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The demand for organosilicon elastomers used in the production of thermally resistant rubbers and organosilicon polymers for making non-metal composite materials is increasing from year to year. This monograph presents a discussion on the methods used for synthesizing and studying properties of newly designed organosilicon polymers, namely organosiloxane copolymers with cyclolinear structure of macromolecules. This book presents an overview of data on methods of synthesizing primary linear and cyclic organosiloxanes of various structures. This book will be of value and interest to researchers working in the field of chemistry of organosilicons.
| Preface | p. v |
| Introduction | p. vi |
| Linear and cyclic organosiloxanes | p. 1 |
| Linear and cyclic organosiloxanes with assigned disposition of functional groups at silicon atoms | p. 1 |
| Polyfunctional linear organochlorosiloxanes and carbosilanes | p. 1 |
| Organocyclosiloxanes with given disposition of functional groups at atoms of silicon | p. 11 |
| Organocyclocarbosiloxanes with functional groups at silicon atoms | p. 27 |
| References | p. 52 |
| Organosilicon oligomers and copolymers of bead-shaped structure | p. 59 |
| Bead-shaped organosiloxane oligomers and copolymers with organocyclotetra(penta,hexa)siloxane fragments in the backbone | p. 59 |
| Bead-shaped methylphenylsiloxane copolymers with ethylene bridges between cycles | p. 106 |
| Bead-shaped methyl(ethyl)siloxane polymers with ethylene bridges between rings | p. 120 |
| Oligomers and copolymers with organocyclocarbosiloxane fragments in the chain | p. 130 |
| Silarylene cyclosiloxane and silarylene carborganocyclosiloxane oligomers and copolymers | p. 135 |
| References | p. 159 |
| Copolymers with cyclic fragments in dimethysiloxane backbone | p. 167 |
| Siloxane cyclolinear copolymers with organocyclotetra(penta,hexa)siloxane fragments in dimethylsiloxane backbone | p. 168 |
| Cyclolinear copolymers with cyclic carbosiloxane fragments in dimethylsiloxane backbone | p. 213 |
| Organosiloxane copolymers with heterocyclic fragments in the dimethylsiloxane backbone | p. 216 |
| Poly(organocarbosiloxanes) with cyclic siloxane fragments in the backbone | p. 220 |
| Cyclolinear copolymers derived by polymerization of organobicyclo- and organotricyclosiloxanes | p. 234 |
| Synthesis of organodi- and organotricyclosiloxanes with labile cyclic fragments | p. 234 |
| Polymerization of cyclolinear organosiloxane copolymers with cyclic fragments in the backbone | p. 237 |
| References | p. 239 |
| Organosilixane copolymers with cyclic fragments in the side chain | p. 245 |
| Synthesis of monomeric difunctional organocyclosiloxanes | p. 245 |
| Synthesis of organosiloxane copolymers with Monocyclic (cyclotri-, cyclotetra-, cyclopentasiloxane) fragments in the side chain | p. 255 |
| Synthesis of organosiloxane oligomers with cyclic fragments in the side chain by catalytic dehydrocondensation | p. 278 |
| Synthesis of cyclolinear organosiloxane copolymers by hydrosilylation | p. 284 |
| References | p. 290 |
| Organosilicon copolymers with carbocyclosiloxane fragments in dimethylsiloxane backbone | p. 293 |
| Synthesis of organospirobicyclosiloxanes and organospirobicyclosilazasiloxanes | p. 293 |
| Synthesis of difunctional heterocyclic compounds | p. 300 |
| Synthesis and study of properties of organosilicon copolymers with cardocyclosiloxane fragments | p. 303 |
| Organosilicon copolymers with card-type heterocyclic fragments in the linear chain | p. 316 |
| Synthesis and studies of properties of card-type organosilicon oligomers with silaoxadihydrophenentrene fragments in the chain | p. 322 |
| References | p. 328 |
| Organosilicon copolymers with bi-, tri- and tetracyclic structures in dimethylsiloxane backbone | p. 331 |
| Synthesis of organobi-, organotri- and organotetracyclosiloxanes and bicyclocarbosiloxanes with functional groups | p. 331 |
| Synthesis of difunctional bicyclocarbosiloxanes | p. 365 |
| Synthesis of organosilicon copolymers with organobi-, organotri- and organotetracyclosiloxane fragments in dimethylsiloxane backbone | p. 366 |
| Organosilicon copolymers with bicyclocarbosiloxane fragments in the backbone | p. 393 |
| Carbosiloxane copolymers with tricyclic fragments in the backbone | p. 396 |
| References | p. 405 |
| Synthesis of organosilicon cyclolinear block-copolymers | p. 409 |
| Block-copolymers with poly(phenylsilsesquioxane) fragments in the dimethylsiloxane backbone | p. 410 |
| Synthesis of poly(phenylsilsesquioxanes) with functional groups | p. 410 |
| Phenylsilsesquioxane-dimethylsiloxane copolymers. Block copolymers of A[subscript m]B[subscript n] type | p. 422 |
| Organosilicon cyclolinear block-copolymers of the (AB)[subscript m]C[subscript n] type | p. 480 |
| References | p. 494 |
| Table of Contents provided by Ingram. All Rights Reserved. |
ISBN: 9789067643979
ISBN-10: 9067643971
Series: New Concepts in Polymer Science
Audience:
Professional
Format:
Hardcover
Language:
English
Number Of Pages: 498
Published: 1st November 2003
Dimensions (cm): 23.5 x 15.6
Weight (kg): 0.907
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