversible-Deactivation ('Living') Radical Polymerizations | |
| Non-Linear Radical Polymerizations | |
| Ionic Polymerization | |
| Introduction to Ionic Polymerization | |
| Cationic Polymerization | |
| Anionic Polymerization | |
| Group-Transfer Polymerization | |
| Stereochemistry and Coordination Polymerization | |
| Introduction to Stereochemistry of Polymerization | |
| Tacticity of Polymers | |
| Geometric Isomerism in Polymers Prepared from Conjugated Dienes | |
| Ziegler-Natta Coordination Polymerization | |
| Metallocene Coordination Polymerization | |
| Ring-Opening Polymerization | |
| Introduction to Ring-Opening Polymerization | |
| Cationic Ring-Opening Polymerization | |
| Anionic Ring-Opening Polymerization | |
| Free-Radical Ring-Opening Polymerization | |
| Ring-Opening Metathesis Polymerization | |
| Specialized Methods of Polymer Synthesis | |
| Introduction | |
| Solid-State Topochemical Polymerization | |
| Polymerization by Oxidative Coupling | |
| Precursor Routes to Intractable Polymers | |
| Supramolecular Polymerization (Polyassociation) | |
| Copolymerization | |
| Introduction | |
| Step Copolymerization | |
| Chain Copolymerization | |
| Block Copolymer Synthesis | |
| Graft Copolymer Synthesis | |
| Characterization Of Polymers | |
| Theoretical Description of Polymers in Solution | |
| Introduction | |
| Thermodynamics of Polymer Solutions | |
| Chain Dimensions | |
| Frictional Properties of Polymer Molecules in Dilute Solution | |
| Number-Average Molar Mass | |
| Introduction to Measurements of Number-Average Molar Mass | |
| Membrane Osmometry | |
| Vapour Pressure Osmometry | |
| Ebulliometry and Cryoscopy | |
| End-Group Analysis | |
| Effects of Low Molar Mass Impurities upon Mn | |
| Scattering Methods | |
| Introduction | |
| Static Light Scattering | |
| Dynamic Light Scattering | |
| Small-Angle X-Ray and Neutron Scattering | |
| Frictional Properties of Polymers in Solution | |
| Introduction | |
| Dilute Solution Viscometry | |
| Ultracentrifugation | |
| Molar Mass Distribution | |
| Introduction | |
| Fractionation | |
| Gel Permeation Chromatography | |
| Field-Flow Fractionation | |
| Mass Spectroscopy | |
| Chemical Composition and Molecular Microstructure | |
| Introduction | |
| Principles of Spectroscopy | |
| Ultraviolet and Visible Light Absorption Spectroscopy | |
| Infrared Spectroscopy | |
| Raman Spectroscopy | |
| Nuclear Magnetic Resonance Spectroscopy | |
| Mass Spectroscopy | |
| Phase Structure And Morphology Of Bulk Polymers | |
| The Amorphous State | |
| Introduction | |
| The Glass Transition | |
| Factors Controlling the Tg | |
| Macromolecular Dynamics | |
| The Crystalline State | |
| Introduction | |
| Determination of Crystal Structure | |
| Polymer Single Crystals | |
| Semi-Crystalline Polymers | |
| Liquid Crystalline Polymers | |
| Defects in Crystalline Polymers | |
| Crystallization | |
| Melting | |
| Multicomponent Polymer Systems | |
| Introduction | |
| Polymer Blends | |
| Block Copolymers | |
| Properties Of Bulk Polymers | |
| Elastic Deformation | |
| Introduction | |
| Elastic Deformation | |
| Elastic Deformation of Polymers | |
| Viscoelasticity | |
| Introduction | |
| Viscoelastic Mechanical Models | |
| Boltzmann Superposition Principle | |
| Dynamic Mechanical Testing | |
| Frequency Dependence of Viscoelastic Behaviour | |
| Transitions and Polymer Structure | |
| Time-Temperature Superposition | |
| Effect of Entanglements | |
| Non-Linear Viscoelasticity | |
| Elastomers | |
| Introduction | |
| Thermodynamics of Elastomer Deformation | |
| Statistical Theory of Elastomer Deformation | |
| Stress-Strain Behaviour of Elastomers | |
| Factors Affecting Mechanical Behaviour | |
| Yield and Crazing | |
| Introduction | |
| Phenomenology of Yield | |
| Yield Criteria | |
| Deformation Mechanisms | |
| Crazing | |
| Fracture and Toughening | |
| Introduction | |
| Fundamentals of Fracture | |
| Mechanics of Fracture | |
| Fracture Phenomena | |
| Toughened Polymers | |
| Polymer Composites | |
| Introduction to Composite Materials | |
| Matrix Materials | |
| Types of Reinforcement | |
| Composite Composition | |
| Particulate Reinforcement | |
| Fibre Reinforcement | |
| Nanocomposites | |
| Electrical Properties | |
| Introduction to Electrical Properties | |
| Dielectric Properties | |
| Conduction in Polymers | |
| Polymer Electronics | |
| Answers to Problems | |
| Index | |
| Problems and Further Reading appear at the end of each chapter | |
| Table of Contents provided by Publisher. All Rights Reserved. |
ISBN: 9780849339295
ISBN-10: 0849339294
Audience:
Tertiary; University or College
Format:
Paperback
Language:
English
Number Of Pages: 688
Published: 24th June 2011
Dimensions (cm): 25.4 x 17.8
x 3.7
Weight (kg): 1.166